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SAMPLE EXERCISE 21.1 Predicting the Product of a Nuclear Reaction What product is formed when radium-226 undergoes alpha decay? Solution Analyze: We are asked to determine the nucleus that results when radium-226 loses an alpha particle. Plan: We can best do this by writing a balanced nuclear reaction for the process. where A is the mass number of the product nucleus and Z is its atomic number. Mass numbers and atomic numbers must balance, so and Hence, Again, from the periodic table, the element with Z = 86 is radon (Rn). The product, therefore, is and the nuclear equation is Solve: The periodic table or a list of elements shows that radium has an atomic number of 88. The complete chemical symbol for radium-226 is therefore An alpha particle is a helium-4 nucleus, and so its symbol is (sometimes written as ). The alpha particle is a product of the nuclear reaction, and so the equation is of the form

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SAMPLE EXERCISE 21.1 continued PRACTICE EXERCISE Which element undergoes alpha decay to form lead-208? Answer:

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SAMPLE EXERCISE 21.2 Writing Nuclear Equations Write nuclear equations for the following processes: (a) mercury-201 undergoes electron capture; (b) thorium- 231 decays to form protactinium-231. Solution Analyze: We must write balanced nuclear equations in which the masses and charges of reactants and products are equal. Plan: We can begin by writing the complete chemical symbols for the nuclei and decay particles that are given in the problem. Solve: (a) The information given in the question can be summarized as The mass numbers must have the same sum on both sides of the equation: Thus, the product nucleus must have a mass number of 201. Similarly, balancing the atomic numbers gives Thus, the atomic number of the product nucleus must be 79, which identifies it as gold (Au): (b) In this case we must determine what type of particle is emitted in the course of the radioactive decay:

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SAMPLE EXERCISE 21.2 continued From 231 = A and 90 = 91 + Z, we deduce A = 0 and Z = –1. According to Table 21.2, the particle with these characteristics is the beta particle (electron). We therefore write PRACTICE EXERCISE Write a balanced nuclear equation for the reaction in which oxygen-15 undergoes positron emission. Answer:

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SAMPLE EXERCISE 21.3 Predicting Modes of Nuclear Decay Predict the mode of decay of (a) carbon-14, (b) xenon-118. This is indeed the mode of decay observed for carbon-14. Solution Analyze: We are asked to predict the modes of decay of two nuclei. Plan: To do this, we must calculate the neutron-to-proton ratios and compare the values with those for nuclei that lie within the belt of stability shown in Figure In this case both modes of decay are observed. Solve: (a) Carbon has an atomic number of 6. Thus, carbon-14 has 6 protons and 14 –6 = 8 neutrons, giving it a neutron-to-proton ratio of Elements with low atomic numbers normally have stable nuclei with approximately equal numbers of neutrons and protons. Thus, carbon-14 has a high neutron-to-proton ratio, and we expect that it will decay by emitting a beta particle: (b) Xenon has an atomic number of 54. Thus, xenon-118 has 54 protons and 118 – 54 = 64 neutrons, giving it a neutron-to-proton ratio of According to Figure 21.2, stable nuclei in this region of the belt of stability have higher neutron-to-proton ratios than xenon-118. The nucleus can increase this ratio by either positron emission or electron capture:

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SAMPLE EXERCISE 21.3 continued Answer: (a) decay, (b) decay PRACTICE EXERCISE Predict the mode of decay of (a) plutonium-239, (b) indium-120. Comment: Keep in mind that our guidelines dont always work. For example, thorium-233, which we might expect to undergo alpha decay, actually undergoes beta decay. Furthermore, a few radioactive nuclei actually lie within the belt of stability. Both for example, are stable and lie in the belt of stability. however, which lies between them, is radioactive.

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SAMPLE EXERCISE 21.4 Predicting Nuclear Stability Solution Analyze: We are asked to identify especially stable nuclei, given their mass numbers and atomic numbers. Plan: We look to see whether the numbers of protons and neutrons correspond to magic numbers. Which of the following nuclei are especially stable: Solve: The nucleus (the alpha particle) has a magic number of both protons (2) and neutrons (2) and is very stable. The nucleus also has a magic number of both protons (20) and neutrons (20) and is especially stable. The nucleus does not have a magic number of either protons or neutrons. In fact, it has an odd number of both protons (43) and neutrons (55). There are very few stable nuclei with odd numbers of both protons and neutrons. Indeed, technetium-98 is radioactive. PRACTICE EXERCISE Which of the following nuclei would you expect to exhibit a special stability:

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SAMPLE EXERCISE 21.5 Writing a Balanced Nuclear Equation Solution Analyze: We must go from the condensed descriptive form of the nuclear reaction to the balanced nuclear equation. Plan: We arrive at the full nuclear equation by writing n and each with its associated subscripts and superscripts. Write the balanced nuclear equation for the process summarized as Solve: The n is the abbreviation for a neutron and represents an alpha particle The neutron is the bombarding particle, and the alpha particle is a product. Therefore, the nuclear equation is PRACTICE EXERCISE Using a shorthand notation, write the nuclear reaction

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SAMPLE EXERCISE 21.6 Calculation Involving Half-life The half-life of cobalt-60 is 5.3 yr. How much of a mg sample of cobalt-60 is left after a 15.9-yr period? Solve: A period of 15.9 yr is three half-lives for cobalt-60. At the end of one half-life, mg of cobalt-60 remains, mg at the end of two half-lives, and mg at the end of three half-lives. PRACTICE EXERCISE Carbon-11, used in medical imaging, has a half-life of 20.4 min. The carbon-11 nuclides are formed and the carbon atoms are then incorporated into an appropriate compound. The resulting sample is injected into a patient, and the medical image is obtained. If the entire process takes five half-lives, what percentage of the original carbon-11 remains at this time? Answer: 3.12% Solution Analyze: We are given the half-life for cobalt-60 and asked to calculate the amount of cobalt-60 remaining from an initial mg sample after a 15.9-yr period. Plan: We can proceed by utilizing the fact that the half-life characteristic of a first-order decay process is a constant.

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SAMPLE EXERCISE 21.7 Calculating the Age of a Mineral A rock contains mg of lead-206 for every milligram of uranium-238. The half-life for the decay of uranium-238 to lead-206 is yr. How old is the rock? Solution Analyze: Were told that a rock sample has a certain amount of lead-206 for every unit weight of uranium- 238 and asked to estimate the age of the rock. Plan: Presumably the lead-206 is due entirely to radioactive decay of uranium-228 to form lead-206, with a known half-life. To apply first-order kinetics expressions (Equations and 21.20) to calculate the time elapsed since the rock was formed, we need first to calculate how much initial uranium-238 there was for every 1 milligram that remains today. Solve: Lets assume that the rock contains mg of uranium-238 at present. The amount of uranium- 238 in the rock when it was first formed therefore equals mg plus the quantity that decayed to lead-206. We obtain the latter quantity by multiplying the present mass of lead-206 by the ratio of the mass number of uranium to that of lead, into which it has decayed. The total original was thus Using Equation 21.20, we can calculate the decay constant for the process from its half-life:

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SAMPLE EXERCISE 21.7 continued PRACTICE EXERCISE A wooden object from an archeological site is subjected to radiocarbon dating. The activity of the sample that is due to 14 C is measured to be 11.6 disintegrations per second. The activity of a carbon sample of equal mass from fresh wood is 15.2 disintegrations per second. The half-life of 14 C is 5715 yr. What is the age of the archeological sample? Rearranging Equation to solve for time, t, and substituting known quantities gives Answer: 2230 yr

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SAMPLE EXERCISE 21.8 Calculations Involving Radioactive Decay If we start with g of strontium-90, g will remain after 2.00 yr. (a) What is the half-life of strontium- 90? (b) How much strontium-90 will remain after 5.00 yr? (c) What is the initial activity of the sample in Bq and in Ci? Solution (a) Analyze: We are asked to calculate a half-life, t 1/2, based on data that tell us how much of a radioactive nucleus has decayed in a given period of time and (N 0 = g, N t = g, and t = 2.00 yr). Plan: We first calculate the rate constant for the decay, k, then use that to compute t 1/2. (b) Analyze: We are asked to calculate the amount of a radionuclide remaining after a given period of time. Plan: We need to calculate the amount of strontium at time t, N t, using the initial quantity, N 0, and the rate constant for decay, k, calculated in part (a). Solve: Equation is solved for the decay constant, k, and then Equation is used to calculate half- life, t 1/2 :

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SAMPLE EXERCISE 21.8 continued (c) Analyze: We are asked to calculate the activity of the sample in becquerels and curies. Plan: We must calculate the number of disintegrations per second per atom, then multiply by the number of atoms in the sample. Solve: Again using Equation 21.19, with k = yr –1, we have N t /N 0 is calculated from ln(N t /N 0 ) = –0.120 using the e x or INV LN function of a calculator: Because N 0 = g, we have Solve: The number of disintegrations per atom per second is given by the rate constant, k.

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SAMPLE EXERCISE 21.8 continued PRACTICE EXERCISE A sample to be used for medical imaging is labeled with 18 F, which has a half-life of 110 min. What percentage of the original activity in the sample remains after 300 min? To obtain the total number of disintegrations per second, we calculate the number of atoms in the sample. We multiply this quantity by k, where we express k as the number of disintegrations per atom per second, to obtain the number of disintegrations per second: Because a Bq is one disintegration per second, the activity is just Bq. The activity in Ci is given by Answer: 15.1% We have used only two significant figures in products of these calculations because we dont know the atomic weight of 90 S to more than two significant figures without looking it up in a special source.

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SAMPLE EXERCISE 21.9 Calculating Mass Change in a Nuclear Reaction Solution Analyze: We are asked to calculate the energy change in a nuclear reaction. Plan: We must first calculate the mass change in the process. We are given atomic masses, but we need the masses of the nuclei in the reaction. We calculate these by taking account of the masses of the electrons that contribute to the atomic masses. Solve: A atom has 27 electrons. The mass of an electron is –4 amu. (See the list of fundamental constants in the back inside cover). We subtract the mass of the 27 electrons from the mass of the atom to find the mass of the nucleus: Likewise, for the mass of the nucleus is The mass change in the nuclear reaction is the total mass of the products minus the mass of the reactant: Thus, when a mole of cobalt-60 decays, How much energy is lost or gained when a mole of cobalt-60 undergoes beta decay: The mass of the atom is amu, and that of a atom is amu.

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SAMPLE EXERCISE 21.9 continued Answer: – –3 g PRACTICE EXERCISE Positron emission from occurs with release of J per mole of 11 C. What is the mass change per mole of 11 C in this nuclear reaction? Because the mass decreases ( m < 0), energy is released ( E < 0). The quantity of energy released per mole of cobalt-60 is calculated using Equation 21.22:

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SAMPLE EXERCISE Writing Nuclear Equations Write the nuclear equations for the formation of 239 Pu from 238 U. Solution Analyze: We are asked to write the nuclear equations for the nuclear reactions leading to formation of 239 Pu from 238 U. Plan: We know from the previous discussion that the formation of 239 Pu from 238 U involves absorption of a neutron by 238 U, followed by two successive beta emissions. Comment: We can check our equations for balance in both charge and mass. Solve: Beta emission from a U nuclide increases the nuclear charge by one. Thus, it yields a Np nuclide. Beta emission from an Np nuclide in turn will yield a Pu nuclide. The three nuclear reactions are PRACTICE EXERCISE Write the balanced nuclear equation for formation of

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SAMPLE INTEGRATIVE EXERCISE Putting Concepts Together Potassium ion is present in foods and is an essential nutrient in the human body. One of the naturally occurring isotopes of potassium, potassium-40, is radioactive. Potassium-40 has a natural abundance of % and a half-life of t 1/2 = yr. It undergoes radioactive decay in three ways: 98.2% is by electron capture, 1.35% is by beta emission, and 0.49% is by positron emission. (a) Why should we expect 40 K to be radioactive? (b) Write the nuclear equations for the three modes by which 40 K decays. (c) How many 40 K + ions are present in 1.00 g of KCl? (d) How long does it take for 1.00% of the 40 K in a sample to undergo radioactive decay? Solution (a) The 40 K nucleus contains 19 protons and 21 neutrons. There are very few stable nuclei with odd numbers of both protons and neutrons. (Section 21.2) (b) Electron capture is capture of an inner-shell electron by the nucleus: Beta emission is loss of a beta particle by the nucleus: Positron emission is loss of by the nucleus: (c) The total number of K + ions in the sample is

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SAMPLE INTEGRATIVE EXERCISE continued That is, it would take 18.6 million years for just 1.00% of the 40 K in a sample to decay. (d) The decay constant (the rate constant) for the radioactive decay can be calculated from the half-life, using Equation 21.20: The rate equation, Equation 21.19, then allows us to calculate the time required: Of these, % are 40 K + ions:

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Fig 21.2 BACK Figure 21.2 The belt of stability. The number of neutrons is graphed versus the number of protons for stable nuclei. As the atomic number increases, the neutron-to- proton ratio of the stable nuclei increases. The stable nuclei are located in the shaded area of the graph known as the belt of stability. The majority of radioactive nuclei occur outside this belt.

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Table 21.2 BACK

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