Presentation is loading. Please wait.

Presentation is loading. Please wait.

Chapter 2 Atoms and Molecules: The Chemical Basis of Life

Similar presentations


Presentation on theme: "Chapter 2 Atoms and Molecules: The Chemical Basis of Life"— Presentation transcript:

1 Chapter 2 Atoms and Molecules: The Chemical Basis of Life

2 Chemistry and Life All organisms share fundamental similarities in their chemical composition and basic metabolic processes The structure of atoms determines the way they form chemical bonds to produce complex compounds molecular biology Chemistry and physics of the molecules that constitute living things

3 Inorganic and Organic Compounds
inorganic compounds Small, simple substances Biologically important groups include water, simple acids and bases, and simple salts organic compounds Generally large, complex carbon-containing compounds Typically, two or more carbon atoms are bonded to each other to form the backbone, or skeleton, of the molecule

4 2.1 ELEMENTS AND ATOMS LEARNING OBJECTIVES:
Name the principal chemical elements in living things and provide an important function of each Compare the physical properties (mass and charge) and locations of electrons, protons, and neutrons. Distinguish between the atomic number and the mass number of an atom Define the terms orbital and electron shell; relate electron shells to principal energy levels

5 Elements elements Substances that can’t be broken down into simpler substances by ordinary chemical reactions Each element has a chemical symbol (Example: C for carbon) Four elements (oxygen, carbon, hydrogen, and nitrogen) make up more than 96% of the mass of most organisms Calcium, phosphorus, potassium, and magnesium, are present in smaller quantities Iodine and copper are trace elements

6 Functions of Elements in Organisms
Table 2-1, p. 27

7 Atoms and Matter atom Smallest unit of an element that retains that element’s chemical properties Made up of tiny subatomic particles of matter matter Anything that has mass and takes up space

8 Subatomic Particles There are three basic types of subatomic particles: An electron carries a unit of negative electric charge A proton carries a unit of positive charge A neutron is an uncharged particle Protons and neutrons compose the atomic nucleus Electrons move rapidly around the atomic nucleus In an electrically neutral atom, the number of electrons equals the number of protons

9 Atomic Number and the Periodic Table
Every element has a fixed number of protons in the atomic nucleus (atomic number) which determines an atom’s identity and defines the element The periodic table is a chart of the elements arranged in order by atomic number and chemical behavior Bohr models represent the electron configurations of elements as a series of concentric rings

10 The Periodic Table

11 Chemical symbol Atomic number Chemical name Number of e– in each energy level Figure 2.1: The periodic table. Note the Bohr models depicting the electron configuration of atoms of some biologically important elements, plus neon, which is unreactive, because its valence shell is full (to be discussed later in the chapter). Although the Bohr model does not depict electron configurations accurately, it is commonly used because of its simplicity and convenience. A complete periodic table is given in Appendix A. Fig. 2-1, p. 28

12 Atomic Mass The mass of a subatomic particle is expressed in terms of the atomic mass unit (amu) or dalton One amu equals the approximate mass of a single proton or a single neutron; an electron is about 1/1800 amu The atomic mass of an atom equals the total number of protons and neutrons, expressed in amus or daltons

13 Characteristics of Subatomic Particles
Particle Charge ~Mass Location Proton Positive 1 amu Nucleus Neutron Neutral 1 amu Nucleus Electron Negative ~1/1800 amu Outside nucleus

14 Isotopes Most elements consist of a mixture of atoms with different numbers of neutrons and different masses isotopes Atoms of the same element (having the same number of protons and electrons) with varying numbers of neutrons The mass of an element is expressed as an average of the masses of its isotopes

15 Isotopes of Carbon

16 Radioisotopes Some isotopes are unstable and tend to break down (decay) to a more stable isotope (usually a different element) radioisotope Unstable isotope that emits radiation as it decays Example: 14C decays to 14N when a neutron decomposes to form a proton and a fast-moving electron Radioactive decay can be detected by autoradiography, on photographic film

17 Radioisotopes in Biology
Radioisotopes such as 3H (tritium), 14C, and 32P can replace normal molecules and are used as tracers in research In medicine, radioisotopes are used for both diagnosis (such as thyroid function or blood flow) and treatment (such as cancer)

18 Autoradiography Tritium (3H) incorporated into the DNA of a fruit fly

19 Atomic Orbitals and Energy
Electrons move through characteristic regions of 3-D space (orbitals), each containing a maximum of 2 electrons The energy of an electron depends on the orbital it occupies Electrons in orbitals with similar energies (the same principal energy level) make up an electron shell Electrons farther from the nucleus generally have greater energy than those closer to the nucleus

20 Valence Electrons The most energetic electrons (valence electrons) occupy the valence shell, represented as the outermost concentric ring in a Bohr model Valence electrons participate in chemical reactions An electron can move to a higher orbital by receiving more energy, or give up energy and sink to a lower orbital Changes in electron energy levels are important in energy conversions in organisms

21 Atomic Orbitals

22 Nucleus (a) The first principal energy level contains a maximum of 2 electrons, occupying a single spherical orbital (designated 1s). The electrons depicted in the diagram could be present anywhere in the blue area. 1s Figure 2.4: Atomic orbitals. Each orbital is represented as an “electron cloud.” The arrows labeled x, y, and z establish the imaginary axes of the atom. Fig. 2-4a, p. 30

23 2s 2py 2px 2pz Figure 2.4: Atomic orbitals. Each orbital is represented as an “electron cloud.” The arrows labeled x, y, and z establish the imaginary axes of the atom. (b) The second principal energy level includes four orbitals, each with a maximum of 2 electrons: one spherical (2s) and three dumbbell-shaped (2p) orbitals at right angles to one another. Fig. 2-4b, p. 30

24 z 1s 2s y 2py 2px x 2pz Figure 2.4: Atomic orbitals. Each orbital is represented as an “electron cloud.” The arrows labeled x, y, and z establish the imaginary axes of the atom. (c) Orbitals of the first and second principal energy levels of a neon atom are shown superimposed. Note that the single 2s orbital plus three 2p orbitals make up neon's full valence shell of 8 electrons. Compare this more realistic view of the atomic orbitals with the Bohr model of a neon atom at right. Fig. 2-4c, p. 30

25 (d) Neon atom (Bohr model)
Figure 2.4: Atomic orbitals. Each orbital is represented as an “electron cloud.” The arrows labeled x, y, and z establish the imaginary axes of the atom. (d) Neon atom (Bohr model) Fig. 2-4d, p. 30

26 ANIMATION: The shell model of electron distribution
To play movie you must be in Slide Show Mode PC Users: Please wait for content to load, then click to play Mac Users: CLICK HERE

27 Key Concepts 2.1 Carbon, hydrogen, oxygen, and nitrogen are the most abundant elements in living things

28 ANIMATION: Atomic number, mass number
To play movie you must be in Slide Show Mode PC Users: Please wait for content to load, then click to play Mac Users: CLICK HERE

29 ANIMATION: Electron arrangement in atoms
To play movie you must be in Slide Show Mode PC Users: Please wait for content to load, then click to play Mac Users: CLICK HERE

30 Animation: Electron distribution

31 ANIMATION: Subatomic particles
To play movie you must be in Slide Show Mode PC Users: Please wait for content to load, then click to play Mac Users: CLICK HERE

32 Explain why the mole concept is so useful to chemists
2.2 CHEMICAL REACTIONS LEARNING OBJECTIVES: Explain how the number of valence electrons of an atom is related to its chemical properties Distinguish among simplest, molecular, and structural chemical formulas Explain why the mole concept is so useful to chemists

33 Valence Electrons Chemical behavior of an atom is determined by the number and arrangement of its valence electrons Atoms with full valence shells are unreactive When the valence shell is not full, an atom tends to lose, gain, or share electrons to achieve a full outer shell Elements in the same vertical column (group) of the periodic table have similar chemical properties

34 Compounds and Molecules
Two or more atoms may combine chemically A chemical compound consists of atoms of two or more different elements combined in a fixed ratio Two or more atoms joined very strongly form a stable molecule Example: H20 (water) is a molecular compound

35 Chemical Formulas A chemical formula is a shorthand expression that describes the chemical composition of a substance In a simplest formula (empirical formula), subscripts give the smallest ratios for atoms in a compound (e.g. NH2) A molecular formula gives the actual numbers of each type of atom per molecule (e.g. N2H4) A structural formula shows the arrangement of atoms in a molecule (e.g. water, H—O—H)

36 The Mole The molecular mass of a compound equals the sum of the atomic masses of the component atoms of a single molecule The amount of a compound whose mass in grams is equivalent to its molecular mass is 1 mole (mol) Example: Molecular mass of water (H2O) is (hydrogen: 2 × 1 amu) + (oxygen: 1 × 16 amu) = 18 amu 1 mol of water is 18 grams (g)

37 The Mole (cont.) 1 mol of any substance has exactly the same number of atoms or molecules: × 1023 (Avogadro’s number) Avogadro’s number allows scientists to calculate the number of atoms or molecules in sample simply by weighing it A 1 molar solution (1 M) contains 1 mol of a substance dissolved in a total volume of 1 liter (L)

38 Chemical Reactions Chemical reactions, such as the reaction between glucose and oxygen, are described by chemical equations: C6H12O6 + 6 O2 → 6 CO2 + 6 H2O + energy Substances that participate in the reaction (reactants) are written on the left side of the arrow Substances formed by the reaction (products) are written on the right side

39 Chemical Reactions (cont.)
Many reactions proceed forward and reverse simultaneously At dynamic equilibrium, the rates of forward and reverse reactions are equal CO2 + H2O ↔ H2CO3 When this reaction reaches equilibrium, there will be more reactants (CO2 and H2O) than product (H2CO3)

40 Key Concepts 2.2 The chemical properties of an atom are determined by its highest-energy electrons, known as valence electrons

41 ANIMATION: Chemical bookkeeping
To play movie you must be in Slide Show Mode PC Users: Please wait for content to load, then click to play Mac Users: CLICK HERE

42 Animation: Covalent bonds

43 2.3 CHEMICAL BONDS LEARNING OBJECTIVE:
Distinguish among covalent bonds, ionic bonds, hydrogen bonds, and van der Waals interactions Compare them in terms of the mechanisms by which they form and their relative strengths

44 Chemical Bonds Atoms can be held together by chemical bonds
Valence electrons dictate how many bonds an atom can form bond energy Energy necessary to break a chemical bond Two types of strong chemical bonds: covalent and ionic

45 Covalent Bonds Covalent bonds involve sharing electrons between atoms in a way that fills each atom’s valence shell A molecule consists of atoms joined by covalent bonds Example: hydrogen gas (H2) Unlike atoms linked by covalent bonds form a covalent compound

46 Lewis Structure A simple way of representing valence electrons is to use dots placed around the chemical symbol of the element: Oxygen (6 valence electrons) shares electrons with two hydrogen atoms to complete its valence shell of 8 – each hydrogen atom completes a valence shell of 2

47 Carbon Bonds Carbon has 4 electrons in its valence shell, all of which are available for covalent bonding (e.g. methane, CH4) Each orbital holds a maximum of 2 electrons

48 Single, Double, and Triple Covalent Bonds
When one pair of electrons is shared between two atoms, the covalent bond is called a single covalent bond A double covalent bond is formed when two pairs of electrons are shared (represented by two parallel solid lines) A triple covalent bond is formed when three pairs of electrons are shared (represented by three parallel solid lines)

49 Electron Sharing in Covalent Compounds

50 Molecular hydrogen (H2) or H H
(a) Single covalent bond formation. Two hydrogen atoms achieve stability by sharing a pair of electrons, thereby forming a molecule of hydrogen. In the structural formula on the right, the straight line between the hydrogen atoms represents a single covalent bond. Figure 2.5: Electron sharing in covalent compounds. Fig. 2-5a, p. 33

51 Molecular oxygen (O2) (double bond is formed)
Figure 2.5: Electron sharing in covalent compounds. (b) Double covalent bond formation. In molecular oxygen, two oxygen atoms share two pairs of electrons, forming a double covalent bond. The parallel straight lines in the structural formula represent a double covalent bond. Fig. 2-5b, p. 33

52 Bonds Found in Biologically Important Molecules
Atom Symbol Covalent Bonds Hydrogen H 1 Oxygen O 2 Carbon C 4 Nitrogen N 3 Phosphorus P 5 Sulfur S 2

53 Molecular Shape and Function
The functions of molecules in living cells are determined largely by their geometric shapes When atoms form covalent bonds, orbitals in valence shells may become rearranged (orbital hybridization), affecting the shape of the resulting molecule Example: In methane (CH4), the hybridized valence shell orbitals of the carbon form a tetrahedron

54 Tetrahedron: Methane (CH4)
Geometric shape of a molecule provides the optimal distance between atoms to counteract repulsion of electron pairs

55 Methane (CH4) Fig. 2-6, p. 34

56 Polar and Nonpolar Covalent Bonds
electronegativity A measure of an atom’s attraction for shared electrons in chemical bonds (e.g. oxygen has high electronegativity) nonpolar covalent bond When covalently bonded atoms have similar electronegativities, electrons are shared equally polar covalent bond Covalent bond between atoms that differ in electronegativity; electrons are pulled closer to the nucleus of the atom with greater electron affinity

57 Polar Molecules A polar covalent bond has two dissimilar ends (poles), one with a partial positive charge and the other partially negative A polar molecule has one end with a partial positive charge and another end with a partial negative charge Example: Water has a partial positive charge at the hydrogen end and a partial negative charge at the oxygen end, where “shared” electrons are more likely to be

58 Water: A Polar Molecule

59 Hydrogen (H) Oxygen (O) Hydrogen (H)
Figure 2.7: Water, a polar molecule. Note that the electrons tend to stay closer to the nucleus of the oxygen atom than to the hydrogen nuclei. This results in a partial negative charge on the oxygen portion of the molecule and a partial positive charge at the hydrogen end. Although the water molecule as a whole is electrically neutral, it is a polar covalent compound. Hydrogen (H) Oxygen (O) Hydrogen (H) Fig. 2-7, p. 34

60 Partial negative charge at oxygen end of molecule
Oxygen part Hydrogen parts Partial negative charge at oxygen end of molecule Partial positive charge at hydrogen end of molecule Figure 2.7: Water, a polar molecule. Note that the electrons tend to stay closer to the nucleus of the oxygen atom than to the hydrogen nuclei. This results in a partial negative charge on the oxygen portion of the molecule and a partial positive charge at the hydrogen end. Although the water molecule as a whole is electrically neutral, it is a polar covalent compound. Water molecule (H2O) Fig. 2-7b, p. 34

61 Ions An atoms or group of atoms with 1 or more units of electric charge is called an ion Atoms with 1, 2, or 3 valence electrons tend to lose electrons to other atoms and become positively charged cations Atoms with 5, 6, or 7 valence electrons tend to gain electrons from other atoms and become negatively charged anions

62 Functions of Ions The properties of ions are different from those of the electrically neutral atoms from which they were derived Electric charges of cations and anions provide a basis for energy transformations within the cell, transmission of nerve impulses, muscle contraction, and other biological processes

63 Ions and Biological Processes
Sodium, potassium, and chloride ions are essential for a nerve cell to stimulate muscle fibers, initiating a muscle contraction Calcium ions in the muscle cell are required for muscle contraction

64 Muscle fiber Nerve Figure 2.8: Ions and biological processes.
Sodium, potassium, and chloride ions are essential for this nerve cell to stimulate these muscle fibers, initiating a muscle contraction. Calcium ions in the muscle cell are required for muscle contraction. Fig. 2-8, p. 35

65 Ionic Bonds An ionic bond is formed by attraction between the positive charge of a cation and the negative charge of an anion An ionic compound is a substance consisting of anions and cations bonded by their opposite charges Example: Sodium chloride (NaCl), an ionic compound When sodium reacts with chlorine, sodium’s single valence electron is transferred completely to chlorine Sodium becomes a cation (Na+); chlorine becomes an anion (Cl−)

66 Ionic Bonding 11 protons 17 protons and 11 electrons Sodium (Na)
17 electrons Chlorine (Cl) 10 electrons Sodium ion (Na+) 18 electrons Chloride ion (Cl–) Sodium chloride (NaCl) Figure 2.9: Ionic bonding. Sodium becomes a positively charged ion when it donates its single valence electron to chlorine, which has 7 valence electrons. With this additional electron, chlorine completes its valence shell and becomes a negatively charged chloride ion. These sodium and chloride ions are attracted to one another by their unlike electric charges, forming the ionic compound sodium chloride. Arrangement of atoms in a crystal of salt Fig. 2-9, p. 35

67 ANIMATION: Ionic bonding
To play movie you must be in Slide Show Mode PC Users: Please wait for content to load, then click to play Mac Users: CLICK HERE

68 Ionic Compounds in Solution
In the absence of water, ionic bonds are very strong Example: Electrical attraction in ionic bonds holds Na+ and Cl− together to form NaCl (sodium chloride, table salt) When placed in water, ionic compounds (such as sodium chloride) tend to dissociate into individual ions : NaCl (in H2O) → Na+ + Cl–

69 Water as a Solvent Water is an excellent solvent, capable of dissolving many substances (solutes) Because of their polarity, water molecules easily dissolve polar or ionic substances In solution, each cation or anion is surrounded by oppositely charged ends of the water molecules (hydration)

70 Hydration of an Ionic Compound

71 Salt Figure 2.10: Hydration of an ionic compound.
When the crystal of NaCl is added to water, the sodium and chloride ions are pulled apart. When the NaCl is dissolved, each Na+ and Cl− is surrounded by water molecules electrically attracted to it. Fig. 2-10, p. 36

72 ANIMATION: Spheres of hydration
To play movie you must be in Slide Show Mode PC Users: Please wait for content to load, then click to play Mac Users: CLICK HERE

73 Hydrogen Bonds Hydrogen bonds are relatively weak bonds (easily formed and broken) that are very important in living organisms When hydrogen combines with a relatively electronegative atom, it acquires a partial positive charge Hydrogen bonds form between an atom with a partial negative charge and a hydrogen atom that is covalently bonded to oxygen or nitrogen Water molecules interact with one another extensively through hydrogen bond formation

74 Hydrogen Bonding

75 ANIMATION: Examples of hydrogen bonds
To play movie you must be in Slide Show Mode PC Users: Please wait for content to load, then click to play Mac Users: CLICK HERE

76 van der Waals Interactions
Adjacent molecules may interact in transient regions of weak positive and negative charge The resulting attractive forces (van der Waals interactions) operate over very short distances and are weaker and less specific than other types of interactions They are important when they occur in large numbers and when molecular shapes permit close contact between atoms

77 Key Concepts 2.3 A molecule consists of atoms joined by covalent bonds
Other important chemical bonds include ionic bonds Hydrogen bonds and van der Waals interactions are weak attractions

78 ANIMATION: How atoms bond
To play movie you must be in Slide Show Mode PC Users: Please wait for content to load, then click to play Mac Users: CLICK HERE

79 2.4 REDOX REACTIONS LEARNING OBJECTIVE:
Distinguish between the terms oxidation and reduction, and relate these processes to the transfer of energy

80 Redox Reactions Many energy conversions involve oxidation–reduction (redox) reactions in which an electron (and its energy) is transferred from one substance to another oxidation Chemical process in which an atom, ion, or molecule loses one or more electrons reduction Chemical process in which an atom, ion, or molecule gains one or more electrons

81 Redox Reactions (cont.)
Redox reactions occur simultaneously; one substance accepts electrons that are removed from the other The oxidizing agent accepts electrons and is reduced The reducing agent gives up electrons and is oxidized In cells, oxidation often involves removal of a hydrogen atom (an electron plus a proton) from a covalent compound Reduction often involves the addition of a hydrogen atom

82 Key Concepts 2.4 The energy of an electron is transferred in a redox reaction

83 2.5 WATER LEARNING OBJECTIVE:
Explain how hydrogen bonds between adjacent water molecules govern many of the properties of water

84 Importance of Water About 70% of our total body weight is water
Water (via photosynthesis) is the source of oxygen in air, and hydrogen atoms used in many organic compounds Water is a solvent for biological reactions, and a reactant or product in many chemical reactions Water is a principal environmental factor for organisms Water’s unique properties are essential to life

85 Effects of Water on an Organism
(a) Commonly known as "water bears," tardigrades, such as these members of the genus Echiniscus, are small animals (less than 1.2 mm long) that normally live in moist habitats, such as thin films of water on mosses. Figure 2.12: The effects of water on an organism. Fig. 2-12a, p. 37

86 (b) When subjected to desiccation (dried out), tardigrades assume a barrel-shaped form known as a tun, remaining in this state, motionless but alive, for as long as 100 years. When rehydrated, they assume their normal appearance and activities. Figure 2.12: The effects of water on an organism. 10 μm Fig. 2-12b, p. 37

87 Hydrogen Bonds Between Water Molecules
Water molecules are polar Hydrogen bonds form between the partial positive charge (hydrogen) of one water molecule and the partial negative charge (oxygen) of a neighboring water molecule Each water molecule can form hydrogen bonds with up to four neighboring water molecules

88 Hydrogen Bonding of Water Molecules
Figure 2.13: Hydrogen bonding of water molecules. Each water molecule can form hydrogen bonds (dotted lines) with as many as four neighboring water molecules. Fig. 2-13, p. 38

89 Cohesion and Adhesion cohesion
Tendency of water molecules to stick to one another, due to hydrogen bonds among molecules Any force exerted on part of a column of water is transmitted to the column as a whole Major mechanism of water movement in plants adhesion The ability of water to stick to other substances, particularly those with charges on their surfaces Explains how water makes things wet

90 Capillary Action and Surface Tension
The tendency of water to move in narrow tubes, even against the force of gravity A combination of adhesive and cohesive forces surface tension Molecules at water’s surface crowd together, producing a strong layer as they are pulled downward by the attraction (cohesion) of water molecules beneath them

91 Capillary Action Adhesion between water and glass in a narrow tube pulls other water up by cohesion In the wider tube, adhesion is not strong enough to overcome the cohesion below Figure 2.14: Capillary action. (a) In a narrow tube, there is adhesion between the water molecules and the glass wall of the tube. Other water molecules inside the tube are then “pulled along” because of cohesion, which is due to hydrogen bonds between the water molecules. (b) In the wider tube, a smaller percentage of the water molecules line the glass wall. As a result, the adhesion is not strong enough to overcome the cohesion of the water molecules beneath the surface level of the container, and water in the tube rises only slightly. Fig. 2-14, p. 38

92 Surface Tension Water striders (Gerris) supported by surface tension of water Figure 2.15: Surface tension of water. Hydrogen bonding between water molecules is responsible for the surface tension of water, which causes a dimpled appearance of the surface as these water striders (Gerris) walk across it. Fine hairs at the ends of the legs of these insects create highly water-repellent “cushions” of air. Fig. 2-15, p. 38

93 Interactions with Water
Because water molecules are polar, water dissolves many kinds of substances, and excludes others Hydrophilic (“water-loving”) substances interact easily with water (polar and ionic compounds) Hydrophobic (“water-fearing”) substances are not soluble in water (nonpolar molecules) Hydrophobic interactions occur between groups of nonpolar molecules, which cluster together in water

94 Water and Temperature Water exists in three states, which differ in degree of hydrogen bonding: gas (vapor), liquid, and ice (crystalline) Adding heat energy makes molecules move faster (increases kinetic energy) and breaks hydrogen bonds heat The total kinetic energy in a sample of a substance temperature The average kinetic energy of the particles

95 Water and Temperature (cont.)
Much of the heat energy added is used to break hydrogen bonds – less energy is available to speed the movement of water molecules (increasing temperature) heat of vaporization Amount of heat energy required to change 1 g of a substance from liquid phase to vapor phase calorie (cal) Amount of heat energy – equivalent to joules (J) –required to raise 1 g of water 1 degree Celsius (C)

96 Water and Temperature (cont.)
evaporative cooling As water is heated, some molecules move faster than others and are more likely to evaporate, taking heat with them and lowering the temperature of the water Humans dissipate excess heat as sweat evaporates specific heat A large amount of energy is required to raise the temperature of water (1 cal/g of water per degree Celsius) Maintains constant environmental temperatures

97 Water and Temperature (cont.)
Hydrogen bonding causes ice to have unique properties with important environmental consequences Liquid water expands as it freezes, making ice about 10% less dense than liquid water – ice floats on denser cold water Ice insulates liquid water below it, retarding freezing and permitting organisms to survive without freezing

98 Three Forms of Water

99 (a) Steam becoming water vapor (gas)
212°F 100°C (a) Steam becoming water vapor (gas) 50°C (b) Water (liquid) Figure 2.16: Three forms of water. (a) When water boils, as in this hot spring at Yellowstone National Park, many hydrogen bonds are broken, causing steam, consisting of minuscule water droplets, to form. If most of the remaining hydrogen bonds break, the molecules move more freely as water vapor (a gas). (b) Water molecules in a liquid state continually form, break, and re-form hydrogen bonds with one another. (c) In ice, each water molecule participates in four hydrogen bonds with adjacent molecules, resulting in a regular, evenly distanced crystalline lattice structure. 32°F 0°C (c) Ice (solid) Fig. 2-16, p. 39

100 ANIMATION: Structure of water
To play movie you must be in Slide Show Mode PC Users: Please wait for content to load, then click to play Mac Users: CLICK HERE

101 Key Concepts 2.5 Water molecules are polar, having regions of partial positive and partial negative charge that permit them to form hydrogen bonds with one another and with other charged substances

102 ANIMATION: Dehydration synthesis and hydrolysis
To play movie you must be in Slide Show Mode PC Users: Please wait for content to load, then click to play Mac Users: CLICK HERE

103 3D Animation: Dissolution

104 Contrast acids and bases, and discuss their properties
2.6 ACIDS, BASES, AND SALTS LEARNING OBJECTIVES: Contrast acids and bases, and discuss their properties Convert the hydrogen ion concentration (moles per liter) of a solution to a pH value and describe how buffers help minimize changes in pH Describe the composition of a salt and explain why salts are important in organisms

105 Ionization of Water In pure water, a small number of water molecules dissociate into hydrogen ions (H+) and hydroxide ions (OH−) HOH ↔ H+ + OH− The concentrations of hydrogen ions and hydroxide ions in pure water are exactly equal Such a solution is said to be neutral – neither acidic nor basic

106 Acids and Bases acid Substance that dissociates in solution to yield hydrogen ions (H+) and anion; a proton donor Acid → H+ + anion base Substance that dissociates in solution to yield a hydroxide ion (OH−) and a cation; a proton acceptor NaOH → Na+ + OH- OH- + H+ → H2O

107 Acids and Bases (cont.) Some bases do not dissociate to yield hydroxide ions directly Example: Ammonia (NH3) acts as a base by accepting a proton from water, producing an ammonium ion (NH4+) and releasing a hydroxide ion: NH3 + H2O → NH4+ + OH−

108 pH A solution’s acidity is expressed in terms of pH pH
The negative logarithm (base 10) of the hydrogen ion concentration [H+] (expressed in moles per liter): pH = −log10[H+] The negative logarithm corresponds to a positive pH value Pure water has a hydrogen ion concentration of (10—7 mol/L) Logarithm = −7; pH is 7

109 pH of Solutions neutral solution (pH 7)
Equal concentrations of hydrogen ions and hydroxide ions (concentration of each is 10−7 mol/L) acidic solution (pH <7) Hydrogen ion concentration is higher than hydroxide ion concentration basic solution (pH >7) Hydrogen ion concentration is lower than hydroxide ion concentration

110 Calculating pH Values and Hydroxide Ion Concentrations
Table 2-2, p. 41

111 pH Values pH of most plant and animal cells (and their environment) ranges from around 7.2 to 7.4

112 pH scale Battery acid 0.0 Hydrochloric acid 0.8 Stomach acid 1.0 1 2 Stomach gastric juice 2.0 Increasing acidity 3 Vinegar 3.0 4 Beer 4.5 5 Black coffee 5.0 6 Rainwater 6.25 Cow milk 6.5 Neutrality 7 Distilled water 7.0 Blood 7.4 8 Seawater 8.0 Figure 2.17: pH values of some common solutions. A neutral solution (pH 7) has equal concentrations of H+ and OH−. Acidic solutions, which have a higher concentration of H+ than OH−, have pH values less than 7; pH values greater than 7 characterize basic solutions, which have an excess of OH−. 9 Bleach 9.0 Mono Lake, California 9.9 10 Increasing alkalinity 11 Household ammonia 11.5 12 13 Oven cleaner 13.0 14 Lye 14.0 Fig. 2-17, p. 41

113 Animation: The pH scale

114 Buffers Minimize pH Change
Homeostatic mechanisms maintain appropriate pH values Example: pH of human blood is about 7.4 and must be maintained within very narrow limits buffer Substance that resists changes in pH when an acid or base is added A buffering system includes a weak acid or a weak base

115 A Buffering System In blood, carbon dioxide reacts with water to form carbonic acid, a weak acid that dissociates to yield H+ and bicarbonate: CO2 + H2O ↔ H2CO3 ↔ H+ + HCO3– Addition of excess hydrogen ions shifts the system to the left, as H+ combine with bicarbonate ions to form carbonic acid Addition of hydroxide ions shifts the system to the right

116 Formation of Salts When an acid and a base are mixed in water, anions from the acid and cations from the base combine to form a salt salt Compound in which the hydrogen ion of an acid is replaced by some other cation Example: Sodium chloride (NaCl) is a salt in which the H+ of HCl has been replaced by the cation Na+ HCl + NaOH → H2O + NaCl

117 Salts (cont.) When a salt, acid, or base is dissolved in water, its dissociated ions (electrolytes) can conduct an electric current Animals and plants contain a variety of dissolved salts (important mineral ions) essential for fluid balance and acid–base balance Homeostatic mechanisms maintain concentrations and relative amounts of various cations and anions

118 Key Concepts 2.6 Acids are hydrogen ion donors; bases are hydrogen ion acceptors The pH scale is a convenient measure of the hydrogen ion concentration of a solution


Download ppt "Chapter 2 Atoms and Molecules: The Chemical Basis of Life"

Similar presentations


Ads by Google