6 } Bohr’s Model Further away from the nucleus means more energy. Fifth There is no “in between” energyEnergy LevelsFifthFourthThirdIncreasing energySecondFirstNucleus
7 The Quantum Mechanical Model Energy is quantized. It comes in chunks.Quanta - the amount of energy needed to move from one energy level to another.Quantum leap in energy.Schrödinger derived an equation that described the energy and position of the electrons in an atomTreated electrons as waves
8 The Quantum Mechanical Model a mathematical solutionIt is not like anything you can see.
9 The Quantum Mechanical Model Does have energy levels for electrons.Orbits are not circular.It can only tell us the probability of finding an electron a certain distance from the nucleus.
10 The Quantum Mechanical Model The electron is found inside a blurry “electron cloud”An area where there is a chance of finding an electron.Draw a line at 90 %
11 Atomic OrbitalsPrincipal Quantum Number (n) = the energy level of the electron.Within each energy level the complex math of Schrödinger's equation describes several shapes.These are called atomic orbitalsRegions where there is a high probability of finding an electron.
12 S orbitals 1 s orbital for every energy level Spherical shaped Each s orbital can hold 2 electronsCalled the 1s, 2s, 3s, etc.. orbitals.
13 P orbitals Start at the second energy level 3 different directions 3 different shapes (dumbell)Each can hold 2 electrons
18 Summary # of shapes Max electrons Starts at energy level s 1 2 1 p 3 6 d51037144f
19 By Energy Level First Energy Level only s orbital only 2 electrons 1s2 Second Energy Levels and p orbitals are available2 in s, 6 in p2s22p68 total electrons
20 Filling order Lowest energy fill first. The energy levels overlap The orbitals do not fill up order of energy level.Counting systemEach box is an orbital shapeRoom for two electrons
21 Increasing energy 7s 2p 3p 4p 5p 6p 7p 3d 4d 5d 6d 6s 5s 4f 5f 4s 3s
22 Increasing energy 7p 6d 5f 7s 6p 5d 6s 4f 5p 4d 5s 4p 3d 4s 3p 3s 2p
23 Electron Configurations The way electrons are arranged in atoms.Aufbau principle- electrons enter the lowest energy first.This causes difficulties because of the overlap of orbitals of different energies.Pauli Exclusion Principle- at most 2 electrons per orbital - different spins
24 Electron Configuration Hund’s Rule- When electrons occupy orbitals of equal energy they don’t pair up until they have to .Let’s determine the electron configuration for PhosphorusNeed to account for 15 electrons
25 Increasing energy 7p 6d 5f 7s 6p 5d 6s 4f 5p 4d 5s 4p 3d 4s 3p The first to electrons go into the 1s orbitalNotice the opposite spinsonly 13 more
26 Increasing energy 7p 6d 5f 7s 6p 5d 6s 4f 5p 4d 5s 4p 3d 4s 3p The next electrons go into the 2s orbitalonly 11 more
27 Increasing energy 7p 6d 5f 7s 6p 5d 6s 4f 5p 4d 5s 4p 3d 4s 3p The next electrons go into the 2p orbitalonly 5 more
28 Increasing energy 7p 6d 5f 7s 6p 5d 6s 4f 5p 4d 5s 4p 3d 4s 3p The next electrons go into the 3s orbitalonly 3 more
29 Increasing energy 7p 6d 5f 7s 6p 5d 6s 4f 5p 4d 5s 4p 3d 4s The last three electrons go into the 3p orbitals.They each go into separate shapes3 unpaired electrons1s22s22p63s23p3
30 The easy way to remember 2s 2p3s 3p 3d4s 4p 4d 4f5s 5p 5d 5f6s 6p 6d 6f7s 7p 7d 7f1s22 electrons
31 Fill from the bottom up following the arrows 2s 2p3s 3p 3d4s 4p 4d 4f5s 5p 5d 5f6s 6p 6d 6f7s 7p 7d 7f1s2 2s24 electrons
32 Fill from the bottom up following the arrows 2s 2p3s 3p 3d4s 4p 4d 4f5s 5p 5d 5f6s 6p 6d 6f7s 7p 7d 7f1s2 2s2 2p6 3s212 electrons
33 Fill from the bottom up following the arrows 2s 2p3s 3p 3d4s 4p 4d 4f5s 5p 5d 5f6s 6p 6d 6f7s 7p 7d 7f1s2 2s2 2p6 3s2 3p6 4s220 electrons
34 Fill from the bottom up following the arrows 2s 2p3s 3p 3d4s 4p 4d 4f5s 5p 5d 5f6s 6p 6d 6f7s 7p 7d 7f1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s238 electrons
35 Fill from the bottom up following the arrows 2s 2p3s 3p 3d4s 4p 4d 4f5s 5p 5d 5f6s 6p 6d 6f7s 7p 7d 7f1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s256 electrons
36 Fill from the bottom up following the arrows 2s 2p3s 3p 3d4s 4p 4d 4f5s 5p 5d 5f6s 6p 6d 6f7s 7p 7d 7f1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d10 6p6 7s288 electrons
37 Fill from the bottom up following the arrows 2s 2p3s 3p 3d4s 4p 4d 4f5s 5p 5d 5f6s 6p 6d 6f7s 7p 7d 7f1s2 2s2 2p6 3s2 3p6 4s2 3d10 4p6 5s2 4d10 5p6 6s2 4f14 5d10 6p6 7s2 5f14 6d10 7p6118 electrons
40 Orbitals fill in order Lowest energy to higher energy. Adding electrons can change the energy of the orbital.Filled and half-filled orbitals have a lower energy.Makes them more stable.Changes the filling order of d orbitals
41 Write these electron configurations Titanium - 22 electrons1s22s22p63s23p63d24s2Vanadium - 23 electrons 1s22s22p63s23p63d34s2Chromium - 24 electrons1s22s22p63s23p63d44s2 is expectedBut this is wrong!!
42 Chromium is actually 1s22s22p63s23p63d54s1 Why? This gives us two half filled orbitals.
43 Chromium is actually 1s22s22p63s23p63d54s1 Why? This gives us two half filled orbitals.
44 Chromium is actually 1s22s22p63s23p63d54s1 Why? This gives us two half filled orbitals.Slightly lower in energy.The same principle applies to copper.
45 Copper’s electron configuration Copper has 29 electrons so we expect1s22s22p63s23p63d94s2But the actual configuration is1s22s22p63s23p63d104s1This gives one filled orbital and one half filled orbital.Remember these exceptionsd4s2 d5 s1d9s2 d10s1
46 In each energy levelThe number of electrons that can fit in each energy level is calculated withMax e- = 2n2 where n is energy level1st2nd3rd
47 LightThe study of light led to the development of the quantum mechanical model.Light is a kind of electromagnetic radiation.Electromagnetic radiation includes many kinds of wavesAll move at 3.00 x 108 m/s ( c)
48 Parts of a waveCrestWavelengthAmplitudeOriginTrough
49 Parts of Wave Origin - the base line of the energy. Crest - high point on a waveTrough - Low point on a waveAmplitude - distance from origin to crestWavelength - distance from crest to crestWavelength - is abbreviated l -Greek letter lambda.
50 FrequencyThe number of waves that pass a given point per second.Units are cycles/sec or hertz (Hz)Abbreviated n - the Greek letter nuc = ln
51 Frequency and wavelength Are inversely relatedAs one goes up the other goes down.Different frequencies of light is different colors of light.There is a wide variety of frequenciesThe whole range is called a spectrum
52 Spectrum Low energy High energy Radiowaves Microwaves Infrared . Ultra-violetX-RaysGammaRaysLow FrequencyHigh FrequencyLong WavelengthShort WavelengthVisible Light
53 Light is a Particle Energy is quantized. Light is energy Light must be quantizedThese smallest pieces of light are called photons.Energy and frequency are directly related.
54 Energy and frequency E = h x n E is the energy of the photon n is the frequencyh is Planck’s constanth = x Joules sec.
55 The Math in Chapter 5 Only 2 equations c = ln E = hn c is always x 108 m/sh is always x J s
56 ExamplesWhat is the frequency of red light with a wavelength of 4.2 x 10-5 cm?What is the wavelength of KFI, which broadcasts at with a frequency of 640 kHz?What is the energy of a photon of each of the above?
57 How color tells us about atoms Atomic SpectrumHow color tells us about atoms
58 PrismWhite light is made up of all the colors of the visible spectrum.Passing it through a prism separates it.
71 UltravioletVisibleInfraredFurther they fall, more energy, higher frequency.This is simplifiedthe orbitals also have different energies inside energy levelsAll the electrons can move around.
72 What is light? Light is a particle - it comes in chunks. Light is a wave- we can measure its wave length and it behaves as a waveIf we combine E=mc2 , c=ln, E = 1/2 mv2 and E = hnWe can get l = h/mvThe wavelength of a particle.
73 Matter is a Wave Does not apply to large objects Things bigger than an atomA baseball has a wavelength of about m when moving 30 m/sAn electron at the same speed has a wavelength of 10-3 cmBig enough to measure.
74 DiffractionWhen light passes through, or reflects off, a series of thinly spaced lines, it creates a rainbow effectbecause the waves interfere with each other.
108 Several wavesSeveral wavesSeveral CurvesInterference Pattern
109 Diffraction Light shows interference patterns Light is a wave What will an electron do when going through two slits?Go through one slit or the other and make two spotsGo through both and make a interference pattern
112 Which did it do? It made the diffraction pattern The electron is a waveLed to Schrödingers equation
113 The physics of the very small Quantum mechanics explains how the very small behaves.Quantum mechanics is based on probability because
114 Heisenberg Uncertainty Principle It is impossible to know exactly the speed and position of a particle.The better we know one, the less we know the other.The act of measuring changes the properties.
115 More obvious with the very small To measure where a electron is, we use light.But the light moves the electronAnd hitting the electron changes the frequency of the light.
116 After Before Photon changes wavelength Photon Electron changes velocityMoving Electron
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