1. AP Chemistry Jeopardy
2000

2. AP CHEM JEOPARDY Structure of Matter States of Matter Physical
Chemistry
Chemical
Bonding
Chemical
Reactions
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3. Chemical Bonding $100B
DAILY DOUBLE

4. Q - Which atom has a larger atomic radius?
Chem Bond $100
Q - Which atom has a larger atomic radius?
A) Ar C) Cl
B) Na D) Li

5. Chem Bond $200 Q - How Many Sigma and Pi bond does N2 contain?
A) one sigma, four pi
B) two sigma, two pi
C) three sigma
D) three pi
E) one sigma, two pi

6. Chem Bond $400
What are the the three atoms that bond to hydrogen in hydrogen bonding?

7. Nitrogen
Oxygen
Fluorine

8. Chem Bond $800
What are the two ways for a molecule to have a bent geometry?

9. A tetrahedral arrangement with two
unshared electron pairs (~109.5°)
A planar triangle geometry with one
unshared electron pair (~120°)

10. Chem Bond $1000
What are the four types of Unit Cells possible for crystal structures??

11. Simple Cubic 2r = s
Face centered 4r = 2 (sqr. Root r)
Body centered 4r = s (cube root r)
Hexagonal

12. Chem Bond $1500
Q - Which is NOT linear?
a) CO2
b) H2O
c) BeF2
d) N2

13. A

14. Chem Bond $2000
Why is the P-Cl bond in PCl5 a stronger bond than the C-O in carbon monoxide?
A) Increased Dipole - Dipole Forces
B) Hydrogen Bonding
C) Increased London Dispersion Forces

15. States of Matter $100 A) O2 B) Ar C) F2 D) Br2
Which of the following is not a gas at room temperature?
A) O2
B) Ar
C) F2
D) Br2

16. Bromine is a red liquid

17. States of Matter $200
Under what conditions would a substance sublimate at room conditions (25 °C and 1 atm)?
A) the critical temperature must be below the triple point
B) the slope of the fusion line should be negative
C) the triple point must be at a pressure greater than 1 atm
and 25°C
D) the solid phase must be more dense than the liquid phase

18. States of Matter $400
What would happen to the pressure of a gas if the temperature is tripled, the volume is doubled, and the number of gas molecules is quadrupled ?

19. A) T x (1/3)(1/2)(1/4)
B) T x (3/1)(2/1)(4/1)
C) T x (3/1)(1/2)(4/1)
D) T x (3/1)(1/2)(1/4)

20. Temp. is tripled P = kT
Volume is doubled P=k(1/V)
Moles is quad. P = kn

21. States of Matter $800
Is the slope for the solid/ liquid line in the phase diagram of water positive, negative, or can be either?

22. The kinetic molecular theory predicts that at a given temperature...
States of Matter $1000
The kinetic molecular theory predicts that at a given temperature...

23. A) All gases have the same KE
B) All gas molecules have the same
velocity
C) Only real gas molecules collide
with each other
D) On average, heavier molecules move more slowly
E) Elastic collisions result in the loss of energy.

24. States of Matter $1500
All of the following physical properties change as solute is added to the solution. Which is NOT a colligative property?
A) Boiling Point D) Surface Tension
B) Vapor Pressure E) Melting Point
C) Osmotic Pressure

25. Which of the following is most likely to be soluble in hexane?
States of Matter $2000
Which of the following is most likely to be soluble in hexane?
A) KCl D) H2O
B) C2H5OH E) C6H6
C) HC2H3O2

26. What is the free energy of a system at equilibrium? . . .
Physical Chemistry $100
What is the free energy of a system at equilibrium? . . .

27. ∆ G = equilibrium
< 0 if spontaneous
> 0 if non-spontaneous

28. Physical Chemistry $200
When ∆H is positive and ∆S is negative, will temperature changes have an effect on the spontaneity of a reaction?
YES NO

29. The rate of reaction will be large if:
Physical Chemistry $400
The rate of reaction will be large if:
A) ∆G° is a large (-) number
B) ∆S° is a large (-) number
C) ∆H° is a large (-) number
D) Keq is a large (+) number
E) None of the above

30. Physical Chemistry $800
The Law of Dulong and Petit says that the molar specific heat of solid elements is approximately 25 J/mol•K. This suggests that. . .

31. a) The heat absorbed depends only on the number of atoms
b) the heat absorbed depends on the volume change with temperature
c) the heat absorbed can be calculated from the 1st Law of Thermodynamics
d) this law is an oddity since it does not apply to elements that are liquids / gases

32. An inorganic catalyst doesn’t...
Physical Chemistry $1000
An inorganic catalyst doesn’t...
A) Ensure proper geometry
B) Weaken existing bonds
C) Lose effectiveness when heated
D) Decrease the activation energy of a reaction

33. Catalysts lower the activation energy of a reaction thus increasing the rate by ensuring proper geometry and weakening existing bonds in the molecule.
Only ORGANIC catalysts are effected by a temperature change.

34. What equation would you use to solve:
Physical Chemistry $1500
What equation would you use to solve:
How much heat does it take to raise 10 grams of water by 10°C? . . .

35. q = m • c • ∆T

36. Physical Chemistry $2000
What is the equation is used to find how temperature changes affect rates of reaction?

37. ln k2 = Ea (T2 - T1)
k1 R T2•T1

38. Which of the following would produce odor if heated?
Chemical Reactions $100
Which of the following would produce odor if heated?
A) NH3 D) PbI2
B) Na+(aq) E) A and C
C) KI

39. One mole of electrons is how many coulombs?
Chemical Reactions $200
One mole of electrons is how many coulombs?

40. 96,485 C

41. A molecule of NaHSO4 is . . . a) Acidic b) Basic c) Neutral
Chemical Reactions $400
A molecule of NaHSO4 is . . .
a) Acidic
b) Basic
c) Neutral

42. Na+ is neutral because it is the conjugate acid of a strong base.
HSO4- is acidic because it can further produce H+ ions in solution (but it also has amphoteric properties).

43. Chemical Reactions $800
Which of the following compounds includes an element that has the same oxidation # as the chlorine in sodium chlorate, NaClO3?
A) K3Fe(CN)6 D) (NH4) 2SO4
B) KMnO4 E) KClO4
C) Al(NO3)3

44. Chemical Reactions $1000
DAILY DOUBLE

45. Which of the following statements
is FALSE?

46. A) reduction involves a gain of e-
B) batteries are galvanic cells
C) a spontaneous reaction always has a (+) E°cell
D) electrolysis reactions always produce a gas at at least one electrode
E) Galvanic cells can be used to determine equilibrium constants

47. What will be the products of the following equation?
Chemical Reactions $1500
What will be the products of the following equation?
FeCl2 + HCl + KMnO4 -->
???

48. (K+ and Cl- are spectator ions)
FeCl2 + HCl + KMnO4 -->
FeCl3 + MnCl2 + H2O + KCl
Ox: Fe2+ --> Fe e-
Red: MnO4 - + H+ --> Mn2+ + H2O
(K+ and Cl- are spectator ions)

49. The electrolysis of KI in water
Chemical Reactions $2000
Predict the net ionic equation for the following reaction and tell what form the reactants will be present . . .
The electrolysis of KI in water

50. Electrolysis of KI in water. (H2O has a E°red closer to zero than K+)
Ox: 2 I- --> I e-
Red: 2 H2O e- --> H OH-
2 H2O I- --> H OH- + I2
Electrolysis of KI in water. (H2O has a E°red closer to zero than K+)

51. Structure of Matter $100
Which of the following elements has the greatest number of p electrons?

52. A) C
B) Si
C) Fe
D) Cl
E) As

53. Even though some of the others have more p electrons in their OUTER shell, Arsenic has more TOTAL p electrons.

54. Structure of Matter $200
An electron with the four quantum numbers 3,2,-1,-1/2 may be an electron in an unfilled sublevel of . . .

55. A) Ca
B) Fe
C) Al
D) Ar
E) Ag

56. B) Fe
It says UNFILLED sublevel. Since the 1st two quantum #’s are “3” and “2” that means an unfilled 3-d orbital. Fe is the only one with an unfilled 3-d orbital.

57. Chemical Properties are defined by the:
Structure of Matter $400
Chemical Properties are defined by the:
A) Electrons C) Neutrons
B) Protons D) Ionization Energy
C) Electronegativity

58. The best way to estimate the boiling points of Pd is to:
Structure of Matter $800
The best way to estimate the boiling points of Pd is to:
A) average the b.p.’s of Rh and Ag
B) average the b.p.’s of Ni and Pt
C) average the b.p.’s of Ir and Cu
D) average the b.p.’s of Co and Au
E) None of the above will work.

59. Structure of Matter $1000
In which of the following pairs of elements is the element with the lower boiling point listed first?
A) Na, Cs D) Ba, Sr
B) Te, Se E) I, Br
C) P, N

60. States of Matter $1500
Carbon-14 has a half-life of 5730 years. How old is a wooden object if 70% of the C-14 has decayed?
A) yr D) yr
B) yr E) yr
C) yr

61. Radioactive decay is a first order reaction therefore…
Rate = kX
ln Xo = kt X
Ln X = k t 1/2 X
ln 2 = k t 1/2 ==> t 1/2 = 0.693/k

62. Structure of Matter $2000
An electron that falls from a higher energy level to n=3 emits a wavelength that fall in what “series?”

63. Paschen Series

64. Lyman: n = ∞ --> n = 1 Balmer: n = ∞ --> n = 2
Ultraviolet
Balmer: n = ∞ --> n = 2
Visible
Paschen: n = ∞ --> n = 3
Infrared