Presentation on theme: "Biomass Fundamentals Module 2: Definitions of Biomass"— Presentation transcript:
1Biomass Fundamentals Module 2: Definitions of Biomass A capstone course forBioSUCCEED:Bioproducts Sustainability: a University Cooperative Center of Excellence in EDucationThe USDA Higher Education Challenge Grants program gratefully acknowledged for support
2This course would not be possible without support from: USDAHigher Education Challenge (HEC) Grants Program
3What is biomass? Quiz M2.1 According to the US Department of Energy: Biomass is any organic material made from plants or animals. Domestic biomass resources include agricultural and forestry residues, municipal solid wastes, industrial wastes, and terrestrial and aquatic crops grown solely for energy purposes.In general, it is a carbon- containing substance or material that has a biological origin, is renewable, has little to no impact on green house gases, and is degradableQuiz M2.11. Which of the following cannot be considered biomass according to the DOE definition: (a) corn stover; (b) poultry; feathers; (c) clay; (d) human hair 2. Which of the following can be considered a biomass according to the general definition: (a) petroleum; (b) carbon dioxide; (c) diamond; (d) none of the above 3. What can potentially be another name for biomass: (a) biomaterial; (b) biochemical; (c) bioenergy; (d) all of the aboveFrom the US DOE: Biomass can be converted to other usable forms of energy and is an attractive petroleum alternative for a number of reasons. First, it is a renewable resource that is more evenly distributed over the Earth's surface than are finite energy sources, and may be exploited using more environmentally friendly technologies. Agriculture and forestry residues, and in particular residues from paper mills, are the most common biomass resources used for generating electricity and power, including industrial process heat and steam, as well as for a variety of biobased products. Use of liquid transportation fuels such as ethanol and biodiesel, however, currently derived primarily from agricultural crops, is increasing dramatically.Please see:
4Origins of biomass Where does it come from? HIGHLIGHT: AMBER Biomass comes from plants and animalsGenerally a whole component byproduct of their metabolism, or some modificationIt has been useful for the development of civilizationIt is part of a cycle of biosynthesis (manufacture) and biodegradability (death)The English word amber stems from the old Arabic word anbargris and refers to an oily, perfumed substance secreted by the sperm whale. Middle English ambre > Old French ambre > Medieval Latin ambra (or ambar). It floats on water and is washed up on the beaches. Due to a confusion of terms (see: it became to be the name for fossil resin or tree sap.Amber is fossilized tree resin; resin is the semi-solid, amorphous biomass secreted in wood cells.
5Why is it important? Quiz M2.2 1. Which of the following aspects of civilization did not benefit in some way from biomass? (a) housing construction; (b) food cultivation; (c) clothing; (d) all of the above 2. Where does ethanol come from? (a) wood; (b) wheat; (c) corn; (d) all of the above 3. Does biomass contribute to green house gas accumulation? (a) yes; (b) noBiomass is a source of materials (food, wood, paper, rubber, leather)Biomass is a source of fuel (ethanol, wood, biodiesel, oil)Biomass is a source of chemicals (rosins, detergents, sugars, terpenes)A recent article on ethanol from wood (believe it or not) can be found at:The green house effect or green house gases: The "greenhouse effect" is the heating of the Earth by greenhouse gases. It is named this way because of the trapping of heat by the panes (analogous to the gases) of a greenhouse. Short-wavelength radiation from the sun passes the earth's atmosphere, is absorbed by the surface of the Earth, causing it to warm. Part of the absorbed energy is radiated back to the atmosphere as long wave radiation. Little of this long wave radiation escapes back into space because it cannot pass through the greenhouse gases located in the atmosphere. The greenhouse gases selectively transmit the radiation, trapping some and allowing some to pass. The greenhouse gases absorb this energy and reemits the waves downward, causing the lower atmosphere to warm.Trees can produce some really fascinating chemicals such as aspirin (anti-inflammatory), taxol (cancer drug), and quinine (malaria drug); see:
6What is petroleum? FUEL & MATERIALS!!! Drilling for fuel Thought to be the decomposition product of animal and/or plant matter after protracted periods of timeNeeds to be “refined” to obtain usable chemicals for energy and materials (plastics, resins, composites, tars, asphalts, waxes, etc.)However, difficult to ascertain exactly how formedUS uses 25% or more of world supply to support its infrastructureThe above molecule is a representation of octane, the basic molecule that provide energy rich gasoline for liquid transportation needs in the US and the world.For a simple primer on petroleum, please see:Geologists view crude oil and natural gas as the product of compression and heating of ancient organic materials (i.e. kerogen) over geological time. Formation of petroleum occurs from hydrocarbon pyrolysis, in a variety of mostly endothermic reactions at high temperature and/or pressure. Today's oil formed from the preserved remains of prehistoric zooplankton and algae, which had settled to a sea or lake bottom in large quantities under anoxic conditions (the remains of prehistoric terrestrial plants, on the other hand, tended to form coal). Over geological time the organic matter mixed with mud, and was buried under heavy layers of sediment resulting in high levels of heat and pressure (known as diagenesis). This caused the organic matter to chemically change, first into a waxy material known as kerogen which is found in various oil shales around the world, and then with more heat into liquid and gaseous hydrocarbons in a process known as catagenesis.Geologists often refer to the temperature range in which oil forms as an "oil window"—below the minimum temperature oil remains trapped in the form of kerogen, and above the maximum temperature the oil is converted to natural gas through the process of thermal cracking.For more on the origins:
7What are the similarities between biomass and petroleum? Quiz M2.3Petro-economy vs. bio-economyPetroleum is believed to be the result of biomass being compressed under high pressure and a long time in an anoxic environmentHowever, petroleum is richer in energy by approximately 40% on a gal/gal basis, it is not renewable, and contributes to green house gas pollution1. For which of the following does petroleum not contribute in a petro-economy: (a) gasoline; (b) candles; (c) PVC piping (d) cotton 2. Where does ethanol come from? (a) wood; (b) wheat; (c) corn; (d) all of the above 3. Does biomass contribute to green house gas accumulation? (a) yes; (b) noPetroleum and biomass contribute to the manufacture of almost everything that you can think of. What is the difference? Oh, well, it’s just that biomass conversion was considered to be too expensive to compete with “cheap,” “abundant” oil! Well, we all know that THAT is not the case anymore! The following website contains some very nice background information on petroleum, what is in a barrel of “crude,” what chemicals can be made, and the environmental implications.A wonderful review by Ralph Hardy was written on the subject of the bio-based economy which can be found at:To obtain newsletters on the future economy, go to:To see a wonderful video on the future world and how it may appear, go to:
8What is bioenergy? ESSAY You and me are bioenergy!It is a natural form of energy that does not depend on non- renewable sources, like petroleum; referred to as a biofuelEthanol, biodiesel, pyrolysis oil, and butanol are typical bioenergy stock fuelsWe consider solar, wind, ocean currents, geothermals, nuclear, and others are alternative energy sources not to be confused as bioenergyESSAYAt this point, describe in a page or less, how bioenergy contributes to your lifestyle or how you would like it to. Or if that is too difficult, discuss how alternative fuels are incorporated into your life or how you would like to include them.A photo of a sugarcane is shown above – the traditional source of easily fermentable starting material for ethanol productionBiodiesel is the most common biofuel in Europe.In the US, biodiesel is not practical because we rely almost exclusively on gasoline, especially for light'First-generation biofuels' refer to biofuels made from sugar, starch, vegetable oil, or animal fats using conventional technology.duty vehicle needs (the bulk of our transportation needs). More will be discussed in the “bioenergy” course in the BioSUCCEED series.
9Bioethanol Ethanol-producing corn plants in the The second simplest alcohol on the planet (C2H6OH); also known as grain alcohol (primary origin) as opposed to methanol, simplest alcohol (wood alcohol)Ethanol or ethyl alcohol as we have known it for thousands of glorious, fun-filled years!It has within the last 10 years been mandated as a fuel additive to replace MTBEs (methyl tertiary butyl ether, an oxygenation chemical) to continue clean burning of fuel and thus improve air qualityIt currently supplies about 3% of our total liquid fuel needsWe consider solar, wind, ocean currents, geothermals, nuclear, and others are alternative energy sources not to be confused as bioenergyEthanol-producing corn plants in theMidwest of the USA (the bread basket).Space filling molecular model of ethanol; black = carbon atoms, white = hydrogen atoms, and red = oxygen atomA methanol economy was proposed several years ago: Beyond Oil and Gas: The Methanol Economy , George A. Olah, Angewandte Chemie International Edition Volume 44, Issue 18, Pages , 2005; If you cannot access this article, please write us at and we will be glad to send it to you free of charge.The oldest organic reaction is probably the fermentation of sugar into ethanol.
10BiodieselAnother incredibly useful form of liquid fuelHowever, it is a vegetable oil and fatty acid product (an ester)Made from the transesterification of vegetable oil using an alcohol such as methanol (most common): the three fatty acids on the glycerol residue are esterified to 3 molecules of methanol leaving behind glycerin (a tri-alcohol)Prof. Chavanne of Belgium invented biodiesel in 1937Generally used ast B99 blends (1% petrodiesel is added) to avoid molding of fuelQuiz M2.41. Which has a higher energy value: (a) gasoline; (b) methanol; (c) ethanol; (d) butanol 2. What common oils can make biodiesel: (a) soybean; (b) corn; (c) rapseed; (d) all of the above 3. What is an ester: (a) a female’s name; (b) an organic product also known as an ether; (c) an alcohol-fatty acid compound; (d) all of the aboveApproximate Heating Value of Common FuelsNatural Gas 1,030 Btu/cu ft 100,000 Btu/thermPropane 2,500 Btu/cu ft 92,500 Btu/galMethane 1,000 Btu/cu ftLandfill gas 500 Btu/cu ftButane 3,200 Btu/cu ft 130,000 Btu/galMethanol 57,000 Btu/galEthanol 76,000 Btu/galFuel OilKerosene 135,000 Btu/gal#2 138,500 Btu/gal#4 145,000 Btu/gal#6 153,000 Btu/galWaste oil 125,000 Btu/galBiodiesel – Waste vegetable oil 120,000 Btu/galGasoline 125,000 Btu/galWoodSoftwood 2-3,000 lb/cord 10–15,000,000 Btu/cordHardwood 4-5,000 lb/cord 18–24,000,000 Btu/cordSawdust – green lb/cu ft 8-10,000,000 Btu/tonSawdust – kiln dry 8-10 lb/cu ft 14-18,000,000 Btu/tonChips – 45% moisture lb/cu ft 7,600,000 Btu/tonHogged lb/cu ft 16-20,000,000 Btu/tonBark lb/cu ft 9-10,500,000 Btu/tonWood pellets – 10% moisture lb/cu ft 16,000,000 Btu/tonHard Coal (anthracite) 13,000 Btu/lb 26,000,000 Btu/tonSoft Coal (bituminous) 12,000 Btu/lb 24,000,000 Btu/tonRubber – pelletized 16,000 Btu/lb 32-34,000,000 Btu/tonPlastic 18-20,000 Btu/lbCorn – shelled 7,800-8,500 Btu/lb 15-17,000,000 Btu/toncobs 8,000-8,300 Btu/lb 16-17,000,000 Btu/tonElectricity 3412 Btu/kilowatt hourPrepared by:John W. Bartok, Jr., Agricultural EngineerUniversity of Connecticut, Storrs CTDecember 2004
11What are the uses of biomass? Housing/ShelterFoodClothingPlastics/CompositesDrugs/MedicinesBooks/MediaCarbon sequestrationCarbon creditsUsing biomass to achieve a carbon balance The combustion (direct or indirect) of biomass as a fuel also returns CO2 to the atmosphere. However this carbon is part of the current carbon cycle: it was absorbed during the growth of the plant over the previous few months or years and, provided the land continues to support growing plant material, a sustainable balance is maintained between carbon emitted and absorbed.(a) As trees in the energy plantation grow, they absorb carbon dioxide from the atmosphere.(b) During photosynthesis the trees store carbon in their woody tissue and oxygen is released back to the atmosphere.(c) At harvest, woodfuel is transported from the plantation to the heat or power generating plant.(d) As the wood is burned at the heat or power generating plant the carbon stored in the woody tissue combines with oxygen to produce carbon dioxide, this is emitted back to the atmosphere in the exhaust gases. Permission to reproduce obtained from
12Examples of biomaterials TypicalRenewable-basedDental implantsArtificial jointMammary gland implantsArtificial skinFalse eyeProsthetic jointCadaver implantWood & associated biopolymersPlants & extractivesForest residuesModified wood/agro- biopolymersRenewable natural material for specific function
13Photosynthesis Biomass 1g fixedabsorbedR = CHO Chlorophyll aR = CH3 Chlorophyll b
14CO2 Emissions One Driver for New Economy Mark A. Paisley, “Biomass Energy”, Kirk-Othmer Encyclopedia of Chemical Technology, John Wiley & Sons, Inc. (2002)
15Alternate Feedstock: Biomass Biomass: Organic matter available on a renewable basis.Advantages:Naturally abundantSustainableReduce dependence on petroleumProductive use of wastesLower emissionsGrowth in rural communities
16The Composition of Biomass Starch (Glucose)Lignocellulosic BiomassOils and Proteins
19Lignin Biosynthesis II Anselme Payen 1838: Reacts wood with nitric acid and then sodium hydroxide. Remaining material he names Cellulose.Schulze 1857: Names dissolved material Lignin from the latin lignum meaning wood.Phenolic Polymer - The Glue that Holds the Fibers Together3 Dimensional Crolinked NetworkBranched Polymer/Polydisperse (Large and Small Polymers)Lignin Biosynthesis II
20Hemicelluloses Gymnosperm hemicelluloses Approximately 20% of the total carbohydrate contentAlternating Glucose & Mannose along the main chain; Galactose branches off; Random acetates at C5 & C3 of main chainGalactoglucomannansSoftwood Hemicelluloses (major)The principle hemicellulose of softwoods is the galactoglucomannans (~ 20% of woody material)They are subdivided as :High Galactose content:Galactose 1/Glucose 1/Mannose/4Low Galactose contentGalactose 0.1/Glucose 1/Mannose/3
21Chitin 2nd most plentiful polysaccharide on earth Can form chitosan Usually not fully deacetylated.Deactylation value has striking effect upon solubility and crystallinityCan form cationic site (as ammonium salt)Rare in natureThis is the “acetyl” group (CH3C=O) thatcharacterizes chitin; once removed, it makeschitosan, the de-acetylated by-product