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PPRC Regional Roundtable Chemical Compliance Systems, Inc. Poulsbo, WA October 5-6, 2010 Lake Hopatcong, NJ CCS.

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Presentation on theme: "PPRC Regional Roundtable Chemical Compliance Systems, Inc. Poulsbo, WA October 5-6, 2010 Lake Hopatcong, NJ CCS."— Presentation transcript:

1 PPRC Regional Roundtable Chemical Compliance Systems, Inc. Poulsbo, WA October 5-6, 2010 Lake Hopatcong, NJ CCS

2 California Green Chemistry Initiative (2007) GOAL Change the way business is conducted in California Cradle to Cradle Pending National Standard (ANSI) 2010 GOAL Define green chemical characteristics and manufacturing factors Green Chemistry Legislation Pending Other States GOAL Model after California (?) Green Standards – Current Status Individual Company Initiatives (Beiersdorf AG, Proctor & Gamble, Wal-Mart) GOAL Evaluate Their Supply Chain/Finished Products

3 CAS# DOT# 2029 HYDRAZINE F22 94 CM PK22 ENVIRO FIRE REACT HEALTH EXP Year Received and Disposal Code 7. Special Health Hazard Indicator C (Carcinogen)T (Teratogen) M (Mutagen) N (Neurotoxin) 8. Recommended PPE (symbols not overprinted) 9. SAF-T-Storage Code GROUND VENTILATE WASH GLOVES CLOTHING CARTRIDGE GOGGLES SPECIAL 1. Chemical Name 2. CAS Registry Number 3. DOT ID Number 4. Hazard Ratings (0-Minimal, 4-Severe) Fire-Health (Short Term-Long Term) Reactivity-Environmental (Air-Water-Soil) 5. Special Hazard Indicator OXY (Oxidizer)EXP (Explosive) RAD (Radioactive)-W- (Water Reactive) 8 Reading the CCS SAF-T-LABEL

4 CCS Databases Published in 1990 / Handbook in 1995

5 CCS Relational Chemical and Product Database (R-CPD) Statistics Years of Data Compilation – Ongoing Daily 75,000, ,000 >1,000,000+ >10,000 10,000+ 1, Data Elements Chemicals Product MSDSs Manufacturers Munitions (DoD / UK / Canada / NATO) Public Data Sources Chemical Regulatory Lists

6 Cross Reference Dictionary Physical/Chemical Chemical Names Common Names Foreign Names Numeric Identifiers Health Safety Ecological Alternatives Elemental Composition Redox Potential Pka/Pkb Log Koc Log Kow Other Constants Acute Chronic Incompatibilities Spill Codes Disposal Codes Storage Codes Toxicity Pesticides Long-term Effects Persistence Exposure Green Acids Antioxidants Bases Binders Chelators Oxidizers Propellants Reducers Solvents Surfactants UV Absorbers Viscosity Agents Other (~30) Ecological Health Safety Available Resources – CCS Relational Chemical and Product Database (R–CPD) U.S. EPA U.S. DOL U.S. DOT U.S. FDA U.S. Other States Canada Europe Pacific Rim International Compounds CCS Compiled Manufacturers Composition Description Generic Categories Inventories Alloys MSDS Links MIDAS OB/OD Emissions Live Fire Emissions Eco-Risk Species Factors Wildlife Toxicity Dietary Considerations Ingestion Rates Bioconcentration Bioaccumlation Biotransfer Regulatory Product Munition Chemical CCS Relational Chemical and Product Database (R–CPD) Elements

7 Munitions & Demilitarization Green Capability Status 2003 Specified 43 Green Chemical Characteristic Criteria 2003 Implemented Web-based Green Munitions Analytical Compliance System (G-MACS) Existing Munitions Evaluate Capability New Munitions Design Capability Applicable to Any Type Product (e.g., Furniture, Cosmetics, etc.) Utilized By All JMC Demil Sites Since 2003 (13 8) Interest from 9 NATO Countries Interest from NASA Interest from Industry (e.g., Chemicals, Cosmetics, Furniture)

8 Significance of each sub-score can be individually weighted HEALTH SCORE [people] (0-100%) HEALTH SCORE [people] (0-100%) SAFETY SCORE [people] (0-100%) SAFETY SCORE [people] (0-100%) FINAL GREEN GRADE ( %) FINAL GREEN GRADE ( %) ECOLOGICAL SCORE [planet] (0-100%) ECOLOGICAL SCORE [planet] (0-100%) 43 Endpoint Criteria LONG-TERM EFFECTS - SOIL Groundwater Mobility Factor CERCLA RQ TOXICITY-WATER Fish LC50 Daphae LC50 Green Algae EC50 (Solubility W-LC50) BCF LONG-TERM EFFECTS - WATER Eutrophication Theoretical Oxygen Demand LONG-TERM EFFECTS - AIR Global Warming Potential Ozone-Depleting Potential Smog Acidification TOXICITY - AIR (V.P. LC50) BCF TOXICITY - SOIL (K oc O-LD50) BCF 14-day Worm LC50 Persistence Exposure Toxicity Long-Term Effects Persistence Exposure Toxicity Long-Term Effects Persistence Exposure Toxicity Long-Term Effects Water Score Air Score Soil Score Explosivity Reactivity Score Chronic Health Score FLAMMABILITY Flash Point Boiling Point Flammability Fire Score Oral LD50 Dermal LD50 IDLH STEL/Ceiling Inhalation LC50 Skin Irritation Eye Irritation Odor Threshold Value Acute Health Score Reproductive Effects Carcinogenicity RfC RfD Radioactivity Sensitizer Neurotoxicity TLV Radioactivity Oxidizer Water-Reactive Corrosive Special Score GREEN SCORING PROCESS Munitions – Chemicals – Products – Processes – Wastestreams 10 Web-based Modules 42/43 ENDPOINTS IN THE DRAFT NATIONAL STANDARD

9 Combined COC Ratings & Composite Rankings

10 Ecological Score: (33.34% AW) (65 Pass/Fail) Water Score: (33.34% AW) (65 Pass/Fail) Persistence: (25%AW) (65 Pass/Fail) Exposure: (25%AW) (65 Pass/Fail) Toxicity: (25%AW) (65 Pass/Fail) Long-Term Effects: (25%AW) (65 Pass/Fail) Air Score: (33.33% AW) (65 Pass/Fail) Persistence: (25%AW) (65 Pass/Fail) Exposure: (25%AW) (65 Pass/Fail) Toxicity: (25%AW) (65 Pass/Fail) Long-Term Effects: (25%AW) (65 Pass/Fail) Soil Score: (33.33% AW) (65 Pass/Fail) Persistence: (25%AW) (65 Pass/Fail) Exposure: (25%AW) (65 Pass/Fail) Toxicity: 100 (25%AW) (65 Pass/Fail) Long-Term Effects: (25%AW) (65 Pass/Fail) Health Score: 87.3 (33.33% AW) (65 Pass/Fail) Acute Health Score: (50.% AW) (65 Pass/Fail) Oral LD50: 81.9 (12.5% AW) (65 Pass/Fail) Dermal LD50: (12.5% AW) (65 Pass/Fail) IDLH: (12.5% AW) (65 Pass/Fail) STEL/Ceiling: (12.5% AW) (65 Pass/Fail) Inhalation LC50: 100 (12.5% AW) (65 Pass/Fail) Skin Irritation: (12.5% AW) (65 Pass/Fail) Eye Irritation: (12.5% AW) (65 Pass/Fail) Odor Threshold Value: (12.5% AW) (65 Pass/Fail) Chronic Health Score: (50% AW) (65 Pass/Fail) Reproductive Effects: (12.5% AW) (65 Pass/Fail) Carcinogenicity: (12.5% AW) (65 Pass/Fail) RfC: (12.5% AW) (65 Pass/Fail) RfD: (12.5% AW) (65 Pass/Fail) Radioactivity: 100 (12.5% AW) (65 Pass/Fail) Sensitizer: (12.5% AW) (65 Pass/Fail) Neurotoxicity: (12.5% AW) (65 Pass/Fail) TLV: (12.5% AW) (65 Pass/Fail) Safety Score: (33.33% AW) (65 Pass/Fail) Fire Score: (33.33% AW) (65 Pass/Fail) Flammability: (100% AW) (65 Pass/Fail) Special Score: (33.34% AW) (65 Pass/Fail) Radioactivity: 100 (25% AW) (65 Pass/Fail) Oxidizer: (25% AW) (65 Pass/Fail) Water-Reactive: (25% AW) (65 Pass/Fail) Corrosive: 100 (25% AW) (65 Pass/Fail) Reactivity Score: (33.33% AW) (65 Pass/Fail) Explosivity/Unstability/Shock Sensitivity/Heat/Pressure Sensitivity: (100% AW) (65 Pass/Fail) G-MACS Green Grade Report Card for MIDAS Library Munition DOCUMENT DESTROYER INCND M3 NSN: DODIC: M605 Adjustable Weight Standard Final Green Grade (100%)

11 Munition: DOCUMENT DESTROYER INCND M3 Ecological Score: (65/Pass/Fail) Water Score: (33.34%) (65 Pass/Fail) Persistence: (25%)Exposure: (25%)Toxicity: (25%)Long-Term Effect: (25%) ScorePass/FailScorePass/FailScorePass/FailScorePass/Fail Air Score: (33.33%) (65 Pass/Fail) Persistence: (25%)Exposure: (25%)Toxicity: (25%)Long-Term Effect: (25%) ScorePass/FailScorePass/FailScorePass/FailScorePass/Fail Soil Score: (33.33%) (65 Pass/Fail) Persistence: (25%)Exposure: (25%)Toxicity: (25%)Long-Term Effect: (25%) ScorePass/FailScorePass/FailScorePass/FailScorePass/Fail CAS# Chemical: Formaldehyde Percentage: <0.01% Weight: (Lbs) Master: Enamel Gry (45) Ecological Score: 55.1 (65 Pass/Fail) Water Score: (33.34%) (65 Pass/Fail) Persistence: (25%) Exposure: (25%) Toxicity: (25%) Long-Term Effect: (25%) Air Score: (33.33%) (65 Pass/Fail) Persistence: (25%) Exposure: (25%) Toxicity: (25%) Long-Term Effect: (25%) Soil Score: (33.33%) (65 Pass/Fail) Persistence: (25%) Exposure: (25%) Toxicity: (25%) Long-Term Effect: (25%) Detail Chemical List (partial) Sort by: Ecological Score

12 Chemical Constituents in Munition: DOCUMENT DESTROYER INCND M3 Sort by: Ecological - Soil Score Pass/Fail Standard: 65 CAS#ChemicalScore%Weight in Lbs.Master Name Master SEQ# Formaldehyde57.28< Enamel Gry Chromic Acid58.35< Chromate Coating Pb Thiocyanate58.87< Primer Mix Ba Nitrate59.12< Primer Mix Lead61.03< Pb Alloy, Zn Alloy, Brass, Brass, Brass 90,124,255,2 68, Na Nitrate Ign chg, Oxidizing Agent #3 Chg 1 405, K Perchlorate61.35< Ign Comp Methyl Isobutyl Keto Adhesive, Adhesive, Shellac,Shellac 13,68, 262, Propyleneglycol Mono64.05< Enamel Gry Chromium Stainless Wire, Steel, Al Alloy, Steel 3,182, 203, Cadmium64.10< Zn Alloy, CD Coating124, Isobutyl Alcohol Enamel Gry, Enamel Red45, Isopropyl Alcohol64.62< Enamel Gry Methyl Ethyl Ketone65.75< Adhesive13

13 Detailed Chemical Data (partial list) Chemical: SODIUM NITRATE CAS No: FamilyInorganic salt DescriptionColorless Crystals or Powder FormulaFormula: Na-N-03 Extend Formula: Formula Weight: PhysicalPhysical State: S Physical Description: Odorless, colorless-to-white crystals or powder Purity100PH:0 RTECSWC ALPHAWR IncompatibilityMetals, Barium, Compounds, Metallic Powders Flash PointFlash Point: 0 Flash Point Method: Flash Point Modifier: Gravity2.26Density2.26 Melting PointLower: 5.85 Upper: 0 UOM: F Water o C (77 o F) Boiling Point380 o C (716 o F)Vapor Pressure0 IDLH PPM0IDLH MGM30 Volatile0Odor Index0 Chemical WeaponFalseCW PrecursorFalse Fluka StorageLight Sensitive: False Moist Sensitive: False Hygroscopic: False LogPac Lower: 0 Pac Upper: 0 RTI-P: 0 BCF: 316 Lake DaysBiod: 0 Photo: 0 Hydro: 0 PropertyToxic: True High_toxic: False Teratogen: False Mutagen: False Carcinogen: False Neurotoxin: False Flammable: False Reactive: False Water Reactive: False Explosive: False Irritant: True Corrosive: False Stench: False Radioactive: False Radiotoxic: False

14 Ecological Score: (33.34% AW) (65 Pass/Fail) Water Score: (33.34% AW) (65 Pass/Fail) Persistence: 98 (25% AW) (65 Pass/Fail) Exposure: (25% AW) (65 Pass/Fail) Toxicity: (25% AW) (65 Pass/Fail) Long-Term Effects: (25% AW) (65 Pass/Fail) Air Score: (33.33% AW) (65 Pass/Fail) Persistence: (25% AW) (65 Pass/Fail) Exposure: 99.6 (25% AW) (65 Pass/Fail) Toxicity: (25% AW) (65 Pass/Fail) Long-Term Effects: (25% AW) (65 Pass/Fail) Soil Score: (33.33% AW) (65 Pass/Fail) Persistence: 98 (25% AW) (65 Pass/Fail) Exposure: (25% AW) (65 Pass/Fail) Toxicity: 100 (25% AW) (65 Pass/Fail) Long-Term Effects: 98 (25% AW) (65 Pass/Fail) Health Score: (33.33% AW) (65 Pass/Fail) Acute Health Score: (50.% AW) (65 Pass/Fail) Oral LD50: (12.5% AW) (65 Pass/Fail) Dermal LD50: 100 (12.5% AW) (65 Pass/Fail) IDLH: (12.5% AW) (65 Pass/Fail) STEL/Ceiling: 100 (12.5% AW) (65 Pass/Fail) Inhalation LC50: 100 (12.5% AW) (65 Pass/Fail) Skin Irritation: 96 (12.5% AW) (65 Pass/Fail) Eye Irritation: 97 (12.5% AW) (65 Pass/Fail) Odor Threshold Value: 100 (12.5% AW) (65 Pass/Fail) Chronic Health Score: (50% AW) (65 Pass/Fail) Reproductive Effects: 100 (12.5% AW) (65 Pass/Fail) Carcinogenicity: 100 (12.5% AW) (65 Pass/Fail) RfC: 99.2 (12.5% AW) (65 Pass/Fail) RfD: 99.2 (12.5% AW) (65 Pass/Fail) Radioactivity: 100 (12.5% AW) (65 Pass/Fail) Sensitizer: (12.5% AW) (65 Pass/Fail) Neurotoxicity: 96 (12.5% AW) (65 Pass/Fail) TLV: (12.5% AW) (65 Pass/Fail) Safety Score: 99 (33.33% AW) (65 Pass/Fail) Fire Score: 97 (33.33% AW) (65 Pass/Fail) Flammability: 97 (100% AW) (65 Pass/Fail) Special Score: 100 (33.34% AW) (65 Pass/Fail) Radioactivity: 100 (25% AW) (65 Pass/Fail) Oxidizer: 100 (25% AW) (65 Pass/Fail) Water-Reactive: 100 (25% AW) (65 Pass/Fail) Corrosive: 100 (25% AW) (65 Pass/Fail) Reactivity Score: 100 (33.33% AW) (65 Pass/Fail) Explosivity/Unstability/Shock Sensitivity/Heat/Pressure Sensitivity: 100 (100% AW) (65 Pass/Fail) GP-CAS Green Grade Report Card for Product Index Product Foam Care Skin Care Product; Hand Scrub; Antimicrobial Skin Cleanser Adjustable Weight Standard Manufacturer Kimberly-Clark Corporation Final Green Grade (100%)

15 Ecological Score: (33.34% AW) (65 Pass/Fail) Water Score: (33.34% AW) (65 Pass/Fail) Persistence: 50 (25% AW) (65 Pass/Fail) Exposure: (25% AW) (65 Pass/Fail) Toxicity: (25% AW) (65 Pass/Fail) Long-Term Effects: (25% AW) (65 Pass/Fail) Air Score: (33.33% AW) (65 Pass/Fail) Persistence: (25% AW) (65 Pass/Fail) Exposure: 62.6 (25% AW) (65 Pass/Fail) Toxicity: (25% AW) (65 Pass/Fail) Long-Term Effects: 93.2 (25% AW) (65 Pass/Fail) Soil Score: (33.33% AW) (65 Pass/Fail) Persistence: 50 (25% AW) (65 Pass/Fail) Exposure: (25% AW) (65 Pass/Fail) Toxicity: (25% AW) (65 Pass/Fail) Long-Term Effects: (25% AW) (65 Pass/Fail) Health Score: (33.33% AW) (65 Pass/Fail) Acute Health Score: (50.% AW) (65 Pass/Fail) Oral LD50: (12.5% AW) (65 Pass/Fail) Dermal LD50: (12.5% AW) (65 Pass/Fail) IDLH: (12.5% AW) (65 Pass/Fail) STEL/Ceiling: (12.5% AW) (65 Pass/Fail) Inhalation LC50: 100 (12.5% AW) (65 Pass/Fail) Skin Irritation: 37 (12.5% AW) (65 Pass/Fail) Eye Irritation: 37 (12.5% AW) (65 Pass/Fail) Odor Threshold Value: (12.5% AW) (65 Pass/Fail) Chronic Health Score: (50% AW) (65 Pass/Fail) Reproductive Effects: 60 (12.5% AW) (65 Pass/Fail) Carcinogenicity: 100 (12.5% AW) (65 Pass/Fail) RfC: (12.5% AW) (65 Pass/Fail) RfD: (12.5% AW) (65 Pass/Fail) Radioactivity: 100 (12.5% AW) (65 Pass/Fail) Sensitizer: 100 (12.5% AW) (65 Pass/Fail) Neurotoxicity: 16 (12.5% AW) (65 Pass/Fail) TLV: (12.5% AW) (65 Pass/Fail) Safety Score: (33.33% AW) (65 Pass/Fail) Fire Score: 21 (33.33% AW) (65 Pass/Fail) Flammability: 21 (100% AW) (65 Pass/Fail) Special Score: 100 (33.34% AW) (65 Pass/Fail) Radioactivity: 100 (25% AW) (65 Pass/Fail) Oxidizer: 100 (25% AW) (65 Pass/Fail) Water-Reactive: 100 (25% AW) (65 Pass/Fail) Corrosive: 100 (25% AW) (65 Pass/Fail) Reactivity Score: 100 (33.33% AW) (65 Pass/Fail) Explosivity/Unstability/Shock Sensitivity/Heat/Pressure Sensitivity: 100 (100% AW) (65 Pass/Fail) GP-CAS Green Grade Report Card for Product Index Product Yellow Spray Stencil Ink Adjustable Weight Standard Manufacturer Ideal Stencil Machine & Tape Co. Final Green Grade (100%)

16 Objective & Quantitative Equivalent Product Comparisons Automotive Degreasers Green Grade PRODUCT MANUFACTURER Degreaser #1 Degreaser #2 Eco Score Water Score (4) Air Score (4) Health Score Acute Score (8) Chronic Score (8) Soil Score (4) Safety Score Fire Score (1) Special Score (4) Reactivity Score (1)

17 Green Product Assessment Parameters NSNs = Functionally equivalent products 5 NSNs Selected from USN Facility Inventory –7917Sealants [A] 3 Products –6050Varnish, Fungus Resistant 3 Products –2487Spray Lacquer 9 Products –4597Sealants [B]10 Products –6890Spray Adhesive10 Products 35 Products GP–CAS Green Scoring Criteria

18 Summarized Green Comparison for Five N.I. NSNs LOLsConstituents NSN Product Type No. of Products Green Grades Noteworthy Low ScoresUniqueTotalNo.Total % – 2487Lacquer975–79 (4) a Fire15–46 (9) Chronic Health61–66 (4) Eco – Water62 (1) 8–916–633–1184–110 – 6950FR Varnish379–90 (11) Fire18–55 (3)7–912–2 73–1152–173 – 4597Sealant1087–100 (13) Eco – Soil79 (1)1–111–261–62–120 – 7917Sealant385–99 (14) Safety63 (1) b Fire55 (1) React39 (1) 5–75–101–43–110 – 6860Spray Adhesive 1075–99 (24) Fire10–37 (6)88–212–54–100 a Range spread (in %) b Number of products within this NSN

19 NSN: (SPRAY ADHESIVE) PRODUCTMSDSGREEN GRADE (0–100%) MANUFACTURERNAME# CHEMsTOTAL % 3M CompanySpray Adhesive Camie-Campbell Inc.General Purpose Adhesive Spray National Aerosol ProductsMMM-1058A Adhesive Contact IndustriesMultipurpose Spray-On Adhesive Plasti-KoteMultipurpose Spray-On Adhesive MMM-A-1058A LHB IndustriesMMM-A-1058A Rubber Adhesive LHB IndustriesSo-Sure Rubber Adhesive #532D LHB IndustriesMMM-A-1058 Rubber Adhesive Camie-Campbell Inc.L-6261 GSA Adhesive M Company3M Super 77 Spray Adhesive

20 GP–CAS Cleaning Product Assessments for Concentrates & Ready-to-Use Products Green Grades ConcentrateRTU 1. High density caustic-based solid auto dishwash product Alkaline (non-caustic) solid auto dishwash product High density one shot liquid caustic based laundry detergent Laundry detergent boosted with sustainable surfactant options Alkaline one shot non-caustic liquid laundry detergent, with phosphates Greener alternative to Formula 5 without phosphates Green Seal-certified all purpose cleaner (concentrate for dilution) Green Seal-certified all purpose cleaner (concentrate for dilution) Green Seal-certified all purpose cleaner (concentrate for dilution) Chlorinated alkaline high density cleaner with phosphates (concentrate for dilution) Ready-to-use chlorinated alkaline bathroom cleaner Same as Formula 11 (no chlorine)--99.4

21 GP–CAS Solvent Assessments for Concentrates and Dilutions Solvent GREEN GRADES Concentrate10%1% 2-butoxyethanol Propylene Glycol Methyl Ether butoxypropanol

22 Adjustable Weight List: Preferred Process Name Re-Cal Chem % Overall Assessment Green Grade (100%) Eco (33.34%) (65 Pass/Fail) Health (33.33%) (65 Pass/Fail) Safety (33.33%) (65 Pass/Fail) Regulatory (LOLs) CCS_PROCESS 1 (Chemical of Concern) Manufactured by CCS 0MOST GREEN CCS_PROCESS 2 (Chemical of Concern) Manufactured by CCS 0LEAST GREEN G–PACS Process Comparison

23 Adjustable Weight List: Preferred Process Name Re-Cal Chem % Overall Assessment Green Grade (100%) Eco (33.34%) (65 Pass/Fail) Health (33.33%) (65 Pass/Fail) Safety (33.33%) (65 Pass/Fail) Regulatory (LOLs) CCS_PROCESS 1 (Chemical of Concern) Manufactured by CCS 100MOST GREEN Step 1 (Compatibility) Step 2 (Compatibility) Step 3 (Compatibility) Step 4 (Compatibility) Step 5 (Compatibility) Step 6 (Compatibility) Step 7 (Compatibility) Step 8 (Compatibility) CCS_PROCESS 2 (Chemical of Concern) Manufactured by CCS 100LEAST GREEN G–PACS Step Evaluation

24 Adjustable Weight List: Preferred Process Name Re-Cal Chem % Overall Assessment Green Grade (100%) Eco (33.34%) (65 Pass/Fail) Health (33.33%) (65 Pass/Fail) Safety (33.33%) (65 Pass/Fail) Regulatory (LOLs) CCS_PROCESS 1 (Chemical of Concern) Manufactured by CCS 0MOST GREEN Step 1 (Compatibility)0N/A Step 2 (Compatibility)0N/A Step 3 (Compatibility) TOLUENE CAS# (Values)(Synonyms)(Phys.Property)(Alternative) POTASSIUM TERT-BUTOXIDE CAS# (Values)(Synonyms)(Phys.Property)(Alternative) Step 4 (Compatibility)077.22N/A Step 5 (Compatibility)077.63N/A Step 6 (Compatibility)096.86N/A Step 7 (Compatibility)097.62N/A Step 8 (Compatibility)096.04N/A CCS_PROCESS 2 (Chemical of Concern) Manufactured by CCS 0LEAST GREEN G–PACS Alternative Chemicals [1]

25 42 Alternative Chemical Constituent Generic Categories ChemicalGeneric Category 8Abrasives 34Absorbents 1555Acids 304Additives 3982Alloys 1Anticorrosives 13Antidandruff Agents 15Antifoaming Agents 104Antimicrobials 48Antioxidants 25Antiperspirants 826Antistatic Agents 90Bases 68Binders ChemicalGeneric Category 199Biological Additives 3Bleaching Agents 496Botanicals 76Buffering Agents 44Chelating Agents 207Colorants 26Denaturants 36Deodorants 20Dipilating Agents 985Emollients 112Emulsion Stabilizers 269Film-Formers 245Hair Dyes 153Humectants ChemicalGeneric Category 407Ionic Liquids 90Opacifiers 43Oral Care Agents 913Oxidizing Agents 123Preservatives 13Propellants 28Reducing Agents 649Solvents 13Solvents-Chloro 74Solvents-FDA 141Solvents-NCI 394Surfactants 61UV Absorbers 113Viscosity Controlling Agents

26 G–PACS Alternative Chemicals [2]

27 G–PACS Alternative Chemicals [3]

28 Green Lifecycle Considerations (Within Each/Across All) Design New Constituents A L T E R N A T I V E S Manufacturing Precursor Materials Finished Manufactured Product Transport & Storage DisposalUsage Emissions Design Manufacturing Transportation & Storage UsageDisposal [Screening Test Data Requirements] [Product Specific] [Product Specific] GP–CAS Product (Design) Module Chemicals of Concern Module G–PACS Process Module GP–CAS Product (Evaluate) Module G–WACS Waste Module

29 Chemical or Product Green Grade (0 – 100%) Process Chemical Green Grade (0 – 100%) Process Engineering Green Grade (0 – 100%) [pending] Ecological Green Score Health Green Score Safety Green Score = Air + Water + Soil Green Scores = Acute + Chronic Health Green Scores = Fire + Reactivity + 4 Special Green Scores = 21 Endpoint Criteria = 16 Endpoint Criteria = 6 Endpoint Criteria Ecological Green Score Health Green Score Safety Green Score = Air + Water + Soil Green Scores = Acute + Chronic Health Green Scores = Fire + Reactivity + 4 Special Green Scores = 21 Endpoint Criteria = 16 Endpoint Criteria = 6 Endpoint Criteria + + Renewable Source Materials Green Score Process Mass Efficiency & Waste Green Score Energy Consumption Green Score Water Usage Green Score Process Safety Green Score GREEN SUSTAINABILITY GRADE (0–100%) = = = Ecological Green Score Health Green Score Safety Green Score = Air + Water + Soil Green Scores = Acute + Chronic Health Green Scores = Fire + Reactivity + 4 Special Green Scores = 21 Endpoint Criteria = 16 Endpoint Criteria = 6 Endpoint Criteria = + Integrated Green Chemical and Engineering Sustainability System = 6 Endpoint Criteria = 8 Endpoint Criteria = 5 Endpoint Criteria = 10 Endpoint Criteria Wastestream Green Grade (0 – 100%)

30 Summary SB 509 Requirements Chemical Hazard Traits and Environmental/Toxicological Endpoints Toxic Information Clearinghouse STATUS Utilized & Available Since 2003 Progressively Developed Since 2985 Currently 75 Million Data Elements 275,000 Chemicals Alternative Chemicals AB 1879 Requirements Identify & Prioritize Chemicals of Concern (COCs) Process for Evaluating COCs and Their Alternatives Utilized Since 2004 Public Access to Information Data Selection Screen Advisable Public Utilization of Processes Simpler Report Versions Customizable Natl Standard-Chemical Characteristics 90% Since 2003 Natl Standard-Process Green Engineering Pending

31 For a remote demonstration, or more information, please contact: Dr. George Thompson CHEMICAL COMPLIANCE SYSTEMS, INC. 706 Route 15 South, Suite 207 Lake Hopatcong, NJ CCS Thank You


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