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Chemical Bonding. Chemical Bonding is the mutual electrical attraction between the nuclei and valence electrons of different atoms that binds the atoms.

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Presentation on theme: "Chemical Bonding. Chemical Bonding is the mutual electrical attraction between the nuclei and valence electrons of different atoms that binds the atoms."— Presentation transcript:

1 Chemical Bonding

2 Chemical Bonding is the mutual electrical attraction between the nuclei and valence electrons of different atoms that binds the atoms together.

3 chemical formula. The composition of a formula is given by its chemical formula. A chemical formula indicates the relative number of atoms combined using atomic symbols and numeric subscripts H 2 O, C 6 H 12 O 8, FeCl 3, CaS, Li 3 P

4 Diatomic molecules Di = two Atomic = atoms two atoms Diatomic molecules contain only two atoms. F2F2F2F2 H2H2H2H2NaCl

5 Learn the following diatomic elements F 2 Cl 2 Br 2 I 2 At 2 H 2 O 2 N 2 HalHON All the hologens plus Hydrogen, Oxygen and Nitrogen

6 Lewis Structures Lewis Structures only show the valence electrons. Write the element symbol C

7 Lewis Structures Place one dot to the right of the symbol C

8 Lewis Structures Then add the next electron below the symbol C

9 Lewis Structures The next electron goes to the left C C

10 Lewis Structures Continue moving around the symbol until all electrons have been added. N N

11 Lewis Structures Using electron dot diagrams, a diatomic molecule of hydrogen can be represented as H B period ¼ H

12 Write the Lewis Structures for the following elements Li BeB C NOF Ne

13 Lewis Structures are useful in seeing where an atom is willing to make a bond Atoms can not bond when electrons are paired

14 Helium has full shell with two electrons So it is written He:

15 N has 5 valence electrons N: N: It can only bond in three spots

16 Chemical Bonding There are several types of bonds – IonicCovalentMetallic

17 Covalent bonds Covalent bonds are when nonmetallic elements share an electron pair. Nm + Nm

18 This can be two hydrogen atoms, H 2 or many different elements such as in sucrose (C 6 H 12 O 6 )

19 Molecular compound Molecular compound is the simplest unit for molecules. Remember that only the valance electron are involved in bonding. A molecule is a neutral group of atoms that are held together by covalent bonds. Atoms share electrons

20 Covalent bonds are when nonmetallic elements share an electron pair. Nm + Nm 1s2s 2p F. F F This is the octet rule for covalent bonding. This is the octet rule for covalent bonding.

21 There are several types of covalent bonds. PolarNonpolarCoordinate They tell how well elements share electrons

22 Polar Covalent is a covalent bond that does not share the electrons equally. One side is slightly + and the other is slightly – Because there are two poles of charge involve, the bond is a dipole. H O

23 A dipole caused by the polar covalent bond of the water molecule

24 Nonpolar Covalent is a covalent bond where the electrons are evenly shared. F F

25 Electronegativity! So how do we know what type of bond we have? Electronegativity!Covalent Nonpolar Polar Ionic Nonpolar Polar Ionic E % E %

26 Use the electronegative difference to determine the bond type. The electronegativity can be found on the periodic table Sulfur and Hydrogen Sulfurs electronegativity is 2.5 Hydrogens electronegativity is 2.1 S – H = = 0.4 Where does it fall? Polar covalent

27 Which element is least negative? H So it is written first in the formula

28 Try some more F 2 or F – F, SF 4, LiF Compound F2F2F2F2 SF 4 LiF Electronegativity Difference Type of Bond

29 The HF (Hydrofluoric) can be written: H – F H F The ' +' and ' -' symbols indicate partial positive and negative charges.

30 Coordinate covalent bond is a bond formed when one atom provides both electrons in a shared pair. HNH H

31 How do we know if a double or triple bond in needed? Using the equations to correctly draw the Lewis Structure and Structural Formula for each of the following. All Single Bonds 6(N) + 2 = VE N= number of atoms (not counting H) VE = # of valence electrons

32 p+ e - p+ e - No interaction between atoms

33 p+ e - p+ e - Attraction begins

34 CovalentCovalent bond forms p+ p+ e -

35 Network Solids "Covalent Crystals" (crystal is used to describe Ionic structures) (Diamonds) –Hard –Good insulators –Transparent –High Melting Point

36 Properties of Covalent Compounds These are poor conductors of electricity in the fused or dissolved state Nonelectrolytes-do not conduct electricity in water Poor conductors of heat and electricity Brittle or cleave rather than deform

37 Covalent Compounds Exist as neutral molecules (C 6 H 12 O 2 ) Solids, liquids, or gases (C 6 H 12 O 2 (s), H 2 O(l), CO 2 (g)) Lower melting and boiling points (i.e., often exist as a liquid or gas at room temperature)

38 Covalent Compounds Relatively weak force of attraction between molecules Remain as same molecule in water and will not conduct electricity H 2 O(l), C 6 H 12 O 2 (s) C 6 H 12 O 2 (aq)

39 Naming Covalent Compounds All covalent compounds have two word names. The first word is the first element in the formula and the second corresponds to the second element in the formula except that "-ide" is substituted for the end. All covalent compounds have two word names. The first word is the first element in the formula and the second corresponds to the second element in the formula except that "-ide" is substituted for the end.

40 Rules for Naming Binary Covalent Compounds Rule 1 A binary covalent compound is composed of two different nonmetal elements. For example, a molecule of chlorine trifluoride, ClF 3 contains 1 atom of chlorine and 3 atoms of fluorine.

41 Rules for Naming Binary Covalent Compounds Rule 2. The second element in the name is named as if it were an anion, i.e., by adding the suffix -ide to the name of the element.

42 Rules for Naming Binary Covalent Compounds Rule 3. If both elements are in the same group, the element with the bigger period number is written first in the name. So, BrF is named bromine fluoride", because bromine is the first element and fluorine is the second element.

43 Rules for Naming Binary Covalent Compounds Rule 4. Greek prefixes are used to indicate the number of atoms of each nonmetal element in the chemical formula for the compound. Exception: The only time mono is used is with oxygen

44 Naming Covalent Compounds If there is more than one atom of an element in a molecule, we need to add prefixes to these words to tell us how many are present. Here are the prefixes you'll need to remember:

45 Prefixes for Covalent Number of atoms Prefix 1 mono- (use only for oxygen) 2di- 3tri- 4tetra- 5penta- 6hexa- 7hepta- 8octa- 9Nona- 10Deca-

46 Naming Practice SH SH 2 P 2 S 3 C 4 F 10 NO sulfur dihydride diphosphorous trisulfide tetracarbon decafluoride nitrogen monoxide

47 Some important exceptions To the naming scheme occur because the compounds were originally named before the methodical naming scheme above became widespread. Nowadays, these names are so common that they're officially recognized: H 2 O is "water" NH 3 is "ammonia" CH 4 is "methane"


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