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Nuclear Chemistry—chemistry of the nucleus Chemistry of the Nucleus Marie Curie.

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Presentation on theme: "Nuclear Chemistry—chemistry of the nucleus Chemistry of the Nucleus Marie Curie."— Presentation transcript:

1 Nuclear Chemistry—chemistry of the nucleus Chemistry of the Nucleus http://www.chem.orst.edu/graduate/pics/Reactor.jpg Marie Curie

2 How does a nuclear reactor work? http://www.lanl.gov/science/1663/images/reactor.jpg

3 How does a small mass contained in this bomb cause…… Nuclear Bomb of 1945 known as “fat man” http://www.travisairmuseum.org/assets/images/fatman.jpg

4 …this huge nuclear explosion? http://library.thinkquest.org/06aug/01200/Graphics/705px-Nuclear_fireball.jpg

5 Is there radon in your basement? http://a.abcnews.com/images/Blotter/abc_1radon_ad_070625_ssh.jpg

6 I. Radiation/Radioactivity A.What is it? 1.The release of energy and/or matter from the nuclei of atoms. 2.If something is radioactive it is giving of energy or particles 3.Radioactive decay = the spontaneous break down of an atom’s nucleus; may cause the atom to to turn into a different kind of atom.

7 B. Review of atom 1. nucleus contains protons & neutrons & electrons spin around nucleus 2. proton mass = ____ neutron = ____ electron = ___ 3. proton charge =____ neutron = _____ electron = ___ 4. atomic # = ________ 5. atomic mass = ______ + _______ 6. Isotopes: atoms with the same # of protons, but different number of neutrons than mass number.

8 Notation

9 H H H http://education.jlab.org/glossary/isotope.html

10 Isotopes of Carbon

11 C. Why are atoms radioactive? 1. The nucleus is unstable due to imbalance of protons and neutrons or a large # of neutrons and protons. 2. The strong force (holds the neutrons and protons together) & weak force (holds protons together) are not strong enough. 3. elements with atomic # > 83 = radioactive

12 II. Main Types of Radioactive Decay Alpha  Beta  Gamma 

13 A. Alpha Decay * Emission of alpha particle --  : Nucleus releases a particle that is 2 protons & 2 neutrons = Helium nucleus. (4 amu, 2+ charge) Proton # deceases by 2 & mass decreases by 4 Notation: can travel a few inches through air can be stopped by a sheet of paper, clothing.

14 Alpha Decay http://education.jlab.org/glossary/alphadecay.gif

15 Alpha Decay

16 B. Beta Decay Emission of Beta particles  electrons ejected from the nucleus when neutrons decay into a proton. Proton # increases by 1, mass stays same. Notation: Can be stopped by aluminum foil or a block of wood.

17 Beta Decay

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19 C. Gamma Decay Emission of Gamma radiation--  Gamma rays are electromagnetic waves or energy They have no mass. Gamma radiation has no charge. Most Penetrating, can be stopped by 1m thick concrete or a several cm thick sheet of lead.

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22 Examples of Radioactive Decay Alpha Decay Po  Beta Decay C  Gamma Decay Ni 

23 Band of Stability Number of Neutrons, (N) Number of Protons (Z)

24 III. Radioactive Half-Life : A.What is it: 1.The time it takes for half of a radioactive sample of atoms to change into something else. 2. represented by t 1/2

25 3. After one half -life there is 1/2 of original sample left. 4. After two half-lives, there will be 1/2 of the 1/2 = 1/4 the original sample.

26 Half-life of some isotopes Isotope Half-Life Radiation Emitted Carbon-14 5,730 years  Radon-222 3.8 days  Uranium-235 7.0 x 108 years  Uranium-238 4.46 x 109 years 

27 Example You have 100 g of radioactive C-14. The half-life of C-14 is 5730 years. How many grams are left after one half-life? How many grams are left after two half-lives?

28 Problem A sample of 3x10 7 Radon atoms are trapped in a basement that is sealed. The half-life of Radon is 4 days. How many radon atoms are left after 32 days?

29 B. Half-life Graphs 1.Can use graph to figure out half-life of an atom 2.As the parent isotope decreases the daughter isotope increases

30 C. Uses of Radioactive dating 1.Dating Fossils 2.Dating rocks 3.Finding a safe isotope to put in someone’s body 4.Determining when it is safe to go somewhere that there has been Radiation.

31 IV. Fission A.Splitting of an atomic nucleus into 2 smaller nuclei with the release of a large amount of energy and radiation. 1.Then energy is from the forces that held the nucleus together and also lost mass.

32 2.E= mc2– Einstein’s equation Energy = mass x the speed of light 2 There is the loss of some mass that is converted into energy 3.Nuclear chain reaction: continuous series of fission rxns. * as one nucleus splits, neutronsAre released to split more nuclei

33 B.Uses of fission 1. Nuclear power plants– use fission of Uranium-235 to create heat that create steams that turns a turbine that is used to create electricity. 2. Nuclear weapons: use fission to create immense amounts of energy (an explosion) to destroy people Critical mass: amount of U-235 that will sustain a chain reaction.

34 VI. Uses/Exposure to Radiation A.Uses 1. Fission– nuclear energy 2. Alpha/beta/gamma particles/rays: a.Sterilize food (kill microorganisms) b. detect leaks in pipes c.Medical uses (imaging, detecting disease, tracing Blood circulation, treating cancer

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36 B. Exposure A.Background radiation All around us from stars, rocks, etc. Earth’s atmosphere and magnetic field stops most of the cosmic radiation.

37 B.Other sources X-rays, other medical procedures, nuclear accidents

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39 V. Fusion A.The joining of 2 small atomic nuclei to form a single nucleus releasing a large amount of energy and radiation. 1.Need temps of millions of degrees Celsius 2. Occurs naturally on/in stars 3. Attempting to use it here for energy—but many problems

40 4. Occurs mostly with Hydrogen Atoms (lightest atoms) (drawing)

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42 VI. Stars A.Energy Source 1.Fusion: Hs fuse to make He 2.Produces huge amounts of light and heat B. Properties 1.Color & 2. Temperature—blue (hot!!) red (cool), yellow (medium), White (cool) 3. Brightness—affected by size and surface temperature ---if something is closer, it appears brighter ---Real brightness can be calculated 4. Size/Mass—cannot be measured directly, brightness is used

43 C. Hertzsprung-Russell Diagrams 1.Graph that helps classify stars 2.Used to estimate size, brightness, temp, distance, and changes in stars.

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46 D. Life Cycle of Stars 1.Star Formation a.Nebula b.Protostar c.Star

47 E. Star Death 1.Stars change when the H runs out 2.Now He starts to fuse 3.More mass = increased gravity


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