4Three Subatomic Particles Proton: (+) charged particle found inside the nucleusNeutron: neutral particle found inside the nucleusElectron: (-) charged particle found outside the nucleus in various energy levels
6Atomic Number & Atomic Mass Atomic Number: the number of protons (and electrons in neutral atoms)Mass Number: the numberof protons plus the numberof neutrons (mass of nucleus)Atomic Mass (Weight): weighted average of the isotopes for an elementMass #Atomic #
7Isotopes of Hydrogen What are isotopes? Atoms of the same element with the same # of protons, different # of neutrons
23Unique Properties of Water: Most abundant compound in nearly all living things
24Unique Properties of Water: Density of solid water vs. liquid waterExpansion on freezing – water forms a crystalline structure that expands and is less dense than its liquid state
25Unique Properties of Water: Covers more than 75% of the Earth’s surfaceWater 100°C or 212°FWater 0°C or 32°FUniversal solvent
26Unique Properties of Water: Water has a high heat capacityHeat capacity = the amount of heat energy required to increase its temperature, is relatively high.Large bodies of water (oceans and lakes) can absorb large amounts of heat with only small changes in temperature.This protects organisms living within from drastic changes in temperature.
27What is a polar molecule? An uneven distribution of electronsThe molecule becomes charged on each endIt means that the electrons areNOT shared equally
28Hydrogen BondingBecause of their partial positive and negative charges, polar molecules such as water can attract each other.The attraction between a hydrogen atom on one water molecule and the oxygen atom on another is known as a hydrogen bond.
29Interaction Between Water Molecules Negative Oxygen atomof one water molecule is attracted to the Positive Hydrogen atom of another water molecule to form a HYDROGEN BOND
31CohesionCohesion is when one water molecule sticks to another water molecule due to hydrogen bondingIt creates surface tension (a measure of strength) at the surface of the liquidProduces a surface “film” that allows small insects to “walk on water”
32Surface TensionA measure of how difficult it is to break the surface of a liquid because of hydrogen bonds.The surface tension of a liquid results from an imbalance of intermolecular attractive forces, (cohesive forces) between moleculesA molecule in the bulk liquid experiences cohesive forces with other molecules in ALL directions.A molecule at the surface of a liquid experiences only NET INWARD cohesive forces.
33Adhesion Adhesion is when a water molecule sticks to another substance (NOT another water molecule)A piece of tape adheres to the wallCapillary action is an example of adhesion (water moving from the roots, through the stem, & into the leaves of a flower)
34Capillary ActionWater climbing up a small tube because of the adhesion to the sides and the cohesion between water molecules.
35Adhesion Also Causes Water to … Attach to a silken spider webhold onto plant leaves
36Cohesion and AdhesionMercury does not wet glass - the cohesive forces within the drops are stronger than the adhesive forces between the drops and glass. When liquid mercury is confined in a tube, its surface (meniscus) has a convex shape because the cohesive forces in liquid mercury tend to draw it into a drop.When liquid water is confined in a tube, its surface (meniscus) has a concave shape because water adheres to the surface and creeps up the side.
37High Heat CapacityWater’s heat capacity, the amount of heat energy required to increase its temperature, is relatively high.Because of the multiple hydrogen bonds between water molecules, it takes a large amount of heat energy to cause those molecules to move faster and raise the temperature of the water.Large bodies of water, such as oceans and lakes, can absorb large amounts of heat with only small changes in temperature. This protects organisms living within from drastic changes in temperature.
38Universal Solvent Hydrophilic Hydrophobic A substance that is attracted to water (a polar molecule)Examples: sugar, alcoholHydrophobicA substance that repels (is afraid of) water (a nonpolar molecule)Examples: oilThe Chemistry of Water
39Solutions and Suspensions MixturesSolutions and Suspensions
40What is a Mixture?Substance composed of two or more elements or compounds that are mixed together, but NOT chemically combined.Mixture Examples: salt & pepper; sugar & sand; salt & sand; Earth’s atmosphere; soil
41Solutions and Suspensions Mixture – a material that consists of 2 or more elements or compounds physically mixed together but are not chemically combined.
42Homogeneous Mixture (Solution) Homogeneous mixture in which one substance is dissolved in anotherExamples: sugar in water; salt in water; hot chocolate; tea, Kool-aidSalt Dissolving in Water
43Parts of a Solution All solutions contain a solute and a solvent. Solvent is the substance doing the dissolving.Example: waterSolute is the substance that is being dissolved.Example: salt
44Heterogeneous Mixture (Suspensions) Mixture of water and non-dissolved materials (heterogeneous)Examples: blood; oil and water
45Application: 1 – Choose one of your examples of a solution. Explain how the parts(components of the solution) can beseparated.2 – For the same example, identify thesolute and solvent in the solution.Explain your reasoning.
46Example of a Solution: Water is the universal solvent. The solute (sugar) dissolves in the solvent (water).The solute (Kool-aid) dissolves in the solvent (water).The solute (oxygen) dissolves in the solvent (nitrogen).Water is the universal solvent.
47Homeostasis a. Makes a good insulator b. Resists temperature change Ability to maintain a steady state despite changing conditionsWater is important to this process because…a. Makes a good insulatorb. Resists temperature changec. Universal solventd. Coolante. Ice protects against temperature extremes (insulates frozen lakes)4
48Acids, Bases, pH, & Buffers All about the pH Scale
50Acids Compounds that release H+ into solution H+ = hydrogen ion If [H+] > [OH-] then thesolution is acidic.HCl H+ + Cl-
51Bases If [OH-] > [H+] then the solution is basic Compounds that releaseOH- into solutionOH- = hydroxide ionIf [OH-] > [H+] then thesolution is basicNaOH Na+ + OH-
52The pH scale (power of Hydrogen) as in Hydrogen ions Measures the relative concentration of H+ and OH-
53Interpreting the pH Scale pH is based on a logarithmic scaleA pH of 5 is 10× more concentrated than a pH of 6 (in terms of H+ concentration)A pH of 9 is 100× more concentrated than a pH of 11 (in terms of H+ concentration)
54Classifying Acids & Bases Strong acids have a pH value between 1-3Weak acids have a pH value between 4-6Bases:Strong bases have a pH value between 12-14Weak bases have a pH value between 8-11
55BuffersWeak acids or bases that can react with strong acids or bases to prevent sharp sudden changes in pHProduced naturally by the body to maintain homeostasisThe pH value in most cells isThe pH of stomach acid is 2The pH of the blood is 7.4
56Blood Buffer – pH needs to be 7.4 Double arrows meanreactions are inequilibriumbicarbonate ion (buffer)(Kidney – carriedaway in urine)Free hydrogen ionsCarbonic Acid(Lungs – carriedaway as CO2)
57Blood Buffer – pH needs to be 7.4 You can see that if the reactions go to the right, hydrogen ions are released, making the solution more acidic, and if the reactions go to the left, hydrogen ions are sucked up, making the solution more basic. The question that is probably eating away at you right now is: "how do I know which way the reactions are going to go-- to the right or to the left?“Good question! The bicarbonate ion isn't a very strong acid or base. It doesn't have to go one way or the other all the time. Instead, the direction it goes depends on the solution it is in. You see, if it is in an acidic solution, there are lots of hydrogen ions floating around; in this situation, the presence of tons of hydrogen ions will force the reaction to go to the left. Do you see why? Look at the reaction again. All you need for the reaction to be able to go to the left is available hydrogen ions (see the H+ in the middle that is needed for the reaction to go to the left?). So if bicarbonate ions find themselves in acidic solutions, they tend to act like the weak base they can be, and suck up the excess hydrogen ions.Consider what will happen if bicarbonate is put into a basic solution. A basic solution has very few hydrogen ions floating around. In this condition, the bicarbonate reaction cannot proceed to the left, since no hydrogen ions are available. Instead, it will go to the right, producing hydrogen ions. In this manner, bicarbonate ions will tend to act like the weak acid they can be, and release hydrogen ions.
58Use the structure of a water molecule to explain why it is polar. Why is water such a good solvent?What is the difference between a solution and a suspension?How do hydrogen bonds between water molecules occur?How does the body counteract a drop in blood pH during strenuous exercise?If a strong acid is dissolved in pure water will the pH of the solution be greater or less than 7?
59Water ChemistryPlease draw the structure of a water molecule (H2O).Label the charges on the molecule that make it polar (negative and positive ends).See if you can connect the water molecule that you drew to two other molecules of water using hydrogen bonds.Can you think of any unique properties that water displays?
60Water ChemistryExplain why water is “polar” in your own words.Explain capillary action in your own words.Explain surface tension in your own words.
61According to the scale, what substance is neutral? What solution has an [H+] of 0.01?Which substance produces the most OH- ions in solution?How many more times basic is pH 14 compared to pH 11.
63Objectives Distinguish between potential and kinetic energy. Differentiate between reactants and products in a chemical reaction.Explain the role of a catalyst in chemical reactions.
64What is energy? The ability to do work or cause a change. Can exist in different forms:thermal radiantchemical nuclearmechanical electrical
65Forms of Energy: POTENTIAL ENERGY stored energy KINETIC ENERGY energy of motionFREE ENERGY the energy available to do work
66Activation Energythe energy needed to start a chemical reaction.
67Chemical Reactions:Everything that happens in an organism is based on chemical reactions.A chemical reaction is a process that changes one set of chemicals into another set of chemicals.CO2 + H2O C6H12O6 + O2
68Chemical Reactions:The elements or compounds that enter into the reaction are the reactants.The elements or compounds produced by the reaction are the productsBonds are broken/formed in chemical reactions.
69What are the Reactants? Products? CO2 + H2O C6H12O6 + O2ReactantsProducts means “Yields” or “Produces”
70Energy RELEASED Reactions Activation Energy: the energy needed to start a chemical reaction.Exergonic (Exothermic) Reactions - involve a net release of free energyOften happen spontaneously
71Energy ABSORBED Reactions Activation Energy: the energy needed to start a chemical reaction.Endergonic (Endothermic) Reactions - involve a net absorption of free energyWill not occur without a source of energy
72Draw the enzyme pathway on your graph EnzymesEnzymes – are proteins that act as a biological catalyst.Catalyst – a substance that speeds up a chemical reaction by lowering the activation energy.Draw the enzyme pathway on your graph
73Enzyme ActionSubstrate – the reactants of an enzyme catalyzed reactionActive Site – where the substrate and enzyme join.Have complimentary shapesCan only bind with a specific molecule – “induced fit”
74How Enzymes Work: Enzymes act on a specific substrate. (Shapes fit together like a lock and a key)A small area on the enzyme, called the active site, can attract and hold only a specific substrate.The enzyme acts as a biological catalyst, which accelerates the rate of the chemical reaction.The enzyme reduces the activation energy needed by weakening the chemical bonds in the substrate.The enzyme is then released unchanged.
76Regulation of Enzyme Activity Enzymes work best at certain pH levels and temperatures.Most enzymes in humans work best at 37CDenaturation – a change in the enzymes shapeEnzyme becomes nonfunctionalHeat and pH can cause denaturationSome enzymes can be turned on and offLactose intolerance
78What letter represents the product? What letter represents the reactant?What letter represents the activation energy?How should the x and y axis be labeled?Is the reaction exergonic or endergonic? Explain