Presentation on theme: "Chemistry Chapter 2 Atoms, Molecules and Ions. Daltons Atomic Theory Lavosier laid down many of the foundations of modern chemistry. John Dalton gave."— Presentation transcript:
Chemistry Chapter 2 Atoms, Molecules and Ions
Daltons Atomic Theory Lavosier laid down many of the foundations of modern chemistry. John Dalton gave us the basic theory that all matter is composed of small particles called atoms.
Daltons Atomic Theory The Postulates of Daltons Theory: –1. All matter is composed of indivisible atoms.* –2. An element is a type of matter composed of only 1 type of atom. Each atom of a given element has a characteristic mass. *recall we know that atoms can be broken down into p +, n 0, and e -.
Daltons Atomic Theory The Postulates of Daltons Theory: –3. A compound is a type of matter composed of atoms of 2 or more elements chemically combined in fixed proportions. The relative numbers of any 2 kinds of atoms occur in simple ratios. –4. A chemical reaction is a rearrangement of atoms in reacting substances yielding new products formed as a result of the reaction.
Daltons Atomic Theory Atomic theory explains the difference between an element and a compound and provides some insight into 2 laws considered in Chapter 1: –The Law of Conservation of Mass –The Law of Definite Proportions (the proportions of elements in a compound are always the same).
Law of Conservation of Mass By Postulates 2 and 4… –By postulate 2, every atom has mass, and by postulate 4 chemical reactions only rearrange atoms, therefore mass must be conserved.
Law of Definite Proportions By Postulate 3, a compound is a type of matter containing atoms of 2 or more elements in definite proportions.
Theories Good theories explain observations (facts & laws) and make predictions about new laws. Thus Dalton observed the law of multiple proportions while thinking about his atomic theory. This was an important step in convincing skeptics about the validity of his atomic theory.
The Law of Multiple Proportions When two elements, A and B combine to form more than one compound, the masses of A and B will combine in simple ratios. Consider CO 2 and CO: –In one, 12g of C will combine with 16g of O to give CO. –In the other, 12g of C will combine with 32g of O to give CO 2. The oxygen masses combining with a fixed mass of carbon are in the ratio of 16:32, or 1:2.
How Atomic Theory Fits In… By applying atomic theory and using the calculated ratios, we can assume the compound having 16g of oxygen per 12g of carbon is CO, and the one having 32g of oxygen per 12g of carbon is CO 2.
The Nucleus of an Atom Contains most of the mass (p + and n 0 ) and is surrounded by the e -.
J.J. Thompson J.J. Thompson discovered the electron in 1897 using a cathode ray tube (CRT). A CRT is a sealed vacuum tube with an anode at one end and a cathode at the other. A high voltage source is hooked up to each end and the glass tube emits a green light.
The CRT Continued… Correct setup of the tube allows some of the rays to pass through a hole at one end forming a beam. Beyond the hole are positively and negatively charged plates. The cathode rays bend away from the -ve plate and toward the +ve plate and can be influenced by a magnet revealing their charge.
Earnst Rutherford In 1911, Rutherford proposed a nuclear model of the atom. He used data from his gold foil experiment to demonstrate this and to hypothesize that the atom was comprised mostly of empty space (i.e., the nucleus was very small).
The Gold Foil Experiment What Rutherford and others did was fire -particles at metal foils and used a detector to show that about 7999/8000 passed directly through the foil. The 1/8000 that didnt get through were deflected at large angles.
The Gold Foil Experiment
The Atom The atomic number of an atom is the number of p + in the atom, and is the nuclear charge on that atom. The mass number of an atom is the number of p + + the number of n 0 in the atom.
Isotopes Isotopes are atoms of the same element with a different number of n 0. They behave the same as any other atom in a chemical reaction and are used as tracers. These give us the decimals associated with the atomic masses.
Isotopes When we work with elements, we are working with a mixture of isotopes. To determine the masses of each of the elements, a scale was devised based on the carbon-12 isotope. Carbon-12 was assigned a mass of exactly 12 amu. A mass spectrometer is used to compare the mass of an atom to that of a C-12 atom.
Atomic Mass Units One amu is a mass unit equal to 1/12 of the mass of a carbon-12 atom. With our new scale, the atomic masses are represented on the periodic table as an average atomic mass for naturally occurring elements.
Determining Masses of Elements We look at the fractional abundance.
Dimitri Mendeleev & Julius Lothar Meyer These 2 men independently discovered that elements have similar properties and can be arranged into a table. The only error these two made was that they arranged the elements by atomic masses.
Henry Mosely Eventually, Henry Mosely discovered that the ordering of the atoms by mass created some problems. He found that when he rearranged them by atomic number he was able to eliminate these problems.
Periods and Groups Periods are horizontal rows. Groups, columns, and families are what we call the vertical columns.
Numbering the Columns In North America, we number the columns using Roman Numerals & As and Bs. In Europe, Roman Numerals are often used but some of the As and Bs get switched. The IUPAC recommends numbering them 1-18 to eliminate the confusion.
Our Book Our book uses the traditional North American convention. –A groups are the main group, or representative elements. –B group elements are transition elements. The 2 rows at the bottom are the Lanthanides and the Actinides. Collectively these are referred to as the Inner Transition elements.
Metals, Nonmetals, and Metalloids Metals are good conductors and have shine and luster. Nonmetals are gases or brittle solids. Metalloids are substances with characteristics of both metals and nonmetals.
Chemical Formulas Chemical formulas use atomic symbols to represent the elements in a compound. –NaCl-sodium chloride, no subscripts. –Al 2 O 3 -2 aluminums and 3 oxygens Molecular formulas give the numbers of different atoms in a given element in a compound-H 2 O. Structural formulas show how atoms are bonded together to form a molecule.
Some Vocabulary Monomers vs. polymers Ions, anions, cations Ionic vs. covalent compounds
Ionic Substances Ionic substances dont contain molecules, thus we have to speak of the smallest unit of a substance-the formula unit; NaCl for example. We also use a formula unit to describe the formulas of other compounds-ionic or not-e.g., H 2 O.
Electrically Neutral All substances are electrically neutral, and we can use this fact to obtain the ionic charge on the chemical formula from the ionic charges of the ions. Al 2 O 3 --> Al 3+ O 2- 2(3+) 3(2-) = 0
Organic Compounds Organic compounds are ones which contain carbon, oxygen, and hydrogen. Historically, organic compounds were though to only arise via a vital force.
Frederick Wöhler In 1828, Wöhler disproved the notion of vital force when he synthesized urea from ammonia and cyanic acid. The vitalists did not buy this claim after they discovered that the cyanic acid was produced from animal blood.
Mechanism Vs. Vitalism The debate about such a vital force raged on for a few more years until it was discovered that organic compounds could be synthesized from substances strictly made in the laboratory. Herman Kolbe synthesized acetic acid from inorganic substances obtained from pure elements.
Inorganic Compounds Inorganic compounds are composed of elements other than carbon. Some substances such as CO 2, CO, CN, and CaCO 3 are considered to be inorganic because they dont contain hydrogen.
Naming Compounds There is a process for naming compounds. To name an ionic compound, give the name of the cation first, then give the name of the anion. –NaCl Na + = Sodium Cl - = Chlorine –Name = Sodium Chloride
Predicting Charges on Monoatomic Ions 1. Most main group metallics have one monoatomic cation with a charge equal to the group number: –Al, Group IIIA (13), Al 3+
Predicting Charges on Monoatomic Ions 2. Some metallic ions in elements with a high atomic number break the previous rule--they have more than one cation. They have a common cation with a charge equal to the group number minus 2, (In addition, they have a cation with a charge equal to the group number): –Pb, Group IVA (14), Pb 2+, Pb 4+
Predicting Charges on Monoatomic Ions 3. Most transition elements form more than one monoatomic cation, and most have one ion with a charge of +2. –Fe 2+, Fe 3+
Predicting Charges on Monoatomic Ions 4. The charge on a monoatomic anion for a nonmetallic main group element is the group number minus 8: –O, Group VIA, O 2-
Rules for Naming Monoatomic Ions 1. Monoatomic cations are named after the element if there is only one such ion. –Al 3+ = aluminum ion –Na + = sodium ion
Rules for Naming Monoatomic Ions 2. If there is more than one monoatomic cation, the stock system is used which names the cation after the element followed by a Roman Numeral to indicate the charge. –Fe 2+ = iron(II) –Fe 3+ = iron(III)
Rules for Naming Monoatomic Ions In an older system* of nomenclature, -ous and -ic are added to the stem name of the element. –-ous indicates the atom with the lower charge. e.g., Cu + = cuprous –-ic indicates the atom with a higher charge. e.g., Cu 2+ = cupric *Often with this system, the Latin name of the element is involved.
Rules for Naming Monoatomic Ions Monoatomic anions are named using the stem name of the element followed by -ide. –Br - = bromide –Cl - = chloride
Rules for Naming Polyatomic Ions Polyatomic ions are ions with more than one element chemically bonded and contains a charge. –NH 4 + = ammonium ion There are no simple rules for writing polyatomics. Often there is a central element associated with oxygen called an oxoanion. –ClO 2 -, for example
Usually the oxoanions have the name of the characteristic element with the suffix -ate or -ite. –The oxoanion with the greater number of oxygens = -ate. –The one with the lesser number of oxygens is -ite. NO 3 - = nitrate ion NO 2 - = nitrite ion Rules for Naming Polyatomic Ions
When there are more than 2 oxoanions, the prefixes hypo - and per- are used. A classic example: Rules for Naming Polyatomic Ions Hypo -ClO - hypochlorite ClO ite chlor ite ClO 3 - -atechlorate Per-ClO 4 - perchlorate
Binary Compounds Binary compounds are composed of only 2 elements. When composed of a metal and a nonmetal, these compounds are usually ionic and are named as such. –NaCl, KCl, MgCl 2
Binary Compounds Those binary compounds comprised of 2 nonmetals or a nonmetal and a metalloid are named using prefixes. –H 2 O, CO 2, CO
Rules for Naming Binary Molecular Compounds 1. The compound name usually has the elements in the order given in the formula. 2. Name the 1st element using the exact element name.
Rules for Naming Binary Molecular Compounds 3. Write the second elements prefix with the suffix -ide. 4. If there is more than one element, add the Greek prefix to the stem of each element. In general, mono- isnt used on the 1st element in the compound.
Rules for Naming Binary Molecular Compounds Mono-1 Di-2 Tri-3 Tetra-4 Penta-5 Hexa-6 Hepta-7 Octa-8 Nona-9 Deca-10 H 2 O = dihydrogen monoxide CO = carbon monoxide CO 2 = carbon dioxide PCl 5 = phosphorous pentachloride
Acids In general (for now) an acid is a compound that donates a H + in solution along with an anion. –HNO 3 H + + NO 3 - –HCl H + + Cl - HNO 3 is an oxyacid--an acid containing H, O, and a central atom.
Acids The name of the oxoacid is easy. They are related to the name of the oxoanion. By knowing the name of the oxoanion, drop the –-ate and add -ic –-ite and add -ous HNO 3 nitric acid H + NO 3 - nitrite nitric HNO 2 nitrous acid H + NO 2 - nitrite nitrous
Acids A small number of binary compounds containing hydrogen and a nonmetal give an acid solution when dissolved in water. To name these solutions, add the prefix hydro- and add the suffix -ic to the nonmetal followed by the word acid.
Acids The solution of the formula is denoted with an (aq). HCl (aq) H + Cl - Chlor Hydro- chlor -ic + acid Hydrochloric acid
Hydrates Hydrates contain water molecules weakly bound in crystals. Name them by naming the compound, adding a Greek prefix to the word hydrate. CuSO 4 5H 2 O (the indicates hydrate) Copper(II) Sulfate pentahydrate
Atom Rearrangement Recall one of the aspects of Daltons atomic theory is that it explains a chemical reaction as a rearrangement of the atoms of the reacting substances in the formation of new compounds. A chemical equation is a representation of this reaction: –2Na (s) + Cl 2 (g) 2NaCl (s) reactants products yields
Balancing Equations It is important that we balance chemcial equations because according to the law of conservation of mass, we cannot creat nor destroy matter, we can only change its form. –2H 2 (g) + O 2 (g) 2H 2 O (l) To balance these equations, you must choose coefficients that make the numbers of atoms on each side of the equation equal.