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© 2011 Atlantium Technologies Ltd. Dairy Industry UV Water Treatment Atlantium Hydro-Optic Solutions Only Medium Pressure does more for less! The Next-Generation UV Technology Hydro-Optic Dechlorination & Disinfection Technology (HOD): Achieve PMO Pasteurized Equivalent Water from UV HOD – A Bright Idea to cost effectively protect your Brand Dairy industry – 2012 Bob English
© 2011 Atlantium Technologies Ltd. 2 A cutting edge UV technology company formed in Israel in 2003 by PhDs in Microbiology, Optical Physics, Software Engineering, Hydrology, and Environmental Science. Atlantium was borne out of the absence and need for a Regulatory Agency approved primary line of disinfecting UV systems that could produce 3 rd party validated FDA- PMO Pasteurized Equivalent Water and EPA drinking water with 4 log adenovirus and 5 log bacteria reduction. This was a industry paradigm shift from a good idea to include to a FDA & EPA approved best practice for water disinfection and pasteurization. Atlantium expanded that vision to now include feed and process water dechlorination for food and beverage applications to complement our pharmaceutical application achievement. Whos Atlantium UV
© 2011 Atlantium Technologies Ltd. 3 1.Identify Specific Problem 2.Define cause of problem 3.Present the Best Solution. Presentation Design:
© 2011 Atlantium Technologies Ltd. 4 Aseptic rinse line Frequent process interruptions and maintenance attention required to change very expensive 0.2 um bacteria reduction filter cartridges (sterilization filters) #1 Identify the Current Problem:
© 2011 Atlantium Technologies Ltd. 5 Even with the frequent Carbon Filter and Sand Filter backwashes, the fine microbial matter and bacteria that are innately associated with ALL carbon filters contaminate the water lines and plug your filters. #2 Cause of the current problem:
© 2011 Atlantium Technologies Ltd. 6 Replace the root cause of your problem with a full flow inline Atlantium HOD UV Dechlorination and Sanitization system. #3 Best solution for your problem Get significantly higher quality water with less cost, less water use, less time, less attention, and less effort.
© 2011 Atlantium Technologies Ltd. 7 Eliminates the need for frequent replacement of the expensive 0.2 um What Dechlorination with UV means for you ? Atlantium HOD UV treats water beyond PMO pasteurized equivalent water quality – which exceeds your cartridge filters performance!! Excellent ROI Cartridges Backwash Water Carbon Rebeds Maintenance time and attention Process interruption Increase in reliability and quality Save water, time and money.
© 2011 Atlantium Technologies Ltd. 8 Light-based De-Chlorination – Very clean no chemical or particulate additions (carbon and sand fines) Extreme Disinfection – bonus -4 log +++ elimination on all microbiology!! -No other technology or vendor can meet this performance guarantee! Important Benefits of UV replacing Carbon(GAC) Filters used in Dechlorination
© 2011 Atlantium Technologies Ltd. 9 This system configuration eliminates the need for the 0.2 absolute bacteria filter since it sanitizes the water to a higher quality standard than that filter. For extreme conservatism a 0.45 nominal filter could be left in place but is not necessary. (28.9) Design #1 PMO quality disinfection of your Carbon filtered water
© 2011 Atlantium Technologies Ltd. 10 This system configuration eliminates the carbon filter, the 0.2 absolute bacteria filter from the aseptic cap rinse line while producing PMO Pasteurized Equivalent water up to a max flow of 250 GPM for all other Dairy water uses. The ROI these pasteurized equivalent water push, rinse, or CIP make up water applications can be as short a 4 months! For extreme conservatism a 0.45 nominal filter could be left in place but is not necessary. ((35.1)) Design #2 Cost Effective, Elegant, Reliable and Robust Dechlorinate and Produce PMO quality Water
© 2011 Atlantium Technologies Ltd. 11 Why is Atlantium MP HOD the most efficient UV system for your Dechlorination and disinfection? 1.Total Internal Reflectance 2.High Efficiency and Output Medium Pressure Lamps that are powered to maintain the user set UV dose even as flow rate and UV transmittance change.
© 2011 Atlantium Technologies Ltd. 12 Operation principles: RZ series HOD system cross section Stainless Quartz Tube Air Block Conventional UV Light Paths HOD Total Internal Reflectance
© 2011 Atlantium Technologies Ltd. 13 HOD Product Safety Better Product/Water ratio Less waste water Less Manpower Brand Security Less Energy Less Chemicals Less Down Time HOD- Changing the UV DISINFECTION Paradigm Product Safety Brand Security
© 2011 Atlantium Technologies Ltd. 14 Where else has this been done? Atlantium HOD Worldwide UV Dechlorination/Disinfectant Installations & Pending Applications: Wawa Dairy – Publix Dairy – Kruger Dairy - Coca Cola Jacksonville
© 2011 Atlantium Technologies Ltd. 15 More information For Greater Detail the following subjects continue on : 1.Why did we Dechlorinate with Carbon in the first place? 2.Basic Chemistry associated with Chlorine in water 3.Why Medium-Pressure Lamps Target Dechlorination 4.The HOD Advantage – Why HOD MP is better than LP or conventional MP 5.Pasteurized-Equivalent Water Application 6.UV that really works – Promises that are kept 7.Robust and Elegantly simple Application Attributes
© 2011 Atlantium Technologies Ltd. 16 One of the greatest success stories in that past 5 years in water treatment is how very effectively UV energy is at used to Dechlorinate - chlorinated feed and process waters. Why did we Dechlorinate with Carbon in the first place? The proven practice of dechlorination with UV incorporates an unrivaled level of disinfection but due to the extremely high UV dose (at nm) that is required to actually break the free chlorine bonds, all UV reactors that where properly sized and effectively used for this application have been very large and extremely expensive for all but the most critical pharmaceutical and high tech applications. Atlantium Medium Pressure HOD makes this application a cost effective alternative carbon filtration in the Dairy Industry through Total Internal Reflectance
© 2011 Atlantium Technologies Ltd. 17 Problems with the early UV dechlorination applications: Water pH dependent Water temperature dependent Excess Heat from the LP lamps Excess energy draw LP lamps UV system very large and VERY expensive Why did we Dechlorinate with Carbon in the first place? Continued Low Pressure Lamps are very inefficient at Dechlorination as they produce 254 nm light while the ideal dechlorination wavelength are nm!
© 2011 Atlantium Technologies Ltd. 18 Basic Chemistry associated with Chlorine in water The three Free-Chlorine components ClCl ClCl ClCl ClCl O O H Hypochlorous Acid [HOCl] Chlorine (Dichlorine) [Cl 2 ] Hypochlorite ion [OClˉ]
© 2011 Atlantium Technologies Ltd. 19 Dissociation Coordinate (R ) Molecule Photo-dissociation Bond Potential UV Photon Bullet breaks the chlorine based molecule hν HCl O Basic Chemistry associated with Chlorine in water
© 2011 Atlantium Technologies Ltd. 20 Chloride ions (Cl - ) Carbon – GAC Bisulfite(chem feed) MP UV Photons Cl - Na + All three methods: Free Chlorine to Chloride ions Basic Chemistry associated with Chlorine in water
© 2011 Atlantium Technologies Ltd. 21 Free Chlorine reduction alternatives Activated Carbon FilterSodium BisulfitePharmaGuard UV system Bacteria proliferation Yes. Intensive. Anaerobic, including sulfur- reducing bacteria. No. The very high UV-Dose "kills" ALL micro- organisms. Chemicals into the water NoYes. Must be removed.No – chemical-free. Maintenance burden Yes. Ongoing routine. No. Easy maintenance. Effect on RO membranes Bio- fouling.Bio- fouling and scaling. Greatly reduces any bio- fouling and scaling. On-Demand Not always. Intensive maintenance, risk of breakthrough. Yes Basic Chemistry associated with Chlorine in water
© 2011 Atlantium Technologies Ltd. 22 HOCl Cl 2 OCl - Free active Cl components vs. water acidity (pH) Basic Chemistry associated with Chlorine in water
© 2011 Atlantium Technologies Ltd. 23 Figure 2: Absorption spectra of HOCl and OCl - measured respectively at pH 5 and pH 10 Medium Pressure Lamp Low Pressure Lamp OCl - HOCl Why Medium-Pressure Lamps Target Dechlorination?
© 2011 Atlantium Technologies Ltd. 24 Atlantium HOD Operation principles: Atlantium MP HOD system cross section Stainless Quartz Tube Air Block Conventional UV Light Paths HOD Total Internal Reflectance
© 2011 Atlantium Technologies Ltd. 25 The HOD Advantage – Why HOD MP is better than LP or conventional MP Conventional UV Uniform dose distribution Non-uniform dose distribution Light in a steel tube 304 or 316 SS Absorbs > 90% of the UV energy on impact
© 2011 Atlantium Technologies Ltd. Pasteurized-Equivalent Water Application 26
© 2011 Atlantium Technologies Ltd. 27 UV that really works – Promises Kept FDA, EPA Regulatory compliance 3 rd party validated It is the Primary disinfectant Control pseudomonas, Algae, and other microbes that resist chlorine Fight biofilms and its causes and reduce CIP costs Assure quality: monitor, track; searchable records for disinfection verification Meets the PMO 2011 for Appendix H (Pasteurized Equivalent Water) and Appendix D (Disinfected Water) for:
© 2011 Atlantium Technologies Ltd. 28 UV that really works – Promises Kept It is the Primary disinfectant : Sustainability, cost and chemical reduction chemical resistant organisms Alternative solutions are needed Disinfectant by products alter the taste and quality
© 2011 Atlantium Technologies Ltd. 29 UV that really works– Promises Kept Meets the PMO 2011 for Appendix H (Pasteurized Equivalent Water) and Appendix D (Disinfected Water) for: Push Water Final Rinse CIP Water reuse such as Cow Water
© 2011 Atlantium Technologies Ltd. 30 Robust and Elegantly simple Application Attributes Atlantium Dechlorination UV System solves the problem of reducing free chlorine without the biofouling associated with carbon filters. Ideal for Low foul rates associated with Pharm and Biopharm applications Very high UV-Dose levels required to address free chlorine and other oxidizers guarantees a very effective bio-reduction
© 2011 Atlantium Technologies Ltd. 31 Transforming Free Available Chlorine to Chloride Ions
© 2011 Atlantium Technologies Ltd. 32 HCl + H 2 O H 3 O + + Cl Hydronium Ion Chloride Ion Activated Carbon Filter and Free-Chlorine
© 2011 Atlantium Technologies Ltd. 33 Sodium bisulfite (sodium hydrogen sulfite) [SBS]: NaHSO 3 Sodium metabisulfite or sodium pyrosulfite [SMBS]: Na 2 S 2 O 5 Sodium bisulfate OR: 2NaHSO 3 + 2HOCl --> H 2 SO 4 + 2HCl + Na 2 SO 4 Sodium sulfate Sodium bisulfite / Sodium metabisulfite
© 2011 Atlantium Technologies Ltd. 34 Ultraviolet Photon Bullets
© 2011 Atlantium Technologies Ltd. 35 Free-Cl concentration vs. time UV-on UV-off
© 2011 Atlantium Technologies Ltd. 36 Out-in Ratio vs. UV-Dose
© 2011 Atlantium Technologies Ltd. 37 HACH DR/890
© 2011 Atlantium Technologies Ltd. Validation with third party De-Chlorination 38
© 2011 Atlantium Technologies Ltd. 39 Light-based De-Chlorination – Very clean Extreme disinfection – bonus Summary
© 2011 Atlantium Technologies Ltd. Atlantium Technologies Ltd. Har Tuv Industrial Park POB 11071, Israel Tel: Fax: Thank You Bob English Dechlorinate and
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