1. Air and Air Pollution CHAPTER 17

2. Key Concepts  Structure and composition of the atmosphere  Types and sources of outdoor air pollution  Types, formation, and effects of smog  Sources and effects of acid deposition  Effects of air pollution  Prevention and control of air pollution

3. The Atmosphere  Troposphere  Stratosphere  78% N, 21% O  Ozone layer  Greenhouse effect Pressure = 1,000 millibars at ground level Atmospheric pressure (millibars) 02004006008001,000 120 110 100 90 80 70 60 50 40 30 20 10 0 (SeaLevel) –80–4004080120 Temperature (˚C) Altitude (kilometers) Altitude (miles) 75 65 55 45 35 25 15 5 Thermosphere Heating via ozone Mesosphere Stratosphere Ozone “layer” Heating from the earth Troposphere Temperature Pressure Mesopause Stratopause Tropopause Fig. 17.2, p. 418

4. Outdoor Air Pollution  Primary pollutants  Secondary pollutants Primary Pollutants Secondary Pollutants Sources Natural Stationary COCO 2 SO 2 NONO 2 Most hydrocarbons Most suspended particles SO 3 HNO 3 H 2 SO 4 H2O2H2O2 O3O3 PANs MostandsaltsNO 3 – Mobile SO 4 2 – FIGURE 17-4 pg. 421

5. Photochemical Smog  Brown-air smog  Photochemical reaction  Photochemical oxidants Solar radiation Ultraviolet radiation NO Nitric oxide Photochemical smog: Photochemical oxidants; irritate respiratory tract H 2 O Water NO 2 Nitrogen dioxide Hydrocarbons O 2 Molecular oxygen HNO 3 Nitric acid PANs Peroxyacyl nitrates Aldehydes (e.g., formaldehyde) O 3 Ozone O Atomic oxygen Fig. 17.6, p. 424

6. Industrial Smog  Gray-air smog  Industrial smog  Sulfuric acid  Sulfur dioxide  Particulates Ultra Fine Particles Fine*** ParticlesLargeParticles Sea salt nuclei Carbon black Pollens Cement dust Oil smoke Combustion nuclei Metallurgical dust and fumes Photochemical smog Insecticide dusts Coal dust Average particle diameter (micrometers or microns) 0.0010.012.510.0100.0 Tobacco smoke Paint pigments Fly ash Milled flour Fig. 17.7, p. 425

7. Temperature Inversions  Subsidence inversion  Radiation inversion Warmer air Inversion layer Cool layer Mountain Mountain Valley Decreasing temperature Increasing altitude Fig. 17.9, p. 427

8. Regional Outdoor Air Pollution from Acid Deposition  Acid deposition  Wet deposition  Dry deposition Wind Transformation to sulfuric acid (H 2 SO 4 ) and nitric acid (HNO 3 ) Nitric oxide (NO) Acid fog Ocean Sulfur dioxide (SO 2 ) and NO Windborne ammonia gas and particles of cultivated soil partially neutralize acids and form dry sulfate and nitrate salts Dry acid deposition (sulfur dioxide gas and particles of sulfate and nitrate salts) Farm Lakes in deep soil high in limestone are buffered Lakes in shallow soil low in limestone become acidic Wet acid deposition (droplets of H 2 SO 4 and HNO 3 dissolved in rain and snow) Fig. 17.10, p. 428

9. Acid Deposition in the US Fig. 17.10, p. 428

10. Acid Deposition and Humans  Respiratory diseases  Toxic metal leaching  Decreased visibility  Damage to structures, especially containing limestone  Decreased productivity and profitability of fisheries, forests, and farms

11. Acid Deposition and Aquatic Systems  Fish declines  Undesirable species  Aluminum toxicity  Acid shock Waterboatman Whirligig Yellow perch Lake trout Brown trout Salamander(embryonic) Mayfly Smallmouthbass Mussel 6.56.05.55.04.54.03.5 pH Fig. 17.14, p. 431

12. Acid Deposition, Plants, and Soil  Damaging leaves and needles directly  Nutrient leaching  Damaging leaves and needles directly  Nutrient leaching  Heavy metal release  Weakens trees  Growth of acid-loving mosses  Weakens trees  Growth of acid-loving mosses

13. Indoor Air Pollution/Sick Building Syndrome Chloroform chlorine treated water Para-dichlorobenzene: air fresheners, mothball Tetrachloroethylene: dry-cleaning fluids Formaldehyde furniture stuffing, etc Benzo-  -pyrene Tobacco smoke, wood stoves Styrene: carpets, plastic Radon-222: radioactive soil, water Methylene Chloride Tobacco Smoke cigarettes Carbon Monoxide: faulty furnaces, stoves Asbestos insulation, tiles Nitrogen Oxides stoves, heaters 1, 1, 1- Trichloroethane aerosol sprays Fig. 17.16, p. 435

14. Radon  Radon-222  Lung cancer  Occurs in certain areas based on geology  Associated with uranium and organic material in rock Outlet vents for furnaces and dryers Slab joints Wood stove Cracks in floor Clothes dryer Furnace Radon-222 gas Slab Radium-222 Soil Uranium-238 Sump pump Cracks in wall Open window Openings around pipes Openings around pipes Fig. 17.18, p. 436

15. Effects of Air Pollution on Living Organisms and Materials  Damage to mucous membranes  Respiratory diseases (see Fig. 17-19 p. 437)  Damage to plant leaves and roots  Reduction in primary productivity  Deterioration of materials (See Table 17-3 p. 439)

16. Solutions: Preventing and Reducing Air Pollution  Clean Air Act: Good, but deficiencies  National Ambient Air Quality Standards (NAAQS)  Primary and secondary standards - protect human health and property

17. Emission Reduction PreventionDispersion or Cleanup Burn low-sulfur coal Remove sulfur from coal Convert coal to a liquid or gaseous fuel Shift to less polluting fuels Disperse emissions above thermal inversion layer with tall smokestacks Remove pollutants after combustion Tax each unit of pollution produced Fig. 17.22, pg.441

18. Reducing Indoor Air Pollution PreventionCleanup or Dilution Cover ceiling tiles and lining of AC ducts to prevent release of mineral fibers Ban smoking or limit it to well- ventilated areas Set stricter formaldehyde emissions standards for carpet, furniture, and building materials Prevent radon infiltration Use office machines in well-ventilated areas Use less polluting substitutes for harmful cleaning agents, paints, and other products Use adjustable fresh air vents for work spaces Increase intake of outside air Change air more frequently Circulate building’s air through rooftop greenhouses Use exhaust hoods for stoves and appliances burning natural gas Install efficient chimneys for wood-burning stoves Fig. 17.25, p. 443