Download presentation

Presentation is loading. Please wait.

1
**Three-Dimensional Symmetry**

How can we put dots on a sphere?

2
**The Seven Strip Space Groups**

3
**Simplest Pattern: motifs around a symmetry axis (5) Equivalent to wrapping a strip around a cylinder**

4
**Symmetry axis plus parallel mirror planes (5m)**

5
**Symmetry axis plus perpendicularmirror plane (5/m)**

6
**Symmetry axis plus both sets of mirror planes (5m/m)**

7
**Symmetry axis plus perpendicular 2-fold axes (52)**

8
**Symmetry axis plus mirror planes and perpendicular 2-fold axes (5m2)**

9
**The three-dimensional version of glide is called inversion**

10
**Axial Symmetry (1,2,3,4,6 – fold symmetry) x 7 types = 35**

Only rotation and inversion possible for 1-fold symmetry ( = 30) 3 other possibilities are duplicates 27 remaining types

11
**Isometric Symmetry Cubic unit cells**

Unifying feature is surprising: four diagonal 3-fold symmetry axes 5 isometric types + 27 axial symmetries = 32 crystallographic point groups Two of the five are very common, one is less common, two others very rare

12
The Isometric Classes

13
The Isometric Classes

14
**Non-Crystallographic Symmetries**

There are an infinite number of axial point groups: 5-fold, 7-fold, 8-fold, etc, with mirror planes, 2-fold axes, inversion, etc. In addition, there are two very special 5-fold isometric symmetries with and without mirror planes. Clusters of atoms, molecules, viruses, and biological structures contain these symmetries Some crystals approximate these forms but do not have true 5-fold symmetry, of course.

15
Icosahedral Symmetry

16
**Icosahedral Symmetry Without Mirror Planes**

17
**Why Are Crystals Symmetrical?**

Electrostatic attraction and repulsion are symmetrical Ionic bonding attracts ions equally in all directions Covalent bonding involves orbitals that are symmetrically oriented because of electrostatic repulsion

18
Malformed Crystals

19
**Why Might Crystals Not Be Symmetrical?**

Chemical gradient Temperature gradient Competition for ions by other minerals Stress Anisotropic surroundings

20
**Regardless of Crystal Shape, Face Orientations and Interfacial Angles are Always the Same**

21
**We Can Project Face Orientation Data to Reveal the Symmetry**

22
**Projections in Three Dimensions are Vital for Revealing and Illustrating Crystal Symmetry**

Similar presentations

OK

Homework Look at the Space Group P21/c (#14). This is the most common space group for small molecules. 1. No protein has ever been found to crystallize.

Homework Look at the Space Group P21/c (#14). This is the most common space group for small molecules. 1. No protein has ever been found to crystallize.

© 2018 SlidePlayer.com Inc.

All rights reserved.

Ads by Google

Ppt on online marketing research Ppt on file system in mobile computing Ppt on bluetooth hacking tools Ppt on db2 mainframes computer Ppt on conceptual art books Ppt on nature and human figure Ppt on solar energy advantages and disadvantages Ppt on muhammad ali boxer Ppt on ozymandias download Ppt on save environment poster