2Group Theory II Today Repetition Block matrices Character tables The great and little orthogonality theoremsIrreducible representationsBasis functions and Mulliken symbolsHow to find the symmetry speciesProjection operatorApplications
3Repetition We already know… Symmetry operations obey the laws of group theory.Great, we can use the mathematics of group theory.A symmetry operation can be represented by a matrix operating on a base set describing the molecule.Different basis sets can be choosen, they are connected by similarity transformations.For different basis sets the matrices describing the symmetry operations look different. However, their character (trace) is the same!
4Repetition We already know… Matrix representations of symmetry operations can often be reduced into block matrices. Similarity transformations may help to reduce representations further. The goal is to find the irreducible representation, the only representation that can not be reduced further.The same ”type” of operations (rotations, reflections etc) belong to the same class. Formally R and R’ belong to the same class if there is a symmetry operation S such that R’=S-1RS. Symmetry operations of the same class will always have the same character.
6Block MatricesIf a matrix representing a symmetry operation is transformed into block diagonal form then each little block is also a representation of the operation since they obey the same multiplication laws.When a matrix can not be reduced further we have reached the irreducible representation. The number of reducible representations of symmetry operations is infinite but there is a small finite number of irreducible representations.The number of irreducible representations is always equal to the number of classes of the symmetry point group.
7Group Theory IIReducing big matrices to block diagonal form is always possible but not easy. Fortunately we do not have to do this ourselves.As stated before all representations of a certain symmetry operation have the same character and we will work with them rather than the matrices themselves. The characters of different irreducible representations of point groups are found in character tables. Character tables can easily be found in textbooks.
8Character Tables The C3v character table Symmetry operations The order h is 6There are 3 classesIrreducible representations
9Character TablesOperations belonging to the same class will have the same character so we can write:ClassesIrreducible representations (symmetry species)
10The Great Orthogonality Theorem ”Consider a group of order h, and let D(l)(R) be the representative of the operation R in a dl-dimensional irreducible representation of symmetry species G(l) of the group. Then”Read more about it in section 5.10.
11The Little Orthogonality Theorem Here’s a smaller one,where c(l)(R) is the character of the operation (R). Or even more simple if the number of symmetry operations in a class c is g(c). Thensince all operations belonging to the same class have the same character.
12character TablesThere is a number of useful properties of character tables:The sum of the squares of the dimensionality of all the irreducible representations is equal to the order of the groupThe sum of the squares of the absolute values of characters of any irreducible representation is equal to the order of the group.The sum of the products of the corresponding characters of any two different irreducible representations of the same group is zero.The characters of all matrices belonging to the operations in the same class are identical in a given irreducible representation.The number of irreducible representations in a group is equal to the number of classes of that group.
13Irreducible representations Each irreducible representation of a group has a label called a symmetry species, generally noted G. When the type of irreducible representation is determined it is assigned a Mulliken symbol:One-dimensional irreducible representations are called A or B.Two-dimensional irreducible representations are called E.Three-dimensional irreducible representations are called T (F).The basis for an irreducible representation is said to span the irreducible representation.Don’t mistake the operation E for the Mulliken symbol E!
14Irreducible representations The difference between A and B is that the character for a rotation Cn is always 1 for A and -1 for B.The subscripts 1, 2, 3 etc. are arbitrary labels.Subscripts g and u stands for gerade and ungerade, meaning symmetric or antisymmetric with respect to inversion.Superscripts ’ and ’’ denotes symmetry or antisymmetry with respect to reflection through a horizontal mirror plane.
15character Tables Example: The complete C4v character table These are basis functions for the irreducible representations. They have the same symmetry properties as the atomic orbitals with the same names.
16character Tables Example: The complete C4v character table A1 transforms like z.E does nothing, C4 rotates 90o about the z-axis, C2 rotates 180o about the z-axis, sv reflects in vertical plane and sd in a diagonal plane.
17character Tables A2 transforms like a rotation around z. sv E -Rz +Rz sd-RzC4+Rz
18Reducible to Irreducible representation Given a general set of basis functions describing a molecule, how do we find the symmetry species of the irreducible representations they span?
19Reducible to Irreducible representation If we have an interesting molecule there is often a natural choice of basis. It could be cartesian coordinates or something more clever.From the basis we can construct the matrix representations of the symmetry operations of the point group of the molecule and calculate the characters of the representations.
20Reducible to Irreducible representation How do we find the irreducible representation?Let’s use an old example from two weeks ago:123NC3v in the basis (Sn, S1, S2, S3)To find the characters of the symmetry operations we look at how many basis elements ”fall onto themselves” (or their negative self) after the symmetry operation.C3: c=1sv: c=2E: c=4
21Reducible to Irreducible representation 123NSo C3v in the basis (Sn, S1, S2, S3) will have the following characters for the different symmetry operations.
22Reducible to Irreducible representation 123NSo C3v in the basis (Sn, S1, S2, S3) will have the following characters for the different symmetry operations.Let’s add the character table of the irreducible representationBy inspection we findGred=2A1+E
23Reducible to Irreducible representation The decomposition of any reducible representation into irreducible ones is uniqe, so if you find combination that works it is right.If decomposition by inspection does not work we have to use results from the great and little orthogonality theorems (unless we have an infinite group).
24Reducible to Irreducible representation From LOT we can derive the expression (see section 5.10)where ai is the number of times the irreducible representation Gi appears in Gred, h the order of the group, l an operation of the group, g(c) the number of symmetry operations in the class of l, cred the character of the operation l in the reducible representation and ci the character of l in the irreducible representation.
25Reducible to Irreducible representation Let’s go back to our example again.So once again we find Gred=2A1+E
26Projection Operator Symmetry-adapted bases The projection operator takes non-symmetry-adapted basis of a representation and and projects it along new directions so that it belongs to a specific irreducible representation of the group.^where Pl is the projection operator of the irreducible representation l, c(l) is the character of the operation R for the representation l and R means application of R to our original basis component.^
27Can all of this actually be useful? Applications?Can all of this actually be useful?Yes, in many areas for example when studying electronic structure of atoms and molecules, chemical reactions, crystallography, string theory (Lie-algebra) etc…Let’s look at one simple example concering molecular vibrations. Martin Jönsson will tell you a lot more in a couple of weeks.
28Molecular Vibrations Water Molecular vibrations can always be decomposed into quite simplecomponents called normal modes.Water has 9 normal modes of which 3 are translational, 3 are rotational and 3 are the actual vibrations.Each normal mode forms a basis for an irreducible representation of the molecule.
29Molecular Vibrations x1 x3 x2 y1 y2 y3 z1 z2 z3 First find a basis for the molecule. Let’s take the cartesian coordinates for each atom.Water belongs to the C2v group whichcontains the operations E, C2, sv(xz) and sv’(yz).The representation becomesE C2 sv(xz) sv’(yz)Gred9-113
30Molecular Vibrations Character table for C2v. Now reduce Gred to a sum of irreducible representations. Use inspection or the formula.
31Molecular Vibrations The representation reduces to Gred=3A1+A2+2B1+3B2 Gtrans= A1+B1+B2Grot=A2+B1+B2Gvib=2A1+B2Modes left for vibrations
32Molecular VibrationsModes with translational symmetry will be infrared active while modes with x2, y2 or z2 symmetry are Raman active.Thus water which has the vibrational modes Gvib=2A1+B2 will be both IR and Raman active.
33Integrals A last example… Integrals of product functions often appear in for example quantum mechanics and symmetry analysis can be helpful with them to.An integral will be non-zero only if the integrand belongs to the totally symmetric irreducible representation of the molecular point group.
34SummaryMolecules (and their electronic orbitals, vibrations etc) are invariant under certain symmetry operations.The symmetry operations can be described by a representation determined by the basis we choose to describe the molecule.The representation can be broken up into its symmetry species (irreducible representations).In character tables we find information about the symmetry properties of the irreducible representations.
35More (and better) reading The group theory chapter in Atkins is not very good (in my opinion). More understandable descriptions can be found in:Harris and Bertolucci, Symmetry and spectroscopyHargittai and Hargittai, Symmetry through the eyes of a chemist