Presentation on theme: "Atoms, Molecules and Ions"— Presentation transcript:
1Atoms, Molecules and Ions Chemistry Chapter 2Atoms, Molecules and Ions
2Dalton’s Atomic Theory Lavosier laid down many of the foundations of modern chemistry.John Dalton gave us the basic theory that all matter is composed of small particles called atoms.
3Dalton’s Atomic Theory The Postulates of Dalton’s Theory:1. All matter is composed of indivisible atoms.*2. An element is a type of matter composed of only 1 type of atom. Each atom of a given element has a characteristic mass.*recall we know that atoms can be broken down into p+, n0, and e-.
4Dalton’s Atomic Theory The Postulates of Dalton’s Theory:3. A compound is a type of matter composed of atoms of 2 or more elements chemically combined in fixed proportions. The relative numbers of any 2 kinds of atoms occur in simple ratios.4. A chemical reaction is a rearrangement of atoms in reacting substances yielding new products formed as a result of the reaction.
5Dalton’s Atomic Theory Atomic theory explains the difference between an element and a compound and provides some insight into 2 laws considered in Chapter 1:The Law of Conservation of MassThe Law of Definite Proportions (the proportions of elements in a compound are always the same).
6Law of Conservation of Mass By Postulates 2 and 4…By postulate 2, every atom has mass, and by postulate 4 chemical reactions only rearrange atoms, therefore mass must be conserved.
7Law of Definite Proportions By Postulate 3, a compound is a type of matter containing atoms of 2 or more elements in definite proportions.
9TheoriesGood theories explain observations (facts & laws) and make predictions about new laws.Thus Dalton observed the law of multiple proportions while thinking about his atomic theory.This was an important step in convincing skeptics about the validity of his atomic theory.
10The Law of Multiple Proportions When two elements, A and B combine to form more than one compound, the masses of A and B will combine in simple ratios.Consider CO2 and CO:In one, 12g of C will combine with 16g of O to give CO.In the other, 12g of C will combine with 32g of O to give CO2.The oxygen masses combining with a fixed mass of carbon are in the ratio of 16:32, or 1:2.
11How Atomic Theory Fits In… By applying atomic theory and using the calculated ratios, we can assume the compound having 16g of oxygen per 12g of carbon is CO, and the one having 32g of oxygen per 12g of carbon is CO2.
12The Nucleus of an AtomContains most of the mass (p+ and n0) and is surrounded by the e-.
13J.J. ThompsonJ.J. Thompson discovered the electron in 1897 using a cathode ray tube (CRT).A CRT is a sealed vacuum tube with an anode at one end and a cathode at the other. A high voltage source is hooked up to each end and the glass tube emits a green light.
14The CRT Continued…Correct setup of the tube allows some of the rays to pass through a hole at one end forming a beam.Beyond the hole are positively and negatively charged plates. The cathode rays bend away from the -ve plate and toward the +ve plate and can be influenced by a magnet revealing their charge.
17Earnst RutherfordIn 1911, Rutherford proposed a nuclear model of the atom.He used data from his gold foil experiment to demonstrate this and to hypothesize that the atom was comprised mostly of empty space (i.e., the nucleus was very small).
18The Gold Foil Experiment What Rutherford and others did was fire -particles at metal foils and used a detector to show that about 7999/8000 passed directly through the foil.The 1/8000 that didn’t get through were deflected at large angles.
20The AtomThe atomic number of an atom is the number of p+ in the atom, and is the nuclear charge on that atom.The mass number of an atom is the number of p+ + the number of n0 in the atom.
21IsotopesIsotopes are atoms of the same element with a different number of n0. They behave the same as any other atom in a chemical reaction and are used as tracers.These give us the decimals associated with the atomic masses.
22IsotopesWhen we work with elements, we are working with a mixture of isotopes.To determine the masses of each of the elements, a scale was devised based on the carbon-12 isotope. Carbon-12 was assigned a mass of exactly 12 amu.A mass spectrometer is used to compare the mass of an atom to that of a C-12 atom.
23Atomic Mass UnitsOne amu is a mass unit equal to 1/12 of the mass of a carbon-12 atom.With our new scale, the atomic masses are represented on the periodic table as an average atomic mass for naturally occurring elements.
24Determining Masses of Elements We look at the fractional abundance.
25Dimitri Mendeleev & Julius Lothar Meyer These 2 men independently discovered that elements have similar properties and can be arranged into a table.The only error these two made was that they arranged the elements by atomic masses.
27Henry MoselyEventually, Henry Mosely discovered that the ordering of the atoms by mass created some problems. He found that when he rearranged them by atomic number he was able to eliminate these problems.
28Periods and Groups Periods are horizontal rows. Groups, columns, and families are what we call the vertical columns.
29Numbering the ColumnsIn North America, we number the columns using Roman Numerals & A’s and B’s.In Europe, Roman Numerals are often used but some of the A’s and B’s get switched.The IUPAC recommends numbering them 1-18 to eliminate the confusion.
30Our Book Our book uses the traditional North American convention. A groups are the “main group,” or “representative” elements.B group elements are “transition elements.”The 2 rows at the bottom are the Lanthanides and the Actinides. Collectively these are referred to as the Inner Transition elements.
31Metals, Nonmetals, and Metalloids Metals are good conductors and have shine and luster.Nonmetals are gases or brittle solids.Metalloids are substances with characteristics of both metals and nonmetals.
32Chemical FormulasChemical formulas use atomic symbols to represent the elements in a compound.NaCl-sodium chloride, no subscripts.Al2O3-2 aluminums and 3 oxygensMolecular formulas give the numbers of different atoms in a given element in a compound-H2O.Structural formulas show how atoms are bonded together to form a molecule.
33Some Vocabulary Monomers vs. polymers Ions, anions, cations Ionic vs. covalent compounds
34Ionic SubstancesIonic substances don’t contain molecules, thus we have to speak of the smallest unit of a substance-the formula unit; NaCl for example.We also use a formula unit to describe the formulas of other compounds-ionic or not-e.g., H2O.
35Electrically NeutralAll substances are electrically neutral, and we can use this fact to obtain the ionic charge on the chemical formula from the ionic charges of the ions.Al2O3 --> Al3+ O2-2(3+) 3(2-)= 0
36Organic CompoundsOrganic compounds are ones which contain carbon, oxygen, and hydrogen.Historically, organic compounds were though to only arise via a “vital force.”
37Frederick WöhlerIn 1828, Wöhler disproved the notion of “vital force” when he synthesized urea from ammonia and cyanic acid.The vitalists did not buy this claim after they discovered that the cyanic acid was produced from animal blood.
38Mechanism Vs. VitalismThe debate about such a “vital force” raged on for a few more years until it was discovered that organic compounds could be synthesized from substances strictly made in the laboratory.Herman Kolbe synthesized acetic acid from inorganic substances obtained from pure elements.
39Inorganic CompoundsInorganic compounds are composed of elements other than carbon.Some substances such as CO2, CO, CN, and CaCO3 are considered to be inorganic because they don’t contain hydrogen.
40Naming Compounds There is a process for naming compounds. To name an ionic compound, give the name of the cation first, then give the name of the anion.NaClNa+ = SodiumCl- = ChlorineName = Sodium Chloride
41Predicting Charges on Monoatomic Ions 1. Most main group metallics have one monoatomic cation with a charge equal to the group number:Al, Group IIIA (13), Al3+
42Predicting Charges on Monoatomic Ions 2. Some metallic ions in elements with a high atomic number “break” the previous rule--they have more than one cation. They have a common cation with a charge equal to the group number minus 2, (In addition, they have a cation with a charge equal to the group number):Pb, Group IVA (14), Pb2+, Pb4+
43Predicting Charges on Monoatomic Ions 3. Most transition elements form more than one monoatomic cation, and most have one ion with a charge of +2.Fe2+, Fe3+
44Predicting Charges on Monoatomic Ions 4. The charge on a monoatomic anion for a nonmetallic main group element is the group number minus 8:O, Group VIA, O2-
45Rules for Naming Monoatomic Ions 1. Monoatomic cations are named after the element if there is only one such ion.Al3+ = aluminum ionNa+ = sodium ion
46Rules for Naming Monoatomic Ions 2. If there is more than one monoatomic cation, the “stock system” is used which names the cation after the element followed by a Roman Numeral to indicate the charge.Fe2+ = iron(II)Fe3+ = iron(III)
47Rules for Naming Monoatomic Ions In an older system* of nomenclature, -ous and -ic are added to the stem name of the element.-ous indicates the atom with the lower charge.e.g., Cu+ = cuprous-ic indicates the atom with a higher charge.e.g., Cu2+ = cupric*Often with this system, the Latin name of the element is involved.
48Rules for Naming Monoatomic Ions Monoatomic anions are named using the stem name of the element followed by -ide.Br- = bromideCl- = chloride
49Rules for Naming Polyatomic Ions Polyatomic ions are ions with more than one element chemically bonded and contains a charge.NH4+ = ammonium ionThere are no simple rules for writing polyatomics. Often there is a central element associated with oxygen called an oxoanion.ClO2-, for example
50Rules for Naming Polyatomic Ions Usually the oxoanions have the name of the characteristic element with the suffix -ate or -ite.The oxoanion with the greater number of oxygens = -ate.The one with the lesser number of oxygens is -ite.NO3- = nitrate ionNO2- = nitrite ion
51Rules for Naming Polyatomic Ions When there are more than 2 oxoanions, the prefixes hypo- and per- are used.A classic example:Hypo-ClO-hypochloriteClO2--itechloriteClO3--atechloratePer-ClO4-perchlorate
52Binary Compounds Binary compounds are composed of only 2 elements. When composed of a metal and a nonmetal, these compounds are usually ionic and are named as such.NaCl, KCl, MgCl2
53Binary CompoundsThose binary compounds comprised of 2 nonmetals or a nonmetal and a metalloid are named using prefixes.H2O, CO2, CO
54Rules for Naming Binary Molecular Compounds 1. The compound name usually has the elements in the order given in the formula.2. Name the 1st element using the exact element name.
55Rules for Naming Binary Molecular Compounds 3. Write the second element’s prefix with the suffix -ide.4. If there is more than one element, add the Greek prefix to the stem of each element. In general, mono- isn’t used on the 1st element in the compound.
57AcidsIn general (for now) an acid is a compound that donates a H+ in solution along with an anion.HNO3 ↔ H+ + NO3-HCl ↔ H+ + Cl-HNO3 is an oxyacid--an acid containing H, O, and a central atom.
58AcidsThe name of the oxoacid is easy. They are related to the name of the oxoanion.By knowing the name of the oxoanion, drop the-ate and add -ic-ite and add -ousHNO3 nitric acidH+ NO3- nitrite → nitricHNO2 nitrous acidH+ NO2- nitrite → nitrous
59AcidsA small number of binary compounds containing hydrogen and a nonmetal give an acid solution when dissolved in water.To name these solutions, add the prefix hydro- and add the suffix -ic to the nonmetal followed by the word acid.
60Acids The solution of the formula is denoted with an (aq). HCl (aq) H+ Cl-ChlorHydro- chlor -ic + acidHydrochloric acid
61Hydrates Hydrates contain water molecules weakly bound in crystals. Name them by naming the compound, adding a Greek prefix to the word hydrate.CuSO4 • 5H2O (the “•” indicates hydrate)Copper(II) Sulfate pentahydrate
62Atom RearrangementRecall one of the aspects of Dalton’s atomic theory is that it explains a chemical reaction as a rearrangement of the atoms of the reacting substances in the formation of new compounds.A chemical equation is a representation of this reaction:2Na(s) + Cl2(g) → 2NaCl(s)reactants ↑ products“yields”
64Balancing EquationsIt is important that we balance chemcial equations because according to the law of conservation of mass, we cannot creat nor destroy matter, we can only change its form.2H2(g) + O2(g) → 2H2O(l)To balance these equations, you must choose coefficients that make the numbers of atoms on each side of the equation equal.