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Thermal and Plasma-Enhanced Atomic Layer Deposition on Powders and Particles Geert Rampelberg, Véronique Cremers, Delphine Longrie, Davy Deduytsche, Johan.

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Presentation on theme: "Thermal and Plasma-Enhanced Atomic Layer Deposition on Powders and Particles Geert Rampelberg, Véronique Cremers, Delphine Longrie, Davy Deduytsche, Johan."— Presentation transcript:

1 Thermal and Plasma-Enhanced Atomic Layer Deposition on Powders and Particles
Geert Rampelberg, Véronique Cremers, Delphine Longrie, Davy Deduytsche, Johan Haemers, Christophe Detavernier Belgian Physical Society General Scientific Meeting 2016 CoCooN Conformal Coating of Nanomaterials

2 Outline Atomic layer deposition Industrial applications
ALD on powders and particles Conclusions BPS – General Scientific Meeting 2016

3 Outline Atomic layer deposition Industrial applications
What is ALD? Plasma-enhanced ALD Advantages and limitations Examples of conformal nanocoatings by ALD Industrial applications ALD on powders and particles Conclusions BPS – General Scientific Meeting 2016

4 Atomic layer deposition
Gas-phase thin film deposition technique Cyclic process of self-limiting surface reactions  layer-by-layer growth Example : ALD growth of Al2O3 from trimethyl aluminum (TMA) and H2O TMA pulse Self-saturated chemisorption One layer of Al2O3 H2O pulse BPS – General Scientific Meeting 2016

5 Plasma-enhanced atomic layer deposition
Plasma: Highly energetic plasma species facilitate surface reactions More coating materials available Coating of temperature-sensitive substrates Cheaper chemicals ... TMA pulse Self-saturated chemisorption One layer of Al2O3 O2 plasma BPS – General Scientific Meeting 2016

6 Advantages and limitations
Growth rate from linear fit: 0.85Å/cycle Advantages: Excellent control of thickness BPS – General Scientific Meeting 2016

7 Advantages and limitations
Excellent control of thickness Stoichiometry determined by chemistry Limitations: Slow: ~1Å/cycle 2 Al(CH3) H2O  Al2O3 + 6 CH4 BPS – General Scientific Meeting 2016

8 Advantages and limitations
Excellent control of thickness Stoichiometry determined by chemistry Excellent uniformity Highest degree of conformality Sol-gel PVD CVD ALD BPS – General Scientific Meeting 2016

9 Advantages and limitations
Excellent control of thickness Stoichiometry determined by chemistry Excellent uniformity Highest degree of conformality Limitations: Slow: ~1Å/cycle Growth rate from linear fit: 0.85Å/cycle ALD = ideal technique for 3D surface engineering BPS – General Scientific Meeting 2016

10 Al2O3 coated paper ALD coated tissue paper
Thermal ALD, TMA + H2O, 50°C, 200 cycles. BPS – General Scientific Meeting 2016

11 Al2O3 coated paper After combustion of the cellulose template: hollow structure, consisting of freestanding 20nm Al2O3 ALD film. Direct, macroscopic illustration of the conformality of ALD, and of its potential for coating porous and fibrous materials. BPS – General Scientific Meeting 2016

12 ALD – a coating technique for the nano era
CNT V2O5 TiO2 TiO2/V2O5/TiO2 multilayer coating of a carbon nanotube TEM imaging by EMAT (UA) BPS – General Scientific Meeting 2016

13 Outline Atomic layer deposition Industrial applications
Microelectronics Solar energy Flexible electronics ALD on powders and particles Conclusions BPS – General Scientific Meeting 2016

14 Functional nanocoatings in micro-electronics
JACS 2008, 131 (10), 3478 DRAM Transistors Patterning Panasonic BPS – General Scientific Meeting 2016

15 Surface passivation in photovoltaics
Increased efficiency by enhanced lifetime of charge carriers Dedicated reactor design Batch ALD (Beneq): 2000 wafers/hour Spatial ALD (SolayTec, Levitech): 4500 wafers/hour BPS – General Scientific Meeting 2016

16 Roll-to-roll ALD Development of roll-to-roll ALD for ALD on flexible substrates Potential use in flexible electronics Beneq: 400,000m²/year (20nm Al2O3) BPS – General Scientific Meeting 2016

17 Outline Atomic layer deposition Industrial applications
ALD on powders and particles UGent rotary reactor Applications Conclusions BPS – General Scientific Meeting 2016

18 Powder coater at UGent Rotary reactor for powder agitation during gas-solid reactions First plasma-enhanced ALD powder coater In-situ characterization of reaction chemistry and saturation: Mass spectroscopy Optical emission spectroscopy BPS – General Scientific Meeting 2016

19 ALD coatings on a wide range of particle sizes
Both thermal and plasma enhanced ALD can be performed on a broad range of particle sizes: Nano ZnO Stainless steel Ti Glass beads D. Longrie et al., Surface & Coatings Technology, 213, , 2012. BPS – General Scientific Meeting 2016

20 Conformal Al2O3 coating on nano ZnO powder
Nano ZnO: nm particle size, 33.2 m²/g C O Zn Al 5nm Al2O3 Nanopowders often form micron-sized aggregates, however, ALD is capable of conformally coating the individual nanoparticles D. Longrie et al., Surface & Coatings Technology, 213, , 2012. BPS – General Scientific Meeting 2016

21 Surface functionalization of powders
Protective coatings Moisture/oxidation: phosphors, copper,... Aggressive chemicals: batteries UV radiation: inks, paint,... Active functionalities Optical coatings Catalysts Conductive coatings Particle-matrix interaction Adhesion: fiber reinforcement ,... Dispersion: inks, paint,... Hydrophobicity: e.g. Teflon Particle-particle interaction Sintering: 3D printing,... Rheology: 3D printing, pharmaceutics,... CoCooN experience BPS – General Scientific Meeting 2016

22 Surface functionalization of powders
Protective coatings Moisture/oxidation: phosphors, copper,... Aggressive chemicals: batteries UV radiation: inks, paint,... Active functionalities Optical coatings Catalysts Conductive coatings Particle-matrix interaction Adhesion: fiber reinforcement ,... Dispersion: inks, paint,... Hydrophobicity: e.g. Teflon Particle-particle interaction Sintering: 3D printing,... Rheology: 3D printing, pharmaceutics,... Phosphors for LED lighting Long term stability by encapsulation Uncoated 10nm Al2O3 20nm Al2O3 Avci et al., J. Electrochem. Soc., 156, J333, 2009. BPS – General Scientific Meeting 2016

23 Surface functionalization of powders
Protective coatings Moisture/oxidation: phosphors, copper,... Aggressive chemicals: batteries UV radiation: inks, paint,... Active functionalities Optical coatings Catalysts Conductive coatings Particle-matrix interaction Adhesion: fiber reinforcement ,... Dispersion: inks, paint,... Hydrophobicity: e.g. Teflon Particle-particle interaction Sintering: 3D printing,... Rheology: 3D printing, pharmaceutics,... Batteries for Electrical Vehicles 5x longer lasting 5x faster charging High-temperature performance 70% capacity fade after 10 years Current Li-ion Life cycle Energy density ALD coated particles (LiNiMnOx) Source: Pneumaticoat BPS – General Scientific Meeting 2016

24 Surface functionalization of powders
Protective coatings Moisture/oxidation: phosphors, copper,... Aggressive chemicals: batteries UV radiation: inks, paint,... Active functionalities Optical coatings Catalysts Conductive coatings Particle-matrix interaction Adhesion: fiber reinforcement ,... Dispersion: inks, paint,... Hydrophobicity: e.g. Teflon Particle-particle interaction Sintering: 3D printing,... Rheology: 3D printing, pharmaceutics,... Hydrophilic coating on Teflon Coating of Teflon (hydrophobic) with ceramic coating (Al2O3, TiO2,...) results in hydrophilic behavior Requirement of plasma-enhanced ALD! water droplet Untreated Teflon: hydrophobic Hydrophilic coating water easily penetrates BPS – General Scientific Meeting 2016

25 Outline Atomic layer deposition Industrial applications
ALD on powders and particles Conclusions BPS – General Scientific Meeting 2016

26 Conclusions Atomic layer deposition: Plasma-enhanced ALD:
3D surface engineering by conformal nanocoatings Industrially applied in microelectronics, photovoltaics, roll-to-roll Plasma-enhanced ALD: Highly energetic plasma species allow for lower deposition temperatures, wider range of coatings,... ALD / PE-ALD on powders and particles enabled by rotary reactor: Nanopowders to millimeter-sized particles New range of applications: battery, catalysts, LED lighting,... BPS – General Scientific Meeting 2016

27 Research Foundation Flanders
Acknowledgements Research Foundation Flanders CoCooN Conformal Coating of Nanomaterials BPS – General Scientific Meeting 2016

28 THANK YOU BPS – General Scientific Meeting 2016

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