Presentation on theme: "Arrangement of Electrons in Atoms"— Presentation transcript:
1Arrangement of Electrons in Atoms Chemistry Ch 4Arrangement of Electrons in Atoms
2Rutherford’s Model Gold Foil Experiment Discovered the nucleus Did not explain where the electrons were in an atomWhy were they not attracted to the protons in the nucleus?
3Background Info Electromagnetic Radiation are types of energy. We describe these as waves. Only a portion of these waves are visible to us (the visible light waves).Each type of wave has different wave characteristics: frequency, wavelength, and the amount of energy it contains.
4Relationship between light and electrons The electromagnetic spectrum includes all types of electromagnetic radiation that behaves as waves.Light can behave as a wave (as in the spectrum) and as a particle of matter like a marble.Speed of all electromagnetic radiation is 3.0 X 108 m/s.
7Wave CharacteristicsWavelength (λ) -the distance between two points on a wave (measured in nm)Frequency (v) –the number of waves that pass in a given point in one secondThe speed of light (c) – is a constantC= λ vWavelength and Frequency are inverse of each other (opposite).
8Converting Wavelength Units Wavelength is measured in nm.Speed is measured in m/s.They must both have the same unit so we must convert nm to m to use it in the equation.You broke your big toe! The x ray they take of toe uses waves that have a length 4.0 X 10-7m. ( 1 meter = 1 X 109 nm)What is the wavelength in nm? (l = 400 nm)
9Frequency and Wavelength Problems Calculate n for a l = 700 nm.(Red 700nm n = 4.3 x 1014 /s or 4.3 x 1014 Hz)A purple light has a frequency of 7.42 x 1014 Hz. What is its wavelength in nm?(l = 404 nm)
10Lets look at a video to see what we are going to be learning and what the scientists were investigating…Video of electron behavior as waves and particles
11Photoelectric EffectExperiments by Einstein and others in the 1900s tried to explain the interactions between light and matter that were not explained with the wave theoryTheir research led them to discover the dual wave particle nature. How electromagnetic radiation behaves as waves and as particles.
12The evidence for this was the Photoelectric Effect experiment, which explained how light, that is usually thought of as a wave, can also behave like a particle of matter.Lois de Broglie wondered if electrons (matter), normally thought of as a particle, maybe have some wave properties too.
14The wave theory predicted that light of any frequency could supply enough energy to eject an electron from its position.However, no electrons were emitted if a light’s frequency was below a certain minimum, regardless of how long the light was shone.
15Max Planck suggested that an object emits energy in small, specific amounts, called quanta. A quantum is the minimum quantity of energy that can be lost or gained by an atom.E= hvh = Planck’s constant X Js
16Photons are the “particles of light” that carry a certain amount of energy. The energy of a photon depends on the frequency of the wave.
17In order for an electron to be ejected from a metal surface, the electron must be struck by a single photon with the minimum energy required to knock the electron lose. (supports the particle theory)Because E = hv, the minimum energy needed corresponds to the frequency
18What is the energy of a photon whose frequency is 3.0 X 1012 Hz? Energy ProblemWhat is the energy of a photon whose frequency is 3.0 X 1012 Hz?E = hvWhere h= x J/Hz E =[6.626 x 3.0] 10 (-34+12) J1.99 X J
19An observation was that different metals required different amounts of energy or frequencies to exhibit the photoelectric effect. (different metals are different elements with different numbers of electrons)So what did all this mean for where the electrons were in an atom?
20It was concluded that electrons exist in specific energy levels in an atom: Ground state = lowest energy state of an atomExcited state = the highest energy stateWhen atoms are excited by energy (heat), they emit energy in the form of light.
21Classical theory predicted that atoms would be excited by whatever amount of energy that was added to them. (there would be a continuous spectrum of frequencies given off-like a prism)However, when current was passed through Hydrogen gas, a series of very specific frequencies were emitted and only certain colors were seen (line emission spectrum)
23This suggested that the electrons of an atom exist in very specific energy states. So, Bohr put all this information together in his model of an atom.
24Bohr ModelOrbits-electrons can only circle the nucleus in allowed pathsEach orbit has a fixed amount of energyClosest to the nucleus has the least amount of energy (ground)Farther from the nucleus has more energy (excited)
25Or in other words,When an excited electron returns to its ground state, it gives off the energy (a photon) in the form of electromagnetic radiation (sometimes visible light).
26From E2 to E1, the electron will gain or lose energy?
27Why do different atoms emit different light? Each atom is unique and contains its own unique electron structure in the different energy levels.
28How does the emission of light relate to the electron structure? Since each atom is unique in its electron structure with differing levels of energy, the transitions between those levels will be unique to each atom.Electrons are in certain energy levels. When electrons give off light, they emit energy, and move to a lower level closer to the nucleus.
31Some electron transitions result in energies and wavelengths within the visible light spectrum so we can see them ( nm).However, there are many transitions that we cannot see (radio waves, x-rays, gamma rays)
32de Broglie concluded that since an electron is so small but its speed is so great, it could orbit a nucleus millions of times in 1 second! (He used algebraic methods and the equations of Einstein, Planck, and the speed of a wave to figure)So, how could we possibly know where an electron is in an atom?
33Schrödinger suggested that since electrons can be thought of like waves, they may be like standing waves outside the nucleus.Only a certain number of waves can exist between the nucleus and a certain point.This fits with Bohr’s idea of energy levels in an atom.
34Ch. 4-2 The Quantum Model Light can behave as waves and particles Louis De Broglie investigated that electrons also behave like waves because:They are confined to a specific frequencyDiffraction-bending of a wave as it passes by somethingInterference-waves overlappingFig. 4-10
35Heisenberg Uncertainty Principle Heisenberg: It is impossible to simultaneously determine the location and velocity of an electron or particleSchrodinger’s theory (that there can only be so many wavelengths of energy in a certain level) led to the development of the quantum theoryQuantum theory-describes the wave patterns of electrons mathematically
36As a result of the Schrodinger equation and Heisenberg’s Principle, the location of an electron is only its probable location around a nucleusOrbital-3D region around the nucleus that describes its probable locationFig. 4-11
37Quantum NumbersSpecify the properties of atomic orbitals and properties of electrons in orbitalsThere are 4 quantum numbers for each electron:Principle Quantum NumberAngular Momentum Quantum NumberMagnetic Quantum NumberSpin Quantum Number
38NO two electrons have the same 4 quantum numbers Similar to a zip code-no 2 cities have the same zip code
39Principal Quantum Number (n)-indicates the main energy level of the electron Ex: n= 1, 2, 3…..Also indicates how many sublevels there may be for a main energy levelAngular Momentum Quantum Number (l)-indicates the shape of the sublevel or oribitalS-sphereP-dumbbell shapedD-3D shapeF- Too complexPg. 102
40Magnetic Quantum Number (m) –orientation of an orbital around the nucleus P-3D-5F-7
41Each orbital can hold 2 electrons So, total electrons for each S = 2 (1 X 2)P = 6 (3 X 2)D = 10 (5 X 2)F = 14 (7 X 2)
42How many electrons in each energy level? Use 2n2 to figure out how many electrons can be in each energy levelEx: for energy level 5, n=5So 2 (5)2 = 50 electrons
43Spin Quantum Number – indicates the direction the electron will spin in orbit * has only 2 possible values for the spin, either +1/2 or -1/2* The two electrons in each orbital have to have opposite spins
44Ch. 4-3 Electron Configurations The quantum model tells us more than the Bohr model of the atom because it tells us where the electrons are locatedElectron configurations-the arrangement of electrons in an atom
45Aufbau principle-an electron occupies the lowest-energy orbital that can receive it Fig. 4-16We always start at 1s and work up to 2s, 2p, etc.
46Pauli exclusion principle-no two electrons in the same atom can have the same set of four quantum numbersEx: zip code
47Hund’s Rule-orbitals of equal energy are each occupied by one electron before any orbital is occupied by a second electron. All the first electrons must all have the same spin
48Electron Configurations Electrons fill orbitals (s, p, d, f) and energy levels (1, 2, 3…) in a certain order according to energy:
49Remember, s orbitals can hold 2 electrons p orbitals can hold 6 electronsd orbitals can hold 10 electronsf orbitals can hold 14 electrons
50Electron Configurations 1. Electron Configuration NotationEx: He- 1s2Ex: Na-1s22s22p63s12. Orbital NotationEx: He-_↑↓_Ex: Na- (1s)_↑↓_ (2s)_↑↓_ (2p)_↑↓_ _↑↓_ _↑↓_ (3s) _↑_3. Noble Gas ConfigurationEx: Li- [He] 2s1Ex: Na-[Ne] 3s1
51Practice Practice Configurations on pg. 114 and 116 Or Practice writing all 3 configurations for Al, Cu, Ag, and Cs