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Materials Characterization at the 3 MV Tandetron Accelerator and at the 9 MV Tandem Accelerator.

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Presentation on theme: "Materials Characterization at the 3 MV Tandetron Accelerator and at the 9 MV Tandem Accelerator."— Presentation transcript:

1 Materials Characterization at the 3 MV Tandetron Accelerator and at the 9 MV Tandem Accelerator

2 ERDA, RBS, NRBS RBS/C F. Negoita, P. Ionescu, N. Scintee, G. Velisa, H. Petrascu, Cristina Roxana Nita, D. Pantelica

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7 (1) (2) For M 2 << M 1 excellent elemental resolution

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10 (1) (2) For M 2 << M 1 excellent elemental resolution

11 (1) (2) For M 2 << M 1 excellent elemental resolution

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13 (1) (2) For M 2 << M 1 excellent elemental resolution

14 (1) (2) For M 2 << M 1 excellent elemental resolution

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16 (1) (2) For M 2 << M 1 excellent elemental resolution

17 (1) (2) For M 2 << M 1 excellent elemental resolution a) b) Fig 3. RBS spectra of the specimen 1, measured with: a) a 4 He beam (E = MeV); b) a 10 B beam (E = 8 MeV)

18 (1) (2) For M 2 << M 1 excellent elemental resolution In Fig. 3a a NRA spectrum of the specimen 1, measured with a 4 He beam (E = MeV) is presented. An enhanced O peak at channel 160 is due to the oxygen contained in the PZT film. The result of a simulation using the RUMP code is presented with continuous line. The simulated and experimental curves show good agreement. The compositions and thicknesses of layers found in specimen 1 are the following: - PZT layer (composition: Pb 0.78 Zr 0.25 Ti 0.50 O 3 ; thickness: 1340 at/cm 2 ) - interfacial layer 1 (composition: Ti 0.02 O 0.1 Pt 0.5 ; thickness: 870 at/cm 2 ) - interfacial layer 2 (composition: TiO 2 ; thickness: 45 at/cm 2 ) - interfacial layer 3 (composition: SiO 2 ; thickness: 3850 at/cm 2 )

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20 (1) (2) For M 2 << M 1 excellent elemental resolution Activitatea de caracterizare a straturilor subtiri utilizind metode IBA s-a concretizat atit in participari la proiecte PNCDI cat si in participari la colaborari internationale: Contract CERES 88 Cercetari interdisciplinare folosind fascicule de particule accelerate Responsabil proiect: Dr. Dan Pantelica; Colaborare cu INCDFM, subcontract CERES 10/2001 Caracterizarea microstructurala avansata si prepararea unor straturi feroelectrice PZT cu orientari cristalografice selectate Responsabil proiect din partea IFIN-HH: Dr Dan Pantelica; Colaborare cu INCDFM, subcontract CERES 8/2001 Structuri cuantice semiconductoare Responsabil proiect din partea IFIN-HH: Dr.Dan Pantelica; Colaborare cu INCDFM, subcontract CERES 15/2001 Efecte cuantice de interfata in nanostructuri metal/C60 Responsabil proiect din partea IFIN-HH: Dr. Dan Pantelica; Colaborarea cu CSNSM-Orsay (Franta) Characterization of nuclear ceramics using Ion Beam Analysis Techniques; WP8 Characterization of surface layers of materials using RBS and ERDA techniques in cadrul Centrului de Excelenta IDRANAP al EU (FP5).

21 (1) (2) For M 2 << M 1 excellent elemental resolution Lucrari recente, contributii la conferinte: 1. M.Balaceanu, E.Grigore, F.Truica-Marasescu, D.Pantelica, F.Negoita, G.Pavelescu, F.Ionescu, Deposition of amorphous hydrogenated carbon nitride films by hollow cathode discharge process, Romanian Reports in Physics, Vol.51, Nos , P. 781–788, M.Balaceanu,E.Grigore, F.Truica-Marasescu, D.Pantelica, F.Negoita, G.Pavelescu, F.Ionescu, Characterization of carbon nitride films deposited by hollow cathode discharge process. Prezentata la IBA–14 International Conference on Ion Beam Analysis, 26–30 Iulie 1999 Dresden, Germany. Nucl. Instrum. and Meth. in Physics Research B161–163 (2000) 1002– A. Crunteanu, M.Charbonnier, M.Romand, F.Vasiliu, D.Pantelica, F.Negoita, R..Alexandrescu, Synthesis and characterization of carbon nitride thin films obtained by laser induced chemical vapor deposition. Prezentata la E-MRS (European-Materials Research Society) 1999 Spring Meeting Strasbourg, France, June 1-4, Surface and Coating Technology 125 (2000) 301– A. Crunteanu,M.Charbonnier,M.Romand,J.Mugnier,R.Alexandrescu,F.Negoita, D.Pantelica, Structural and vibrational characterization of hydrogenated carbon nitride thin films obtained by laser–induced CVD. Prezentata la E-MRS (European-Materials Research Society) 2000 Conference, Strasbourg, France, May 31-June 2, 2000 Applied Surface Science 6422 (2000) 1– 4.

22 (1) (2) For M 2 << M 1 excellent elemental resolution 5. R.V.Ghita, D.Pantelica, F.Negoita, S.Lazanu Characterization of anodic oxide for GaAs based laser diodes, Prezentata la ROMOPTO 2000: Sixth Conference on Optics, Bucharest, Romania, September 4-7, 2000 Proceedings of SPIE 4430,736 (2001). 6. A.Goldemblum, V.Teodorescu, F.Wagner, R.Manaila, G.Filoti, J.Deville, D.Pantelica, F.Negoita, A.Belu-Marian, N.Scintee, Structural properties of sputtered ZnO: Au films, Philosophical Magazine A82,193(2002). 7. M.F.Lazarescu, D.Pantelica, A.S.Manea, R.V.Ghita, F.Negoita Investigation of semi-insulating oxygen-doped GaAs, Prezentata la Thirteenth International Conference on Crystal Growth (ICCG-13) in conjunction with The Eleventh International Conference on Vapor Growth and Epitaxy (ICVGE-11), Doshisha University, Kyoto, Japan, 30 July-4 August, 2001 Journal of Crystal Growth 240,401 (2002). 8. E.A.Preoteasa, C.Ciortea, B.Constantinescu, D.Fluerasu, S.-E.Enescu, D.Pantelica, F.Negoita, E.Preoteasa Analysis of composites for restorative dentistry by PIXE, XRF and ERDA, Prezentata la The Ninth International Conference on Particle-Induced X-ray Emission (PIXE) and its Analytical Applications, Guelph, Canada, June 8-12, 2001 Nuclear Instruments and Methods in Physics Research B 189,426(2002). 9. L.E.Dinca, L.Gheorghe, A.Lupei, D.Pantelica, N.Scintee Growth, RBS-ERDA characterization and modelling in Nd3+-doped calcium-lithium-niobium- gallium garnett (CLNGG:Nd) crystal, Nuclear Instruments and Methods in Physics Research A 486, 93 (2002).

23 (1) (2) For M 2 << M 1 excellent elemental resolution 10. M.Balaceanu, M.Braic, D.Macovei, M.J.Genet, A.Manea, D.Pantelica, V.Braic, F.Negoita Properties of titanium based hard coatings deposited by cathodic arc method Journal of Optoelectronics and Advanced Materials, 4,107 (2002). 11. D.Pantelica, L.Thomé, S.E.Enescu, F.Negoita, P.Ionescu, I.Stefan, A.Gentils Ion beam characterization of He implanted into nuclear matrices Prezentata la IBA 16, Albuquerque, New Mexico, USA, June 29-July 4, 2003 Nucl. Instr. and Meth., B , 373 (2004). 12. D.Pantelica, F.Vasiliu, P.Ionescu, F.Negoita RBS, ERDA, TEM and SAED characterisation of sol-gel PZT films Prezentata la ECAART8 Conference September2004, Paris, France Acceptata spre publicare in Nucl. Instr. and Methods in Phys. Res. B. 13. D.Pantelica, P.Ionescu, F.Negoita, N.Scintee, L.Thome, S.Enescu, J.Jagielski Complementary use of ERDA and RBS/C for the determination of implanted atom and damage distribution in spinel. Prezentata la ECAART8 Conference September 2004, Paris, France Acceptata spre publicare in Nucl. Instr. and Methods in Phys. Res. B. 14. D. Pantelica, M. Petrascu, F. Negoita, N. Scintee, H. Petrascu, A. Isbasescu, I. Stefan, P. Ionescu Characterization of CNx and CNx:H thin layers using ERDA with heavy ions Proceedings of the International Conference on Applications of High Precision Atomic and Nuclear Methods, Neptun, Romania, 2-6 September E. A. Preoteasa, C. Ciortea, D. Fluerasu, D. Pantelica, F. Negoita, L. Haragus, A. Iordan, E. Preoteasa, M. Moldovan PIXE and ERDA analysis of composites for restorative dentistry Proceedings of the International Conference on Applications of High Precision Atomic and Nuclear Methods, Neptun, Romania, 2-6 September 2002.

24 Energy calibration. Comparison method He + + C Au Si D

25 Simulation of the experimental spectrum (previous measurements: January 2010)

26 K= ± keV·amu/e 2 ·MHz 2 The calibration constant obtained from previous measurements January 2010 and March 2011 July 1975-May 1976; December 1999(*) January 2010; March 2011 * K= ± keV·amu/e2·MHz2

27 Growth and characterisation of SrCuO 2 thin films C. N. Mihailescu 1,3 D. Pantelica 4, H.Petrascu 4, P. Ionescu 4, Cristina Roxana Nita 4 I. Athanasopoulos 1, R. Saint-Martin 2, A. Revcolevschi 2, J. Giapintzakis 1 1 Department of Mechanical and Manufacturing Engineering, University of Cyprus, 75 Kallipoleos Av., PO Box 20537, 1678 Nicosia, Cyprus 2 LPCES - ICMMO - Bât 410, Université Paris-Sud XI, 15 Georges Clémenceau St., Orsay Cedex, France 3 National Institute for Lasers, Plasma and Radiation Physics, Lasers Department 4 Horia Hulubei National Institute for Research and Development in Physics and Nuclear Engineering

28 Transition metal oxides (TMOs) exhibit a rich variety of novel properties, which can be exploited for a wide range of applications including ultra-high-density magnetic data storage, spintronics, quantum computing and more recently thermal management applications. Thin films of TMOs offer enormous opportunities to explore intriguing physics and also practical applications. The discovery of high Tc superconductivity in cuprates has increased in recent years the interest for low-dimensional Heisenberg magnetic systems. Among these, the compound SrCuO 2 (SCO) has drawn much attention. SCO in the orthorhombic structure, consisting of zigzag chains of Cu 2+ ions, has been recently shown to exhibit sizeable magnetic heat transport; while SCO in the tetragonal structure exhibits the simplest structure with superconducting CuO 2 planes (so called infinite layer compound). Depending on the phase and the orientation, SCO can then be used for different applications. While it has been possible to obtain bulk SCO only in the orthorhombic structure, in the thin film form this compound has only been stabilized in the tetragonal structure.

29 SrCuO2 (SCO) thin films were grown on (100) SrTiO3 and (100) MgO substrates. SrTiO3 substrates were treated with BHF etching to obtain a clean surface with TiO2 termination layer. Orthorhombic Structure Tetragonal Structure

30 Letter of Intent for Using the 3 MV and 9MV Tandems April 14, 2012 It is proposed to study the elemental composition depth profile, thickness and lattice defects in thin films of novel materials by ion beam techniques such as Rutherford Backscattering Spectroscopy (RBS), Elastic Recoil Detection Analysis (ERDA), Nuclear Reaction Analysis (NRA) and Proton Induced X-ray Emission (PIXE), taking advantage of both the existing 9MV Tandem and the new 3MV Tandem facilities present at the Horia Hulubei National Institute of Physics and Nuclear Engineering. The materials include mainly oxides such as LiCoO 2, SrCuO 2, La 5 Ca 9 Cu 24 O 41, VO 2 etc. Ioannis Giapintzakis, Professor Director of Nanotechnology Research Unit Department of Mechanical & Manufacturing Engineering School of Engineering University of Cyprus 75 Kallipoleos Av., PO Box Nicosia, Cyprus Tel.: Fax:

31 Letters of Intent INCDFM-Tandem Accelerators Corneliu Ghica (lab. 50) Comparison between quantitative analysis results obtained by analytical techniques in our laboratory (e.g. EDS, EELS) and complementary Ion Beam Analysis techniques: -thin films (mono- or multilayers) and nanopowders with low doping (<1%) or containing low atomic number Z (Z<11) elements; - concentration profiles in the case of thin films. Sergiu Nistor ( lab. 50) Ion beam analysis on: -ultrapure Si single crystal (FZ-floating zone) (platelets 20 x 20 x 0.3 mm 3 - orientation ) implanted with ions 13 C and 17 O; - cubic boron nitride single crystals (0.4 x 0.4 x 0.2 mm 3 ) for detection of the presence and concentration of natural impurities (Ca, Ba, Si, C) by microPIXE si PIGE techniques. Ion implantation of transition group elements (iron and rare earths) in single crystals and thin films pf boron nitride (cubic and/or hexagonal).

32 Letters of Intent INCDFM-Tandem Accelerators Ovidiu Crisan, (lab. 20) Florin Vasiliu Ion beam analysis for estimation of nitrogen and boron content in melt spun ribbons (system FePtNbB). Cristian M. Teodorescu (lab. 50) Ion beam analysis of metals deposited on semiconductor wafers at high temperature. Metal: Mn, Fe, Co, Co, Cu, Sm, Gd. Semiconductor: Si(001), Si(111), Ge(001), Ge(111), GaAs(001), rutile TiO2(011). Quantity deposited: nm of equivalent bulk metal. Expected concentrations: 5-50 %. Aim of the study: identification of interface alloys with ferromagnetic properties. Complementary method for composition and concentration profile validation: XPS/AES with depth profiling. Other studies: electron diffraction (LEED, RHEED), angle-resolved ultraviolet photoelectron spectroscopy (ARUPS), yielding experimental band structure, spin-resolved UPS, MOKE, SQUID (collaboration with Lab. 20), STM, HRTEM (collaboration with Lab. 50).

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